Silicic peralkaline volcanic rocks of the afar depression (Ethiopia)

Three main types of recent volcanism may be distinguished in the Afar Depression: 1) oceanic volcanism of the axial ranges; 2) volcanism along the margins where an attenuated sialic crust probably occurs; 3) mainly fissural volcanism of Central-Southern Afar, with associated central volcanoes, similar as a whole to the volcanism of the Ethiopian Rift Valley. Peralkaline silicic volcanic rocks are found in all the three groups but showing some different characteristics which seem related to their geological location and which probably reflect different sources. Moreover emplacement of peralkaline granitic bodies, associated with volcanics of the same composition, marks the first stage of formation of the Afar Depression, in the Early Miocene. Axial Ranges: Erta’Ale and Boina volcanic ranges indicate that peralkaline rocks are the final liquids produced by fractionation of basalt in shallow magma chambers of central volcanoes. The parental magma is a transitional type of basalt with a mildly alkalic affinity, which fractionated under lowpH₂O-pO₂ conditions. Transition to peralkaline liquids is realized without passing a «true» trachytic (low silica) stage. The first peralkaline liquid is a low silica comendite and evidence exists that «plagioclase effect» was active in determining the first peralkalinity. Within the peralkaline field a fractionation mainly controlled by alkali feldspar progressively increases the peralkalinity and silica oversaturation of residual liquids (transition from comendites to pantellerites). The most peralkaline pantellerites of Boina are produced by fractionation of an alkali feldspar of constant composition (Ab_65–68 Or_35–32) suggesting that these liquids lie on a «low temperature zone» of the peralkaline oversaturated system. Marginal Units: On the borders of the depression peralkaline silicics are found in volcanic massifs mainly made of metaluminous silicic products. Petrology and geochemistry suggest a complex origin. Crystal fractionation, contamination with sialic crust and chemical changes related to a volatile rich phase, all these processes probably played a role in the genesis of these peralkaline silicic rocks. Central-Southern Afar Fissural Volcanism: Mildly alkaline basalts are associated with peralkaline and metaluminous silicics; intermediate rocks are very scanty. Fractionation from deep seated magmatic bodies with selective eruptivity and partial melting at depth of associated basalts or of a common source material are possible genetic mechanisms.     

Magmatic changes during the stabilisation of a cordilleran fold belt: the Late Carboniferous–Triassic igneous history of eastern New South Wales, Australia

In a 60 Ma interval between the Late Carboniferous and the Late Permian, the magmatic arc associated with the cordilleran-type New England Fold Belt in northeast New South Wales shifted eastward and changed in trend from north–northwest to north. The eastern margin of the earlier (Devonian–Late Carboniferous) arc is marked by a sequence of calcalkaline lava flows, tuffs and coarse volcaniclastic sedimentary rocks preserved in the west of the Fold Belt. The younger arc (Late Permian–Triassic) is marked by I-type calcalkaline granitoids and comagmatic volcanic rocks emplaced mostly in the earlier forearc, but extending into the southern Sydney Basin, in the former backarc region. The growth of the younger arc was accompanied by widespread compressional deformation that stabilised the New England Fold Belt. During the transitional interval, two suites of S-type granitoids were emplaced, the Hillgrove Suite at about 305 Ma during an episode of compressive deformation and regional metamorphism, and the Bundarra Suite at about 280 Ma, during the later stages of an extensional episode. Isotopic and REE data indicate that both suites resulted from the partial melting of young silicic sedimentary rocks, probably part of the Carboniferous accretionary subduction complex, with heat supplied by the rise of asthenospheric material. Both mafic and silicic volcanic activity were widespread within and behind the Fold Belt from the onset of rifting (ca. 295 Ma) until the reestablishment of the arc. These volcanic rocks range in composition from MORB-like to calcalkaline and alkaline. The termination of the earlier arc, and the subsequent widespread and diverse igneous activity are considered to have resulted from the shallow breakoff of the downgoing plate, which allowed the rise of asthenosphere through a widening lithospheric gap. In this setting, division of the igneous rocks into pre-, syn-, and post-collisional groups is of limited value.     

