Non-biological fractionation of stable Ca isotopes in soils of the Atacama Desert, Chile

We measured Ca stable isotope ratios (δ^44/40Ca) in an ancient (2 My), hyperarid soil where the primary source of mobile Ca is atmospheric deposition. Most of the Ca in the upper meter of this soil (3.5 kmol m⁻²) is present as sulfates (2.5 kmol m⁻²), and to a lesser extent carbonates (0.4 kmol m⁻²). In aqueous extracts of variably hydrated calcium sulfate minerals, δ^44/40Ca_E values (vs. bulk Earth) increase with depth (1.4 m) from a minimum of −1.91‰ to a maximum of +0.59‰. The trend in carbonate-δ^44/40Ca in the top six horizons resembles that of sulfate-δ^44/40Ca, but with values 0.1-0.6‰ higher. The range of observed Ca isotope values in this soil is about half that of δ^44/40Ca values observed on Earth. Linear correlation among δ^44/40Ca, δ³⁴S and δ¹⁸O values indicates either (a) a simultaneous change in atmospheric input values for all three elements over time, or (b) isotopic fractionation of all three elements during downward transport. We present evidence that the latter is the primary cause of the isotopic variation that we observe. Sulfate-δ³⁴S values are positively correlated with sulfate-δ¹⁸O values (R² = 0.78) and negatively correlated with sulfate δ^44/40Ca_E values (R² = 0.70). If constant fractionation and conservation of mass with downward transport are assumed, these relationships indicate a δ^44/40Ca fractionation factor of −0.4‰ in CaSO₄. The overall depth trend in Ca isotopes is reproduced by a model of isotopic fractionation during downward Ca transport that considers small and infrequent but regularly recurring rainfall events. Near surface low Ca isotope values are reproduced by a Rayleigh model derived from measured Ca concentrations and the Ca fractionation factor predicted by the relationship with S isotopes. This indicates that the primary mechanism of stable isotope fractionation in CaSO₄ is incremental and effectively irreversible removal of an isotopically enriched dissolved phase by downward transport during small rainfall events.     

Sequence stratigraphy of the Mancos Shale,lower Tres Hermanos Formation,and coeval middle Cenomanian to middle Turonian strata,southern New Mexico,USA

Sequence stratigraphic analysis of four widely spaced outcrops of middle Cenomanian to middle Turonian strata deposited in the Western Interior foreland basin in southern New Mexico, USA, defines ten sequence boundaries in a marine shale‐rich interval ca 200 m thick. The majority of sequence boundaries are based on basinward shifts in lithofacies characterized by either a non‐Waltherian contact between distal‐bar or lower shoreface sandstone and underlying lower offshore shale, or an erosional contact between distal‐bar or lower shoreface sandstone and underlying upper offshore shale. The sequence boundaries commonly correlate basinward to packages of storm‐deposited sandstone and to beds of sandy grainstone composed of winnowed inoceramid shell fragments. In several cases, however, the sequence boundaries pass basinward into presumably conformable successions of lower offshore shale. Maximum flooding surfaces within the sequences are represented by one or more beds of locally phosphatized globiginerid wackestone and packstone or exist within a conformable succession of lower offshore shale. Following initial south/south‐westward transgression into the study area, the regional trend of palaeoeshorelines was north‐west to south‐east, although isopach data indicate that lobes of sandstone periodically spread south‐eastward across the study area. The ten sequences in the study area are arranged into a third‐order composite megasequence that is characterized by overall upward‐deepening followed by upward‐shallowing of sequences. The composite megasequence is similar but not identical to the previously established T‐1 transgression and R‐1 regression in New Mexico. Based on radioisotopic dates of bentonites, the average frequency of the sequences within the study area was ca 327 kyr, which is consistent with fourth‐order cycles of ca 400 kyr interpreted in coeval marine strata elsewhere in the world.     

