Continental rift systems and anorogenic magmatism

Precambrian Laurentia and Mesozoic Gondwana both rifted along geometric patterns that closely approximate truncated-icosahedral tessellations of the lithosphere. These large-scale, quasi-hexagonal rift patterns manifest a least-work configuration. For both Laurentia and Gondwana, continental rifting coincided with drift stagnation, and may have been driven by lithospheric extension above an insulated and thermally expanded mantle. Anorogenic magmatism, including flood basalts, dike swarms, anorthosite massifs and granite-rhyolite provinces, originated along the Laurentian and Gondwanan rift tessellations. Long-lived volcanic regions of the Atlantic and Indian Oceans, sometimes called hotspots, originated near triple junctions of the Gondwanan tessellation as the supercontinent broke apart. We suggest that some anorogenic magmatism results from decompression melting of asthenosphere beneath opening fractures, rather than from random impingement of hypothetical deep-mantle plumes.     

Iron and Sulfur Chemistry in a Stratified Lake: Evidence for Iron-Rich Sulfide Complexes

A four month study of a man-made lake used for hydroelectric power generation in northeastern Pennsylvania USA was conducted to investigate seasonal anoxia and the effects of sulfide species being transported downstream of the power generation equipment. Water column analyses show that the system is iron-rich compared to sulfide. Total Fe(II) concentrations in the hypolimnion are typically at least twice the total sulfide levels. In situ voltammetric analyses show that free Fe(II) as [Fe(H₂O)₆]²⁺ or free H₂S as H₂S/HS^- are either not present or at trace levels and that iron-rich sulfide complexes are present. From the in situ data and total Fe(II) and H₂S measurements, we infer that these iron-rich sulfide complexes may have stoichiometries such as Fe₂SH³⁺ (or polymeric forms of this and other stoichiometries). These iron-rich sulfide complexes appear related to dissolution of the iron-rich FeS mineral, mackinawite, because IAP calculations on data from discrete bottle samples obtained from bottom waters are similar to the pK_sp of mackinawite. Soluble iron-sulfide species are stable in the absence of O₂ (both in lake waters and the pipeline) and transported several miles during power generation. However, iron-sulfide complexes can react with O₂ to oxidize sulfide and can also dissociate releasing volatile H₂S when the waters containing them are exposed to the atmosphere downstream of the powerplant. Sediment analyses show that the lake is rich in oxidized iron solids (both crystalline and amorphous). Fe concentrations in FeS solids are low (<5 μmole/gr_{dry wt}) and the pyrite concentration ranges from about equal to the solid FeS to 30 times the solid FeS concentration. The degree of pyritization is below 0.12 indicating that pyrite formation is limited by free sulfide, which can react with the iron-rich sulfide complexes.     

Carbon isotope fractionation in phospholipid fatty acid biomarkers of bacteria and fungi native to an acid mine drainage lake

This study identifies isotope signatures associated with autotrophic and heterotrophic microbial communities that may provide a means to determine carbon cycling relationships in situ for acid mine drainage (AMD) sites. Stable carbon isotope ratios (δ¹³C) of carbon sources, bulk cells, and membrane phospholipids (PLFA) were measured for autotrophic and heterotrophic microbial enrichment cultures from a mine tailings impoundment in northern Ontario, Canada, and for pure strains of the sulfur oxidizing bacteria Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans. The autotrophic enrichments had indistinguishable PLFA distributions from the pure cultures, and the PLFA cyc-C_19:0 was determined to be a unique biomarker in this system for these sulfur oxidizing bacteria. The PLFA distributions produced by the heterotrophic enrichments were distinct from the autotrophic distributions and the C_18:2 PLFA was identified as a biomarker for these heterotrophic enrichments. Genetic analysis (16S, 18S rRNA) of the heterotrophic cultures indicated that these communities were primarily composed of Acremonium fungi.Stable carbon isotope analysis revealed that bulk cellular material in all autotrophic cultures was depleted in δ¹³C by 5.6–10.9‰ relative to their atmospheric CO₂ derived carbon source, suggesting that inorganic carbon fixation in these cultures is carbon limited. Individual PLFA from these autotrophs were further depleted by 8.2–14.6‰ compared to the bulk cell δ¹³C, which are among the largest biosynthetic isotope fractionation factors between bulk cell and PLFA reported in the literature. In contrast, the heterotrophic bulk cells were not significantly fractionated in δ¹³C relative to their carbon source and heterotrophic PLFA ranged from 3‰ enriched to 4‰ depleted relative to the isotopic composition of their total biomass. These distinct PLFA biomarkers and isotopic fractionations associated with autotrophic and heterotrophic activity in this laboratory study provide potential biomarkers for delineating autotrophic and heterotrophic carbon cycling in AMD environments.     

