On the kinetics of textural equilibration in forsterite marbles

In the aureole of the Beinn an Dubhaich granite, Skye, the minimum observed median forsterite-calcite-calcite dihedral angle varies from 110° at the olivinein isograd to about 165° (the equilibrium value) at the granite-limestone contact. Laboratory experiments were performed to investigate the kinetics of this textural change. It was found that the rate of change of the forsterite-calcite-calcite dihedral angle followed approximately first-order kinetics with an activation energy of 48±4 kJ mol^-1 for fluid-present conditions, and 90 ±4 kJ mol^-1 for fluid-absent conditions. Scanning ion imaging demonstrated that, at least in the early stages of textural change, solution-reprecipitation of the calcite was the rate determining step in the fluid-present runs. The latter result and the value of the activation energy are both consistent with the activation energy found by previous authors for (albeit zeroth order) silicate-aqueous solution solution-reprecipitation reactions. The value of activation energy for the dry data does not correspond to those for either grain boundary or volume diffusion of oxygen or magnesium in forsterite. The mechanism for textural equilibration in the fluid-absent runs is uncertain. Application of the experimentally-derived rate equation to the Beinn an Dubhaich marbles gave activation energies higher than those obtained experimentally. It is concluded from consideration of grain growth effects that activation energies derived from the Beinn an Dubhaich marbles probably reflect textural equilibration under predominantly fluid-absent conditions.     

The characterisation and origin of graphite in cratonic lithospheric mantle: a petrological carbon isotope and Raman spectroscopic study

Graphite-bearing peridotites, pyroxenites and eclogite xenoliths from the Kaapvaal craton of southern Africa and the Siberian craton, Russia, have been studied with the aim of: 1) better characterising the abundance and distribution of elemental carbon in the shallow continental lithospheric mantle; (2) determining the isotopic composition of the graphite; (3) testing for significant metastability of graphite in mantle rocks using mineral thermobarometry. Graphite crystals in peridotie, pyroxenite and eclogite xenoliths have X-ray diffraction patterns and Raman spectra characteristic of highly crystalline graphite of high-temperature origin and are interpreted to have crystallised within the mantle. Thermobarometry on the graphite-peridotite assemblages using a variety of element partitions and formulations yield estimated equilibration conditions that plot at lower temperatures and pressures than diamondiferous assemblages. Moreover, estimated pressures and temperatures for the graphite-peridotites fall almost exclusively within the experimentally determined graphite stability field and thus we find no evidence for substantial graphite metastability. The carbon isotopic composition of graphite in peridotites from this and other studies varies from δ¹³ C_PDB = ? 12.3 to ? ?3.8%o with a mean of-6.7‰, σ=2.1 (n=22) and a mode between-7 and-6‰. This mean is within one standard deviation of the-4‰ mean displayed by diamonds from peridotite xenoliths, and is identical to that of diamonds containing peridotite-suite inclusions. The carbon isotope range of graphite and diamonds in peridotites is more restricted than that observed for either phase in eclogites or pyroxenites. The isotopic range displayed by peridotite-suite graphite and diamond encompasses the carbon isotope range observed in mid-ocean-ridge-basalt (MORB) glasses and ocean-island basalts (OIB). Similarity between the isotopic compositions of carbon associated with cratonic peridotites and the carbon (as CO₂) in oceanic magmas (MORB/OIB) indicates that the source of the fluids that deposited carbon, as graphite or diamond, in catonic peridotites lies within the convecting mantle, below the lithosphere. Textural observations provide evidence that some of graphite in cratonic peridotites is of sub-solidus metasomatic origin, probably deposited from a cooling C-H-O fluid phase permeating the lithosphere along fractures. Macrocrystalline graphite of primary appearance has not been found in mantle xenoliths from kimberlitic or basaltic rocks erupted away from cratonic areas. Hence, graphite in mantle-derived xenoliths appears to be restricted to Archaean cratons and occurs exclusively in low-temperature, coarse peridotites thought to be characteristic of the lithospheric mantle. The tectonic association of graphite within the mantle is very similar to that of diamond. It is unlikely that this restricted occurrence is due solely to unique conditions of oxygen fugacity in the cratonic lithospheric mantle because some peridotite xenoliths from off-craton localities are as reduced as those from within cratons. Radiogenic isotope systematics of peridotite-suite diamond inclusions suggest that diamond crystallisation was not directly related to the melting events that formed lithospheric peridotites. However, some diamond (and graphite?) crystallisation in southern Africa occurred within the time span associated with the stabilisation of the lithospheric mantle (Pearson et al. 1993). The nature of the process causing localisation of carbon in cratonic mantle roots is not yet clearly understood.     

