Rare earth element partitioning between clinopyroxene and silicate liquid at moderate to high pressure

Experimental determination of over seventy sets of clinopyroxene/silicate liquid (glass) partitition coefficients (D) for four rare earth elements (REE — La, Sm, Ho, Lu) in a range of REE-enriched natural rock compositions (basalt, basaltic andesite, andesite and rhyodacite) demonstrate a convex upward pattern, favouring the heavy REE (Ho, Lu) and markedly discriminating against the light REE (La). These patterns are consistent with previously documented clinopyroxene D values reported from natural phenocryst/matrix pairs and from experimental work using either REE-enriched compositions and electron microprobe analytical techniques (as in the present study) or natural or synthetic undoped compositions and mass spectrometric, ion probe or X-ray autoradiographic analytical techniques. However, the large data base in the present study allows evaluation of the effect of compositional and physical parameters on REE partitioning relationships. Considering D_Ho, it is shown that (1) D increases 6-fold with increasing SiO₂ content of the coexisting liquid from 50 to 70 wt% SiO₂ (2) D increases 4-fold with decreasing temperature from 1,120°C to 900° C (3) D increases 2-fold with increasing pressure from 2.5 to 20 kb. (4) D increases 2-fold fO₂ increases from approximately that of the MW buffer to the HM buffer (5) D remains unchanged within experimental error as the water content of the melt changes from 0.3 to 10% by weight H₂O.The absolute REE content of the clinopyroxene shows no consistent trend with temperature, but decreases slightly with increasing pressure, paralleling an increase in the jadeite component of the pyroxene. Thus the increase in D with increasing pressure is attributed to changes in the silicate liquid structure, which discriminate against accommodation of REE with increasing pressure. The clinopyroxene REE content increases with increasing fO₂, and in this case the increase in D with increasing fO₂ may be attributed mainly to this change in the clinopyroxene composition. Application of the present results to geochemical modelling allows a more appropriate choice of D values, according to the liquid composition and physical conditions applicable in the modelled system. They may also be used to evaluate cognate or xenocrystic relationships between clinopyroxene megacrysts and their host matrix.     

An evolutionary model of the western churchill province and western margin of the superior province in Canada and the North-Central United States

Regional-scale geophysical information, which includes aeromagnetic, gravity, seismic refraction, multi-channel seismic reflection and electromagnetic induction data, is used to extend our knowledge of the Canadian Shield beneath the Phanerozoic Williston basin of south-central Canada and the north-central United States. A new tectonic map based on this information shows the Proterozoic Flin Flon-Snow Lake and La Ronge-Lynn Lake volcanic island arcs and their associated fore-arc (Kisseynew belt) and back-arc (Reindeer-South Indian Lakes belt) basins wedged between the Archean Superior craton on the east and the Archean parts of the Churchill and Wyoming cratons on the west. Along the western margin of the Superior craton the Thompson nickel belt, including its extension southwards beneath the Williston basin, is interpreted to have been successively the site of continental rifting and rupturing, an evolving continental margin, a continent-volcanic island arc “suture” zone and eventually a continental-scale strike-slip fault. The North American Central Plains electrical conductivity anomaly and closely related seismic low-velocity zones are explained by the presence in the lower crust of buried slices of hydrated oceanic-type material, situated within the southward extension of the Reindeer-South Indian Lakes remnant back-arc basin and adjoining tectonic units. A new plate tectonic model is proposed for this region that involves the rifting and rupturing of the Archean continents and the opening and closing of one or more oceanic basins. This model is shown to be consistent with most of the geological, geophysical and geochronological data that pertains to the Proterozoic evolution of the exposed Shield and similar geophysical data and subsurface geochronological information from further south.     

Surface-layer scintillation measurements of daytime sensible heat and momentum fluxes

Line-averaged measurements of the structure parameter of refractive index (C _n ² ) were made using a semiconductor laser diode scintillometer above two markedly different surfaces during hours of positive net radiation. The underlying vegetation comprised in the first instance a horizontally homogeneous, pasture sward well-supplied with water, and in the second experiment, a sparse thyme canopy in a semi-arid environment. Atmospheric stability ranged between near neutral and strongly unstable (–20). The temperature structure parameterC _T ² computed from the optical measurements over four decades from 0.001 to 2 K² m^–2/3 agreed to within 5% of those determined from temperature spectra in the inertial sub-range of frequencies. Spectra were obtained from a single fine thermocouple sensor positioned near the midway position of the 100m optical path and at the beam propagation height (1.5m).With the inclusion of cup anemometer measurements, rule-of-thumb assumptions about surface roughness, and Monin-Obukhov similarity theory, path-averaged optical scintillations allow calculation of surface fluxes of sensible heat and momentum via a simple iterative procedure. Excellent agreement was obtained between these fluxes and those measured directly by eddy correlation. For sensible heat, agreement was on average close to perfect over a measured range of 0 to 500 W m^–2 with a residual standard deviation of 30 W m^–2. Friction velocities agreed within 2% over the range 0–0.9 m s^–1 (residual standard deviation of 0.06 m s^–1). The results markedly increase the range of validation obtained in previous field experiments. The potential of this scintillation technique and its theoretical foundation are briefly discussed.     

