An empirical significant duration relationship for stable continental regions

An empirical predictive relationship correlating significant duration to earthquake magnitude, site-to-source distance, and local site conditions (i.e., rock vs. stiff soil) for stable continental regions is presented herein. The correlations were developed from data derived from 620 horizontal motions for stable continental regions (e.g., central and eastern North America: CENA), consisting of 28 recorded motions and 592 scaled motions. The data set encompasses the earthquake magnitude from 4.5 to 7.6 and the distance from 0.1 to 199 km. The non-linear mixed-effects regression technique was used to fit a predictive model to the significant duration data. Similar to the trend observed from active shallow crustal region motions, significant durations predicted for stable continental region motions increased with increasing earthquake magnitude and increasing site-to-source distance. In comparing the predicted durations for CENA motions with those for motions from active shallow crustal regions (e.g., western North America: WNA), it is shown that the differences in significant durations for the two regions are relatively minor for site-to-source distances less than about 100 km. Lastly, the significant durations predicted by the proposed model are shown to be in good agreement with durations of the motions recorded during the Mineral, Virginia earthquake of August 23, 2011.     

Internal waves,baroclinic energy fluxes and mixing at the European shelf edge

The energy flux in internal waves generated at the Celtic Sea shelf break was estimated by (i) applying perturbation theory to a week-long dataset from a mooring at 200 m depth, and (ii) using a 2D non-hydrostatic circulation model over the shelf break. The dataset consisted of high resolution time-series of currents and vertical stratification together with two 25-h sets of vertical profiles of the dissipation of turbulent kinetic energy. The observations indicated an average energy flux of 139 W m⁻¹, travelling along the shelf break towards the northwest. The average energy flux across the shelf break at the mooring was only 8 W m⁻¹. However, the waves propagating onshelf transported up to 200 W m⁻¹, but they were only present 51% of the time. A comparison between the divergence of the baroclinic energy flux and observed dissipation within the seasonal thermocline at the mooring showed that the dissipation was at least one order of magnitude larger. Results from a 2D model along a transect perpendicular to the shelf break showed a time-averaged onshelf energy flux of 153–425 W m⁻¹, depending on the magnitude of the barotropic forcing. A divergence zone of the energy flux was found a few kilometre offshore of the location of the observations in the model results, and fluxes on the order of several kW m⁻¹ were present in the deep waters further offshelf from the divergence zone. The modelled fluxes exhibited qualitative agreements with the phase and hourly onshelf magnitudes of the observed energy fluxes. Both the observations and the model results show an intermittent onshelf energy flux of 100–200 W m⁻¹, but these waves could only propagate ∼20–30 km onshore before dissipating. This conclusion was supported by a 25-h dataset sampled some 180 km onto the shelf, where a weak wave energy flux was found going towards the shelf break. We therefore conclude that shelf break generated internal waves are unlikely to be the main source of energy for mixing on the inner part of the shelf.     

Microbial food web contributions to bottom water hypoxia in the northern Gulf of Mexico

Nutrients from the Mississippi/Atchafalaya Rivers greatly stimulate biological production in the ‘classical’ food web on the inner shelf of the northern Gulf of Mexico. Portions of this production, especially large diatoms and zooplankton fecal pellets, sink and decompose in the bottom water, consuming oxygen and contributing to the annual development of an extensive zone of bottom water hypoxia, typically >15,000 km² since 1993. The microbial food web is also active in the Mississippi River plume, but consists of small organisms that sink slowly. This ‘recycling’ food web has not been considered as a significant contributor to vertical flux and hypoxia. However, gelatinous zooplankton, especially pelagic appendicularians such as Oikopleura dioica, mediate the conversion of microbial web organisms to organic particles with high sinking rates. When pelagic appendicularians are abundant in coastal regions of the northern Gulf of Mexico, they stimulate the rapid vertical transfer of microbial web productivity in the surface layer, which is only 5–15 m thick in the coastal hypoxic region, to the sub-pycnocline layer that becomes hypoxic each summer. In this paper we present results from two studies examining the significance of this pathway. In both 2002 and 2004, we observed high production rates of appendicularians in coastal waters. Discarded gelatinous houses and fecal pellets from the appendicularian populations often provided more than 1 g m⁻² d⁻¹ of organic carbon for the establishment and maintenance of hypoxia in the northern Gulf of Mexico. This source of organic matter flux is especially important in regions far from the river plumes and during periods of low river discharge. Autotrophic elements of this food web are primarily supported by recycled inorganic nutrients originating in the Mississippi and Atchafalaya Rivers. Sources of dissolved organic matter (DOM) supporting the heterotrophic components of this microbial food web may include in situ production, the Mississippi/Atchafalaya Rivers, and Louisiana's coastal wetlands. If significant, the latter source provides a possible link between Louisiana's high rates of coastal land loss and the large hypoxic zone observed along the coast during summer. Both of the latter DOM sources are independent of phytoplankton production stimulated by inputs of riverine inorganic nutrients.     