Sources of magnetic susceptibility in a slate

Magnetic susceptibility and its anisotropy in the Borrowdale Volcanic slates at Kentmere in the English Lake District are attributed largely to preferred orientation of a paramagnetic chlorite of diabantite-ripidolite composition. In units of 10⁻⁶ cgs/g, the principal susceptibilities for the slates are 9.61; 9.42; 8.69 and for the chlorite grains the minimum anisotropy is represented by principal susceptibilities of 11.57; 11.22 and 9.15. Because the magnetic susceptibility is carried by a tightly packed, matrix-forming mineral that has recrystallised during the deformation it is not possible to imagine simple grain rotation as being responsible for the anisotropy of susceptibility.     

Community structure and productivity of the Cornwallis Estuary, Minas Basin

Preliminary results of a seasonal study of the pelagic community at a station on the outer edge of the Cornwallis Estuary suggest that the seasonal variation in plankton community respiration (PCR) is related to organic inputs from nearby salt marshes. Annual phytoplankton production is low (<30 g C m⁻² y⁻¹) and exhibits a seasonal cycle very different from PCR. There is no indication that resuspension of benthic diatoms is an important energy input to the pelagic system. PCR, however, is quite high and exhibits a seasonal trend similar to the export of salt marsh detritus. Zooplankton densities (5–200 l⁻¹) and biomass (<0.4 g m⁻³) appear to be much greater than could be supported by phytoplankton alone. The Cornwallis Estuary may be an estuarine system exhibiting a net export of organic matter to nearby offshore waters.     

Strontium-calcium ratios in Cenozoic planktonic foraminifera

The $\text{Sr}\text{Ca}$ ratio and other parameters have been measured in fossil planktonic foraminifera from the Atlantic and Pacific Ocean basins in order to evaluate the $\text{Sr}\text{Ca}$ ratio of seawater during the last 75 million years. Results on well-preserved samples indicate that the ratio has increased to its present value by 10–15% during the Cenozoic, and that minima occurred between 55-45 Ma and 10-5 Ma, when the ratio was 15–25% less than at present. The long-term increase may reflect either decreasing deposition of aragonite with a high $\text{Sr}\text{Ca}$ ratio in shallow seas, or decreasing seafloor spreading rates and consequently decreasing hydrothermal supply of Ca during the Cenozoic. Other geologic evidence suggests that the Eocene minimum (near 50 Ma) may have resulted from increased aragonite sedimentation, while the Late Miocene minimum (between 10-5 Ma) may have been caused by an increased rate of seawater-basalt exchange when seafloor spreading rates increased on the East Pacific Rise near 10 Ma.     

Transition from basin-plain to shelf deposits in the carboniferous flysch of Southern Morocco

In the Jebilet Palaeozoic inlier, 20 km north of Marrakech, there are extensive exposures of Carboniferous flysch deposits. Although there are some structural complications due to over-riding nappes with associated chaotic breccias, one clearly unbroken succession from basin-plain turbidites to shallow-marine deposits can be examined. The succession is more than 2 km thick and is dated as Upper Viscan in the uppermost part.The lowermost unit of B- and C-based turbidites shows no sequential organisation and is interpreted as a typical basin-plain association. Above this are similar turbidites arranged in thickening-upward sequences that may represent outer-fan or base-of-slope deposits. Succeeding these are thin-bedded turbidites with interbedded units formed by mass movement that represent a slope deposit. The overlying lenticular-bedded facies resembles previously described overflow deposits of submarine-fan channels, but is here interpreted as comprising storm-generated deposits on the outer shelf/upper slope. These deposits are genetically linked with the overlying parallel-laminated sandstones with irregular-rippled tops for which a storm-surge origin is suggested. The upper part of the succession shows cross-bedded, oolitic, bioclastic, sandy limestones with bipolar current structures sandwiched between low-energy siltstones containing thin-graded silt/sand beds. These are collectively interpreted as shelf deposits that formed under different depths due to transgressive-regressive events.The sequence differs from many described in the literature in that there is an absence of most submarine-fan facies. Locally a NNE-SSW basin strike is proposed with a basin margin to the ESE, but there is at present little control on regional palaeogeography.     

The seismicity of Kohistan, Pakistan: Source studies of the Hamran (1972.9.3), Darel (1981.9.12) and Patan (1974.12.28) earthquakes

Long period body waves are examined to show that the Hamran (1972.9.3), Darel (1981.9.12) and Patan (1974.12.28) earthquakes in Kohistan had focal depths of about 8–10 km. All involved high angle reverse faulting (thrusting) and had seismic moments of about 2.2 to 2.7·10²⁵ dyne cm. These shallow depths contrast with the deeper hypocentres found in the Hindu Kush and northeast Karakoram to the north and in Hazara to the south. The Hamran and Patan shocks were assigned depths of 45 km by the ISC, indicating that even well-recorded events in this region may have focal depths in error by 30 km