Vertical heat transports in the ocean and their effect on time-dependent climate change

In response to increasing atmospheric concentrations of greenhouse gases, the rate of time-dependent climate change is determined jointly by the strength of climate feedbacks and the efficiency of processes which remove heat from the surface into the deep ocean. This work examines the vertical heat transport processes in the ocean of the HADCM2 atmosphere–ocean general circulation model (AOGCM) in experiments with CO₂ held constant (control) and increasing at 1 per year (anomaly). The control experiment shows that global average heat exchanges between the upper and lower ocean are dominated by the Southern Ocean, where heat is pumped downwards by the wind-driven circulation and diffuses upwards along sloping isopycnals. This is the reverse of the low-latitude balance used in upwelling–diffusion ocean models, the global average upward diffusive transport being against the temperature gradient. In the anomaly experiment, weakened convection at high latitudes leads to reduced diffusive and convective heat loss from the deep ocean, and hence to net heat uptake, since the advective heat input is less affected. Reduction of deep water production at high latitudes results in reduced upwelling of cold water at low latitudes, giving a further contribution to net heat uptake. On the global average, high-latitude processes thus have a controlling influence. The important role of diffusion highlights the need to ensure that the schemes employed in AOGCMs give an accurate representation of the relevant sub-grid-scale processes. Received: 8 July 1999 / Accepted: 17 November 1999     

Analysis of the surface temperature and wind forecast errors of the NCAR-AirDat operational CONUS 4-km WRF forecasting system

Investigating the characteristics of model-forecast errors using various statistical and object-oriented methods is necessary for providing useful guidance to end-users and model developers as well. To this end, the random and systematic errors (i.e., biases) of the 2-m temperature and 10-m wind predictions of the NCAR-AirDat weather research and forecasting (WRF)-based real-time four-dimensional data assimilation (RTFDDA) and forecasting system are analyzed. This system has been running operationally over a contiguous United States (CONUS) domain at a 4-km grid spacing with four forecast cycles daily from June 2009 to September 2010. In the result an exceptionally useful forecast dataset was generated and used for studying the error properties of the model forecasts, in terms of both a longer time period and a broader coverage of geographic regions than previously studied. Spatiotemporal characteristics of the errors are investigated based on the 24-h forecasts between June 2009 and April 2010, and the 72-h forecasts between May and September 2010. It was found that the biases of both wind and temperature forecasts vary greatly seasonally and diurnally, with dependency on the forecast length, station elevation, geographical location, and meteorological conditions. The temperature showed systematic cold biases during the daytime at all station elevations and warm biases during the nighttime above 1,000 m above sea level (ASL), while below 600 m ASL cold biases occurred during the nighttime. The forecasts of surface wind speed exhibited strong positive biases during the nighttime, while the negative biases were observed in the spring and summer afternoons. The surface wind speed was mostly over-predicted except for the stations located between 1,000 and 2,100 m ASL, for which negative biases were identified for most forecast cycles. The highest wind-speed errors were found over the high terrain and near sea-level stations. The wind-direction errors were relatively large at the high-terrain elevation in the Rocky and Appalachian mountain ranges and the western coastal areas and the error structure exhibited notable diurnal variability.     

地壳的拆离作用与华北克拉通破坏:晚中生代伸展构造约束

伸展条件下的地壳拆离作用是岩石圈减薄的重要浅部构造响应。晚中生代时期的伸展构造(包括拆离断层、变质核杂岩构造和断陷盆地)在华北、华南、东北和东蒙古及贝加尔地区普遍发育,它们切过上部地壳(断陷盆地)、中、上地壳(拆离断层)或中部地壳(变质核杂岩)。地壳拆离作用具有运动学极性(NWW或SEE)、几何学宏观(区域)对称与微观(局部)不对称性、遍布全区但不均匀性,以及形成时间的跨越性(140~60Ma)等特点,并使得地壳和岩石圈发生显著的减薄。本文研究揭示出现今岩石圈厚度变化与晚中生代伸展构造的发育程度和分布之间并没有必然的联系。其变化的基本规律是,除新生代裂陷发育区岩石圈厚度明显较小且厚度有迅速变化外,从华北向贝加尔地区总体的变化趋势是逐渐加厚,也即东亚地区岩石圈具有楔形形态。晚中生代时期的地壳(或地幔)拆离作用伴随着广泛的岩石圈减薄作用,区域岩石圈同时遭受到一定程度的减薄和破坏,华北克拉通在这一时期的破坏仅仅是区域岩石圈减薄在华北的具体体现。     