Ocean tides and resonance

Tidal currents and surface amplitudes are calculated globally for the dominating diurnal and semidiurnal constituents using an established tidal model under a range of altered bathymetry. The purpose is to evaluate if the well-known amplification of the global tides during the Last Glacial Maximum (LGM) is related to changed propagation properties for the tidal wave or to changed damping due to removal of shelf seas. The response of the tides and tidal dissipation to future sea-level rise is also discussed. The tides in the present and LGM oceans were simulated first, followed by runs where the present day bathymetry was used but the shelf seas removed by the introduction of vertical walls or where sea level is allowed to rise. Previously reported results regarding tidal amplitudes and dissipation rates are reproduced in the control runs. The runs without shelf seas show significantly enhanced tidal amplitudes in the North Atlantic, whereas sea-level rise of 5 m above present levels show a significant shift in the amphidromic points on a local and regional scale but had a limited effect on the open ocean tides. Simulations with very large sea-level rise show a significantly decreased global tidal dissipation, whereas experiments without friction in present-day shallow water display results similar to those with no shelf seas. The results all point towards changing damping properties due to the removal of shelf seas as being the mechanism behind the LGM amplification, and they imply the importance of implementing future sea-level changes properly in tidal simulations.     

The mineralogy,geochemistry and origin of Iherzolite inclusions in Victorian basanites

The mineralogy of Iherzolite inclusions in Victorian basanites indicates an upper mantle origin, but a range of temperatures from igneous to metamorphic (subsolidus) is indicated by the mineral compositions. Pyroxene textural features exhibit a slow cooling history consistent with isotopic evidence that these inclusions are accidental xenoliths. Clinopyroxene-rich inclusions (10–20 vol. % cpx) have higher abundances of Ca, Na, AI, Sc, V, Cr and heavy REE, lower Mg/Mg + Fe²⁺, lower Ni abundances, and more fayalitic olivines than clinopyroxene-poor inclusions (<5 vol. % cpx). A surprising result is that the refractory Mg-rich, clinopyroxenepoor inclusions contain the highest abundances of incompatible elements such as P, K, Ti, light REE, Th and U. We believe these inclusions are composed of two components (A and B). Component A determines the major element abundances and primary mineralogy of the inclusions. Based on Ni abundances component A is interpreted as a melting residue rather than a crystallization accumulate. Component B forms a small and varying portion of the inclusions, and it contributes P, K, Ti, light REE, Th and U. This component has the geochemical characteristics of a liquid formed in equilibrium with garnet.The following model is presented for the origin of Iherzolite inclusions. Residual Iherzolite (Component A) is left in the lithosphere after partial fusion, and it is later modified by a melt which has migrated to the top of the low velocity zone. Because this liquid (Component B) results from a small degree ( <6 per cent) of melting (probably limited by water abundance), and has equilibrated with garnet, it will be very enriched in P, K, Ti, light REE, Th and U. Subsequent cooling and recrystallization forms the present mineralogy. Finally, explosive volcanism, characteristic of silica-undersaturated magmas, incorporates mantle fragments (Iherzolite inclusions), and the increasing temperature and decreasing pressure during ascent causes incongruent melting of minor hydrous phases such as phlogopite and amphibole.     

Surface-layer scintillation measurements of daytime sensible heat and momentum fluxes

Line-averaged measurements of the structure parameter of refractive index (C _n ² ) were made using a semiconductor laser diode scintillometer above two markedly different surfaces during hours of positive net radiation. The underlying vegetation comprised in the first instance a horizontally homogeneous, pasture sward well-supplied with water, and in the second experiment, a sparse thyme canopy in a semi-arid environment. Atmospheric stability ranged between near neutral and strongly unstable (–20). The temperature structure parameterC _T ² computed from the optical measurements over four decades from 0.001 to 2 K² m^–2/3 agreed to within 5% of those determined from temperature spectra in the inertial sub-range of frequencies. Spectra were obtained from a single fine thermocouple sensor positioned near the midway position of the 100m optical path and at the beam propagation height (1.5m).With the inclusion of cup anemometer measurements, rule-of-thumb assumptions about surface roughness, and Monin-Obukhov similarity theory, path-averaged optical scintillations allow calculation of surface fluxes of sensible heat and momentum via a simple iterative procedure. Excellent agreement was obtained between these fluxes and those measured directly by eddy correlation. For sensible heat, agreement was on average close to perfect over a measured range of 0 to 500 W m^–2 with a residual standard deviation of 30 W m^–2. Friction velocities agreed within 2% over the range 0–0.9 m s^–1 (residual standard deviation of 0.06 m s^–1). The results markedly increase the range of validation obtained in previous field experiments. The potential of this scintillation technique and its theoretical foundation are briefly discussed.     

