Estimated N2O and CO2 Emissions as Influenced by Agricultural Practices in Canada

The Denitrification-Decompostion (DNDC) model was used to estimate the impact of change in management practices on N₂O emissions in seven major soil regions in Canada, for the period 1970 to 2029. Conversion of cultivated land to permanent grassland would result in the greatest reduction in N₂O emissions, particularly in eastern Canada wherethe model estimated about 60% less N₂O emissions for thisconversion. About 33% less N₂O emissions were predicted for a changefrom conventional tillage to no-tillage in western Canada, however, a slight increase in N₂O emissions was predicted for eastern Canada. GreaterN₂O emissions in eastern Canada associated with the adoption of no-tillage were attributed to higher soil moisture causing denitrification, whereas the lower emissions in western Canada were attributed to less decomposition of soil organic matter in no-till versus conventional tilled soil. Elimination of summer fallow in a crop rotation resulted in a 9% decrease in N₂O emissions, with substantial emissions occurringduring the wetter fallow years when N had accumulated. Increasing N-fertilizer application rates by 50% increased average emissions by 32%,while a 50% decrease of N-fertilizer application decreased emissions by16%. In general, a small increase in N₂O emissions was predicted when N-fertilizer was applied in the fall rather than in the spring. Previous research on CO₂ emissions with the CENTURY model (Smith et al.,2001) allowed the quantification of the combined change in N₂O andCO₂ emissions in CO₂ equivalents for a wide range of managementpractices in the seven major soil regions in Canada. The management practices that have the greatest potential to reduce the combined N₂O andCO₂ emissions are conversion from conventional tillage to permanent grassland, reduced tillage, and reduction of summer fallow. The estimated net greenhouse gas (GHG) emission reduction when changing from cultivated land to permanent grassland ranged from 0.97 (Brown Chernozem) to 4.24 MgCO₂ equiv. ha^–1 y^–1 (BlackChernozem) for the seven soil regions examined. When changing from conventional tillage to no-tillage the net GHG emission reduction ranged from 0.33 (Brown Chernozem) to 0.80 Mg CO₂ equiv. ha^–1 y^–1 (Dark GrayLuvisol). Elimination of fallow in the crop rotation lead to an estimated net GHG emission reduction of 0.43 (Brown Chernozem) to 0.80 Mg CO₂ equiv.ha^–1 y^–1 (Dark Brown Chernozem). The addition of 50% more or 50% less N-fertilizer both resulted in slight increases in combined CO₂ and N₂O emissions. There was a tradeoff in GHG flux with greaterN₂O emissions and a comparable increase in carbon storage when 50% more N-fertilizer was added. The results from this work indicate that conversion of cultivated land to grassland, the conversion from conventional tillage to no-tillage, and the reduction of summerallow in crop rotations could substantially increase C sequestration and decrease net GHG emissions. Based on these results a simple scaling-up scenario to derive the possible impacts on Canada's Kyoto commitment has been calculated.     

Analytical methods Of assessing the image quality associated with digital and photographic imaging systems

The introduction of digital cameras for aerial survey photography and use of scanners with processed aerial film present a number of technical questions concerning the way photography is to be acquired in the future. Among the questions to be addressed are the comparative metric properties of images acquired by each system and the associated image quality characteristics. The new digital camera systems will require very careful appraisal, using well-established methods of assessing metric quality already available to survey organisations. The questions concerning image quality are more difficult to answer, as they require very specialised instrumentation if measurements are to be made directly in practice. Over the course of the past several decades a more analytical approach to assessing image quality has emerged, and one that may be used by individuals. The method is particularly effective where information on the micro-image characteristics of products is made available by the manufacturers concerned. An outline is given of some considerations that need to be taken into account when using an analytical approach, with references given for further reading.     