The role of baseflow in dissolved solids delivery to streams in the Upper Colorado River Basin

Salinity has a major effect on water users in the Colorado River Basin, estimated to cause almost $300 million per year in economic damages. The Colorado River Basin Salinity Control Program implements and manages projects to reduce salinity loads, investing millions of dollars per year in irrigation upgrades, canal projects, and other mitigation strategies. To inform and improve mitigation efforts, there is a need to better understand sources of salinity to streams and how salinity has changed over time. This study explores salinity in the baseflow fraction of streamflow, assessing whether groundwater is a significant contributor of dissolved solids to streams in the Upper Colorado River Basin (UCRB). Chemical hydrograph separation was used to estimate baseflow discharge and baseflow dissolved solids loads at stream gages (n = 69) across the UCRB. On average, it is estimated that 89% of dissolved solids loads originate from the baseflow fraction of streamflow, indicating that subsurface transport processes play a dominant role in delivering dissolved solids to streams in the UCRB. A statistical trend analysis using weighted regressions on time, discharge, and season was used to evaluate changes in baseflow dissolved solids loads in streams (n = 27) from 1986 to 2011. Decreasing trends in baseflow dissolved solids loads were observed at 63% of streams. At the three most downstream sites, Green River at Green River, UT, Colorado River at Cisco, UT, and the San Juan River near Bluff, UT, baseflow dissolved solids loads decreased by a combined 823,000 metric tons (mT), which is approximately 69% of projected basin‐scale decreases in total dissolved solids loads as a result of salinity control efforts. Decreasing trends in baseflow dissolved solids loads suggest that salinity mitigation projects, landscape changes, and/or climate are reducing dissolved solids transported to streams through the subsurface. Notably, the pace and extent of decreases in baseflow dissolved solids loads declined during the most recent decade; average decreasing loads during the 2000s (28,200 mT) were only 54% of average decreasing loads in the 1990s (51,700 mT).     

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.     

The alluvial architecture of a suspended sediment dominated meandering river: the Río Bermejo,Argentina

The alluvial architecture of fine‐grained (silt‐bed) meandering rivers remains poorly understood in comparison to the extensive study given to sand‐bed and gravel‐bed channels. This paucity of knowledge stems, in part, from the difficulty of studying such modern rivers and deriving analogue information from which to inform facies models for ancient sediments. This paper employs a new technique, the parametric echosounder, to quantify the subsurface structure of the Río Bermejo, Argentina, which is a predominantly silt‐bed river with a large suspended sediment load. These results show that the parametric echosounder can provide high‐resolution (decimetre) subsurface imaging from fine‐grained rivers that is equivalent to the more commonly used ground‐penetrating radar that has been shown to work well in coarser‐grained rivers. Analysis of the data reveals that the alluvial architecture of the Río Bermejo is characterized by large‐scale inclined heterolithic stratification generated by point‐bar evolution, and associated large‐scale scour surfaces that result from channel migration. The small‐scale and medium‐scale structure of the sedimentary architecture is generated by vertical accretion deposits, bed sets associated with small bars, dunes and climbing ripples and the cut and fill from small cross‐bar channels. This style of alluvial architecture is very different from other modern fine‐grained rivers reported in the literature that emphasize the presence of oblique accretion. The Río Bermejo differs from these other rivers because it is much more active, with very high rates of bank erosion and channel migration. Modern examples of this type of highly active fine‐grained river have been reported rarely in the literature, although ancient examples are more prevalent and show similarities with the alluvial architecture of the Río Bermejo, which thus represents a useful analogue for their identification and interpretation. Although the full spectrum of the sedimentology of fine‐grained rivers has yet to be revealed, meandering rivers dominated by lateral or oblique accretion probably represent end members of such channels, with the specific style of sedimentation being controlled by grain size and sediment load characteristics.