Chemical and isotopic signatures of the basement rocks from the Campi Flegrei geothermal field (Naples, southern Italy): inferences about the origin and evolution of its hydrothermal fluids

The Campi Flegrei (Naples, Campanian Plain, southern Italy) geothermal system is hosted by Quaternary volcanic rocks erupted before, during and after the formation of the caldera that represents one of the major structural features in the Neapolitan area. The volcanic products rest on a Mesozoic carbonate basement, cropping out north, east and south of the area. Chemical (major, minor and trace elements) and stable isotope (C, H, O) analyses were conducted on drill-core samples recovered from geothermal wells MF-1, MF-5, SV-1 and SV-3, at depths of ˜ 1100 to 2900 m. The study was complemented by petrographic and SEM examination of thin sections. The water which feeds the system is both marine and meteoric in origin. Mineral zonation typical of a high-temperature geothermal system exists in all the geothermal wells; measured temperatures in wells are as high as ˜ 400 °C. The chemical composition of the waters suggests the existence of two reservoirs: a shallow reservoir (depth < 2000 m) fed by seawater that boiled at 320 °C and became progressively diluted by steam-heated local meteoric water during its ascent; and a deeper reservoir (depth > 2000 m) of hypersaline water. The drill-cores are mainly hydrothermally altered volcanics of trachy-latitic affinity, but some altered pelites and limestones are also present. Published Na, Mg and K concentrations of selected geothermal waters indicate that the hydrothermal fluids are in equilibrium with their host rocks, with respect to K-feldspar, albite, sericite and chlorite. The measured δ¹⁸O_(SMOW) values of rocks range from +4.3 to + 16.5%. The measured δD_(SMOW) values range from − 79 to − 46%. The calculated isotopic composition of the fluids at equilibrium with the samples vary from + 1 to + 8.3%. δ¹⁸O and from − 52 to + 1%. δD. The estimated isotopic composition of the waters at equilibrium with the studied samples confirmed the existence of two distinct fluid types circulating in the geothermal system. The shallower has a marine water signature, while the deeper water has a signature consistent both with magmatic and meteoric origins. In the latter case, the recharge of this aquifer likely occurs at the outcrop of the Mesozoic Limestones surrounding the Campanian Plain; after infiltration, the water percolates through evaporitic layers, becoming hypersaline and D-depleted.     

Phlegraean Fields 1982–1984: Brief chronicle of a volcano emergency in a densely populated area

The essential features of the ongoing potential pre-eruptive crisis at the Phlegraean Fields begun in August 1982 are summarized and the main problems faced by scientists responsible of volcanic hazards evaluation in such a densely populated area are discussed.     

Hazardous gas emissions from the flanks of the quiescent Colli Albani volcano (Rome,Italy)

Gas hazard was evaluated in the three most important cold gas emission zones on the flanks of the quiescent Colli Albani volcano. These zones are located above structural highs of the buried carbonate basement which represents the main regional aquifer and the main reservoir for gas rising from depth. All extensional faults affecting the limestone reservoir represent leaking pathways along which gas rises to the surface and locally accumulates in shallow permeable horizons forming pressurized pockets that may produce gas blowout when reached by wells. The gas, mainly composed of CO₂ (>90 vol.%), contains appreciable quantities of H₂S (0.35–6 vol.%), and both represent a potentially high local hazard. Both gases are denser than air and accumulate near ground where they may reach hazardous concentrations, and lethal accidents frequently occur to animals watering at local ponds. In order to evaluate the rate of degassing and the related hazard, CO₂ and H₂S diffuse soil flux surveys have been repeatedly carried out using an accumulation chamber. The viscous gas flux of some important discrete emissions has been evaluated and the CO₂ and H₂S air concentration measured by portable devices and by Tunable Diode Laser profiles. The minimum potential lethal concentration of the two gases (250 ppm for H₂S and 8 vol.% for CO₂) is 320 times higher for CO₂, whereas the CO₂/H₂S concentration ratio in the emitted natural gas is significantly lower (15–159). This explains why H₂S reaches hazardous, even lethal, concentrations more frequently than CO₂. A relevant hazard exists for both gases in the depressed zones (channels, excavations) particularly in the non-windy early hours of the day.     

Statistical Analysis of Landslide Events in Central America and their Run-out Distance

Statistical analyses of landslide deposits from similar areas provide information on dynamics and rheology, and are the basis for empirical relationships for the prediction of future events. In Central America landslides represent an important threat in both volcanic and non-volcanic areas. Data, mainly from 348 landslides in Nicaragua, and 19 in other Central American countries have been analyzed to describe landslide characteristics and to search for possible correlations and empirical relationships. The mobility of a landslide, expressed as the ratio between height of fall (H) and run-out distance (L) as a function of the volume and height of fall; and the relationship between the height of fall and run-out distance were studied for rock falls, slides, debris flows and debris avalanches. The data show differences in run-out distance and landslide mobility among different types of landslides and between debris flows in volcanic and non-volcanic areas. The new Central American data add to and seem consistent with data published from other regions. Studies combining field observations and empirical relationships with laboratory studies and numerical simulations will help in the development of more reliable empirical equations for the prediction of landslide run-out, with applications to hazard zonation and design of optimal risk mitigation measures.