A complete and easily accessible means of calculating surface exposure ages or erosion rates from Be and Al measurements

We codify previously published means of calculating exposure ages and erosion rates from ¹⁰Be and ²⁶Al concentrations in rock surfaces, and present a single complete and straightforward method that reflects currently accepted practices and is consistent with existing production rate calibration measurements. It is intended to enable geoscientists, who wish to use cosmogenic-nuclide exposure age or erosion rate measurements in their work to: (a) calculate exposure ages and erosion rates; (b) compare previously published exposure ages or erosion rate measurements on a common basis; (c) evaluate the sensitivity of their results to differences between published production rate scaling schemes. The method is available online at http://hess.ess.washington.edu.     

On residual currents in the central strait of Georgia,B.C.: Research note

Abstract

Numerical modelling effort to understand low‐frequency circulation in the Strait of Georgia has been found to underestimate the strength of the circulation by roughly an order of magnitude. At least in part, this model defect may be due to the absence of statistical‐dynamical tendencies that result from eddy interactions (in reality). This defect is generic to ocean numerical models ranging from estuarine to global‐scale applications. A simple change to the formulation of eddy viscosity may help, making models somewhat “less wrong” if not yet “right”.     

Identification of water quality and zooplankton characteristics in Daya Bay, China, from 2001 to 2004

Data collected from 12 marine monitoring stations in Daya Bay from 2001 to 2004 reveal a substantial change in ecological environment in this region. Cluster analysis based on water quality and zooplankton results divided stations into three clusters: Cluster I consisted of stations S1, S2 and S6 in the south part of Daya Bay; Cluster II consisted of stations S3, S8 and S11 in the cage culture areas in the southwest part, the northwest part near Aotou harbor and the northeast part near the Fanhe harbor of Daya Bay; Cluster III consisted of stations S4, S5, S7, S9, S10 and S12 that were in southwest, the middle and northeast parts of Daya Bay. Bivariate correlations between zooplankton biomass and the major physical and nutrient variables were evaluated for all stations. The zooplankton biomass in all stations correlated positively with salinity, pH, secchi, NO₃-N, NH₄-N, TIN/PO₄-P and SiO₃-Si/PO₄-P, and negatively correlated with temperature, DO, COD, NO₂-N and TIN, PO₄-P, SiO₃-Si and BOD₅. Factors analysis shows high positive loading salinity, secchi and NH₄-N of three clusters, which indicates that all stations of the three clusters were primarily grouped according to their respective nutrient conditions. The results of multivariate statistical analysis revealed that temperature, DO, TIN and BOD₅ could also play an important role in determining the biomass of the zooplankton in Daya Bay, especially in the stations near the nuclear power plants and in the cage culture areas.     

Influence of Pore Fluid Chemistry on the Mechanical Properties of Clay-Based Materials

The producers of nuclear waste, within all countries exploring options, including Canada, have determined the long-term solution to be a deep geological repository. In the Canadian concept, within the deep geologic repository a number of clay-based barriers will separate the containers from the surrounding geosphere. Following placement the surrounding groundwater will infiltrate into the repository. In order to analyze the performance of the repository under very complex conditions, accurate material properties are required. The chemistry of the host rock is an important aspect as the behaviour of clay-based barrier materials could be affected by the saturating saline groundwater. This paper investigates the saturated mechanical behaviour of light backfill (composed of 50 % silica sand and 50 % Na-bentonite clay) and dense backfill (composed of 70 % crushed granite, 25 % glacial lake clay and 5 % Na-bentonite clay) and the quantifying the effect of pore fluid chemistry on the strength and compressibility behaviour of the materials. The results indicate that light backfill behaviour is strongly influenced by its pore fluid chemistry while dense backfill shows limited effects. The material parameters of light backfill and dense backfill are interpreted for input into numerical simulations. These results and interpretation enrich the understanding of the mechanical response of light and dense backfill, two components of the sealing system of the Canadian deep geologic repository.     