Aeolian abrasion and modes of fine particle production from natural red dune sands: an experimental study

A series of experiments was conducted to determine the potential for aeolian abrasion of natural dune sands to produce fine particles (< 125 µm) by (1) the release of resident fines; (2) spalling, chipping and breakage of particles; and (3) the removal of grain surface coatings. Parent samples were obtained from the surfaces of four active continental dunes and abraded using a glass ‘test tube’ chamber for up to 120 h. The fine particles produced by this abrasion process were trapped at varying time intervals and subject to detailed particle‐size analyses using a Coulter Multisizer. The abrasion of untreated parent samples produced fine particles in one of two main size classes, < 10 µm and > 50 µm, but when the parent sample was sieved to exclude particles < 250 µm, relatively more material in the range 10–50 µm was produced. For unsieved parent samples, the size range associated with the dominant mode varied according to the length of the abrasion time. The coarsest mode (> 63 µm) was dominant during the first 16 h of abrasion, then became less significant and is thought to be associated with the release of resident fines into suspension. The finest mode (< 10 µm) was absent or very weak during the first 16 h of abrasion, then became more significant and, in some instances, dominated the distribution as abrasion continued. Removal of grain surface coatings is the main source of fine material < 10 µm, and this may be a significant source of fine material in areas where sands are dominated by subrounded and rounded particles. By comparison with previous studies of aeolian particle abrasion, these natural dune sands produced very low quantities of fine material (by weight), but their spatial extent makes them potentially a significant source of dust‐sized particles at the global scale.     

Magnetic fabrics and rock magnetism of Proterozoic dike swarm from the southern São Francisco Craton, Minas Gerais State, Brazil

Magnetic fabric and rock magnetism studies were performed on 32 mafic dikes of a Proterozoic dike swarm from the southern São Francisco Craton (SFC; Minas Gerais State, SE Brazil). Magnetic anisotropies were determined by applying anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of remanent magnetization (ARM). The latter was performed imposing both anhysteretic (total (AAR) and partial pAAR)) and isothermal remanence magnetizations (AIRM). Partial anhysteretic remanence anisotropy was performed based on remanent coercivity spectra from a pilot specimen of each site. In most sites, AMS is dominantly carried by ferromagnetic minerals, however, in some sites, the paramagnetic contribution exceeds 70% of bulk susceptibility. Rock magnetism and thin section analysis allow classifying the dikes as non-hydrothermalized and hydrothermalized. Magnetic measurement shows that the mean magnetic susceptibility is usually lower than 5×10⁻³ (SI). Ti-poor titanomagnetites up to pure magnetite pseudo-single-domain (PSD) grain sizes carry the majority of magnetic fabrics for non-hydrothermalized dikes whereas coarse to fine grained Ti-poor titanomagnetites carry the majority of magnetic fabrics for hydrothermalized dikes.Three primary AMS fabrics are recognized which are coaxial with ARM fabric, except for two dikes, from both non-hydrothermalized and hydrothermalized dikes. Normal AMS fabric surprisingly is not dominant (31%). The parallelism between AMS, pAAR_0–30, pAAR_30–60 and pAAR_60–90 fabrics in the hydrothermalized dikes indicates that magnetic grains formed due to late-stage crystallization or to remobilization of iron oxides due to hydrothermal alteration after dike emplacement have acquired a mimetic fabric coaxial with the primary fabric given by coarse-grained early crystallized Ti-poor titanomagnetites. This fabric is interpreted as magma flow in which the analysis of K_max inclination permitted the inference that the dikes were fed by horizontal or subhorizontal fluxes (K_max<30°). Intermediate AMS fabric is the most important (41%) in the investigated swarm. It is interpreted as due to vertical compaction of a static magma column with the minimum stress along the dike strike. ARM determinations for these sites also remained intermediate except for two dikes. In one of them, AIRM fabric resulted in normal AMS fabric while for the other AAR fabric resulted in inverse AMS fabric. A combination of AMS and ARM fabrics suggest that magmatic fabric for both dikes were overprinted by some late local event, probably related to Brasiliano orogenic processes after dike emplacement. InverseInverse AMS fabric is a minority (four dikes). ARM determinations also remained inverse suggesting a primary origin for inverse AMS fabric.     

Rainfall induced debris flows in pyroclastic deposits, Campania (southern Italy)

A combination of empirical and physically based hydrological models has been used to analyze historical data on rainfall and debris-flow occurrence in western Campania, to examine the correlation between rainfall and debris-flow events.

Rainfall data from major storms recorded in recent decades in western Campania were compiled, including daily series from several rain gauges located inside landslide areas, supplemented by hourly rainfall data from some of the principal storms.