Comparing catchment hydrologic response to a regional storm using specific conductivity sensors

A better understanding of stormwater generation and solute sources is needed to improve the protection of aquatic ecosystems, infrastructure, and human health from large runoff events. Much of our understanding of water and solutes produced during stormflow comes from studies of individual, small headwater catchments. This study compared many different types of catchments during a single large event to help isolate landscape controls on streamwater and solute generation, including human‐impacted land cover. We used a distributed network of specific electrical conductivity sensors to trace storm response during the post‐tropical cyclone Sandy event of October 2012 at 29 catchments across the state of New Hampshire. A citizen science sensor network, Lotic Volunteer for Temperature, Electrical Conductivity, and Stage, provided a unique opportunity to investigate high‐temporal resolution stream behavior at a broad spatial scale. Three storm response metrics were analyzed in this study: (a) fraction of new water contributing to the hydrograph; (b) presence of first flush (mobilization of solutes during the beginning of the rain event); and (c) magnitude of first flush. We compared new water and first flush to 64 predictor attributes related to land cover, soil, topography, and precipitation. The new water fraction was positively correlated with low and medium intensity development in the catchment and riparian buffers and with the precipitation from a rain event 9 days prior to Sandy. The presence of first flush was most closely related (positively) to soil organic matter. Magnitude of first flush was not strongly related to any of the catchment variables. Our results highlight the potentially important role of human landscape modification in runoff generation at multiple spatial scales and the lack of a clear role in solute flushing. Further development of regional‐scale in situ sensor networks will provide better understanding of stormflow and solute generation across a wide range of landscape conditions.     

Experimental phase and melting relations of metapelite in the upper mantle: implications for the petrogenesis of intraplate magmas

We performed a series of piston-cylinder experiments on a synthetic pelite starting material over a pressure and temperature range of 3.0–5.0 GPa and 1,100–1,600°C, respectively, to examine the melting behaviour and phase relations of sedimentary rocks at upper mantle conditions. The anhydrous pelite solidus is between 1,150 and 1,200°C at 3.0 GPa and close to 1,250°C at 5.0 GPa, whereas the liquidus is likely to be at 1,600°C or higher at all investigated pressures, giving a large melting interval of over 400°C. The subsolidus paragenesis consists of quartz/coesite, feldspar, garnet, kyanite, rutile, ±clinopyroxene ±apatite. Feldspar, rutile and apatite are rapidly melted out above the solidus, whereas garnet and kyanite are stable to high melt fractions (>70%). Clinopyroxene stability increases with increasing pressure, and quartz/coesite is the sole liquidus phase at all pressures. Feldspars are relatively Na-rich [K/(K + Na) = 0.4–0.5] at 3.0 GPa, but are nearly pure K-feldspar at 5.0 GPa. Clinopyroxenes are jadeite and Ca-eskolaite rich, with jadeite contents increasing with pressure. All supersolidus experiments produced alkaline dacitic melts with relatively constant SiO₂ and Al₂O₃ contents. At 3.0 GPa, initial melting is controlled almost exclusively by feldspar and quartz, giving melts with K₂O/Na₂O ~1. At 4.0 and 5.0 GPa, low-fraction melting is controlled by jadeite-rich clinopyroxene and K-rich feldspar, which leads to compatible behaviour of Na and melts with K₂O/Na₂O ≫ 1. Our results indicate that sedimentary protoliths entrained in upwelling heterogeneous mantle domains may undergo melting at greater depths than mafic lithologies to produce ultrapotassic dacitic melts. Such melts are expected to react with and metasomatise the surrounding peridotite, which may subsequently undergo melting at shallower levels to produce compositionally distinct magma types. This scenario may account for many of the distinctive geochemical characteristics of EM-type ocean island magma suites. Moreover, unmelted or partially melted sedimentary rocks in the mantle may contribute to some seismic discontinuities that have been observed beneath intraplate and island-arc volcanic regions.