Derivation of potassic (shoshonitic) magmas by decompression melting of phlogopite+pargasite lherzolite

A model metasomatized lherzolite composition contains phlogopite and pargasite, together with olivine, orthopyroxene, clinopyroxene and spinel or garnet as subsolidus phases to 3 GPa. Previous works established that at ≥1.5 GPa, phlogopite is stable above the dehydration solidus, determined by the melting behaviour of pargasite and coexisting phases. At 2.8 GPa, melts with residual phlogopite+garnet lherzolite mineralogy at 1195 °C and with garnet lherzolite mineralogy at 1250 °C are both olivine nephelinite with K/Na (atomic)=0.51 and K/Na=0.65, respectively. Recent work shows that melting along the dehydration (fluid-absent) solidus of the phlogopite+pargasite lherzolite at pressures <1.5 GPa is very different with the presence of phlogopite, decreasing the solidus below that of pargasite lherzolite. At 1.0 GPa, both phlogopite and pargasite disappear at temperatures at or slightly above the solidus. The compositions of two melts at 1.0 GPa, 1075 °C (with different water contents), in equilibrium with residual spinel lherzolite mineralogy are silica-saturated trachyandesite (5% melt fraction, 3% H₂O) to silica-oversaturated basaltic andesite (8% melt fraction, 4.5% H₂O). Both compositions may be classified as ‘shoshonites’ on the basis of normative compositions, silica-saturation, and K/Na ratio. Decompression melting of metasomatized lithospheric lherzolite with minor phlogopite and pargasite may produce primary ‘shoshonitic’ magmas by dehydration melting at 1 GPa, 1050–1150 °C. Such magmas may be parental to Proterozoic batholithic syenites occurring in Brazil.     

Radar observations of asteroid 1 Ceres

Radar observations of asteroid 1 Ceres were made at a 12.6-cm wavelength from the Arecibo Observatory in March/April 1977. The measurements, made with a received circular polarization orthogonal to that transmitted, yield a radar cross section of (0.04 ± 0.01)πR², for R = 510 km. The corresponding radar reflectivity is less than that measured for any other celestial body. Within the accuracy of measurement, no significant variation of cross section with rotational phase is apparent. The shape of the power spectrum suggests that Ceres is rougher at the scale of the observing wavelength than the Moon and inner planets, but smoother than the outer three Galilean satellites.     

Closed-system geochemical recycling of crustal materials in alpine-type peridotite

We examined aluminous mafic rock (with or without corundum or sapphirine) alternating with peridotite from the Ronda peridotite massif, southern Spain. On the basis of petrographic characteristics, these mafic rocks show a decompression history from high pressure (P > 1.5 GPa), but on the basis of their geochemical characteristics, they are crystal accumulates of plagioclase, clinopyroxene, and olivine formed within the lower crust (P < 1 GPa). A complex evolution history, including higher-pressure recrystallization after initial formation as cumulate gabbros at lower-pressure conditions, is proposed. The aluminous mafic rocks and their peridotite hosts are inferred to be recycled crustal materials now observed as centimeter-scale layered components in alpine-type peridotite. The rocks retained their original cumulate compositions; that is, their compositions were not affected by melting and metasomatic modifications during subduction, intense deformation within the upper mantle, and upwelling to the surface.     

Karst unit mapping using geographic information system technology,Mower County,Minnesota, USA

Mower County is in southeastern Minnesota in an area underlain by sedimentary bedrock. These rocks are karsted Middle Devonian and Middle Ordovician limestone and dolomite. The karst features of the county were inventoried. These features include sinkholes, disappearing streams, caves, dry valleys, and springs. Previous karst mapping efforts for other counties in Minnesota have produced sinkhole probability maps and a springshed map. In Mower County, we have developed a new type of karst map using a geographic information system (GIS) to produce a karst unit map. Karst units are discrete three-dimensional bodies in which solution of the bedrock has resulted in the integration of surface water and groundwater. The field mapping and hydrologic investigations were done with conventional methods. The karst unit delineation was done using GIS technology, which allowed us to examine the county's karst using two-dimensional and three-dimensional views. Many different overlays of the karst elements were combined to better understand the landscape dynamics. Ultimately, it was the overlay of the karst features, hydrologic information, and depth-to-bedrock mapping on a shaded relief landscape morphology map which allowed us to best delineate the individual karst units.     

Magnetic fields over active tectonic zones in ocean

The aim of our work is to estimate the electromagnetic effects that can be detected in the submarine zones with hydrothermal activity. It is known that meso-scale flows appear in the regions over underwater volcanoes or hot rocks. Their origin is connected with heat flux and hot jets released from underwater volcanoes or faults in a sea bottom. Values of mean velocities and turbulent velocities in plumes were estimated. Quasiconstant magnetic fields induced by a hot jet and a vortex over a plume top are about 1–40 nT. Variable magnetic fields are about 0.1–1 nT. These magnetic disturbances in the sea medium create an additional natural electromagnetic background that must be considered when making detailed magnetic surveys.