A two-phase approach is proposed. During phase 1, soil moisture levels have been modelled as the hydrological balance between precipitation and evapotranspiration, on a daily scale, using the method of Thornthwaite [Geograph. Rev. 38 (1948) 55].

Phase 2 is related to the accumulation of surplus moisture from intense rainfall, leading to the development of positive pore pressures. These interactions take place on an hourly time scale by the “leaky barrel” (LB) model described by Wilson and Wiezoreck [Env. Eng. Geoscience, 1 (1995) 11]. In combination with hourly rainfall records, the LB model has been used to compare hydrological effects of different storms. The critical level of retained rain water has been fixed by the timing of debris-flow activity, related to recorded storm events.

New rainfall intensity–duration thresholds for debris-flow initiation in western Campania are proposed. These thresholds are related to individual rain gauge and assume a previously satisfied field capacity condition. The new thresholds are somewhat higher than those plotted by previous authors, but are thought to be more accurate and thus need less conservatism.     

Structural variations in derivatives of the bacteriochlorophylls of Chlorobiaceae: impact of stratigraphic resolution on depth profiles as revealed by methanolysis

Bacteriochlorophylls c and d, recovered from two sedimentary sequences, were converted to bacteriophaeophorbide methyl esters by methanolysis and analysed by atmospheric pressure chemical ionisation liquid chromatography-multistage mass spectrometry (APCI LC-MSⁿ). The distributions in both settings, a moderately consolidated sediment from Kirisjes Pond, Antarctica, and in a finely laminated microbial mat from Les Salines de la Trinitat, Spain, show significant variations within a narrow depth interval. The overall bacteriophaeophorbide c to d ratios in the two sediments are different, as are the ratios of particular C-3¹ diastereoisomers, indicating distinct differences between the bacterial communities that contributed to each sediment. Furthermore, a shift towards more extensive alkylation in homologues within each sediment is consistent either with changing environmental conditions in the depositional environments, or development-related changes in the structure of the bacterial community, leading to increased competition for light or nutrients.     

Further examples of ventifacts and unusual patterned ground from the Falkland Islands, South Atlantic

Abstract Examples of ventifacts and forms of unusual patterned ground that differ in situation, characteristics and/or origin to types reported previously are described from the Falkland Islands, South Atlantic. The ventifacts, represented by clasts projecting from an eroding tillite shore platform, have been grooved by the passage of windblown sand. The patterned ground forms comprise stone polygons on clay loam regolith, stone polygons on peat, peat‐filled desiccation cracks on peat, and clusters of on‐edge clasts (stone packings) on a gravel beach. Aeolian transport of particles is considered responsible for the infill of the polygonal cracks. The clusters of on‐edge clasts are thought to have developed as a result of wave action, in particular backwash and/or undertow. Although these features occupy small surface areas they provide useful information about local geomorphic processes and testify to the marked diversity of such features in nature.     

Testing a statistical curve‐fitting procedure for quantifying sediment populations within multi‐modal particle‐size distributions

This paper describes a series of tests designed to evaluate the capacity of a personal computer (PC) based statistical curve‐fitting program called MIX to quantify composite populations within multi‐modal particle‐size distributions. Three natural soil samples were analysed by a Coulter Multisizer, and their particle‐size distributions analysed using MIX software to identify the modes, standard deviations and proportions of their composite populations. The particle‐size distributions of the three natural soil samples were then numerically combined in equal proportions using a spreadsheet program to create synthetic particle‐size distributions of known populations. MIX was then tested on the synthetic particle‐size distributions to see if the modes and proportions it identified were similar to those modes and proportions known to characterize the synthetic particle‐size distributions. The main outcome is that MIX can very accurately describe the modal particle size and proportions of the major composite populations within a particle‐size distribution. However MIX has difficulty in identifying small populations (those contributing <10 per cent of a total particle‐size distribution), particularly when they are located in the central sections of particle‐size distributions, overlain by larger populations, or when positioned in the fine tails of distributions. Despite these minor shortcomings, MIX is a valuable tool for the examination and interpretation of particle‐size data. Copyright © 2005 John Wiley & Sons, Ltd.