Intermediate sulfidation epithermal gold-base metal deposits in Tertiary subaerial volcanic rocks,Sahinli/Tespih Dere (Lapseki/Western Turkey)

Gold in the Sahinli and Tespih Dere intermediate sulfidation gold-base metal deposits in Western Turkey occurs in relatively deep epithermal quartz veins along with base metal minerals which have epithermal textures, including plumose quartz, vug infills, comb and cockade textures and matrix-supported milled breccias. The total sulfide content of the veins in the area is variable ranging from < 1% to 60% and is dominated by pyrite, galena, sphalerite and chalcopyrite. Sphalerite is Fe-poor (0.6 to 1.4 mol% FeS). Minor amounts of Ag-rich tetrahedrite are present. Primary hydrothermal alteration minerals include illite/muscovite, mixed-layer illite/smectite (11.6 Å) and clinochlore towards the east and, alunite, dickite/nacrite and pyrophyllite towards the west at Sahinli; major illite/muscovite and dickite occur at Tespih Dere and Sarioluk, respectively.Fluid inclusions in main-stage quartz at Sahinli are only liquid-rich, with homogenization temperatures ranging from 220 to 322 °C and the majority of T_h values between 250 and 300 °C. Salinity ranges from 4.3 to 6.9 wt.% NaCl equiv. First ice-melting temperatures (T_mf) between ?24.5 and ?19.0 °C indicate that the fluids were dominated by NaCl – H₂O during mineralization. The relatively higher average T_h at the Tespih Dere deposit (295 °C) is attributed to a relatively deeper level of exposure.Calculated δ¹⁸O values indicate that ore-forming hydrothermal fluids in the study area had δ¹⁸O_H2O ranging from + 1.1 to + 9.7‰ (average = 3.8‰), strongly ¹⁸O-enriched compared with present-day hydrothermal meteoric water in the area (δ¹⁸O = ?8.5‰). δD values of fluid inclusions in quartz range from ?58 to ?93‰ and δD values of clay minerals and alunite from ?40 to ?119‰. δD values from intermediate argillic alteration (average = ?68‰) in the study area are very similar to δD values of the present-day local geothermal system (average δD = ?54‰) whereas δD values from advanced-argillic alteration (average δD = ?33‰) are very different from the present-day local geothermal system.The δ³⁴S values in samples from the Sahinli and Tespih Dere deposits average ?2.9‰ for pyrite; ?3.3‰ for chalcopyrite; ?5.4‰ for sphalerite and ?7.6‰ for galena. These data are consistent with derivation of the sulfur from either igneous rocks or possibly from local wallrock.     

Delta13C and delta15N shifts in benthic invertebrates exposed to sewage from McMurdo Station, Antarctica

In an effort to identify biomonitors for contamination of Antarctic marine benthos by sewage, this study determines whether the US Antarctic Program’s McMurdo Station produces a benthic sewage footprint and whether resident megafauna are assimilating sewage-derived material. We identified strong C and N isotopic gradients in benthic sediment as a function of downstream distance from McMurdo Station’s point-source sewage addition. Sediment C and N isotope ratios approached marine background levels at the sampling end-point 612 m downcurrent. Based on isotope abundances in their tissues, at least some sewage C and N were assimilated by the sedentary, suspension feeding soft coral Alcyonium antarcticum, ascidian Cnemidocarpa verrucosa and bivalve Laternula elliptica. However, as inferred by tissue-sediment differences in downstream isotope trends, such assimilation was not in proportion to sewage exposure and input, therefore implying non-generalist feeding behavior by these species. In contrast, the motile, generalist feeding sea urchin Sterechinus neumayeri, sea star Odontaster validus and ribbon worm Parborlasia corrugatus showed isotopic evidence of sewage C and N assimilation roughly in proportion to sewage input. We recommend these generalist feeders for further use as biomonitors at this site now that sewage treatment has been implemented. As these species are circumpolar in distribution, they may also prove useful elsewhere in the Antarctic.