Detrital thermochronologic record of burial heating and sediment recycling in the Magallanes foreland basin,Patagonian Andes

The Patagonian Magallanes retroarc foreland basin affords an excellent case study of sediment burial recycling within a thrust belt setting. We report combined detrital zircon U–Pb geochronology and (U–Th)/He thermochronology data and thermal modelling results that confirm delivery of both rapidly cooled, first‐cycle volcanogenic sediments from the Patagonian magmatic arc and recycled sediment from deeply buried and exhumed Cretaceous foredeep strata to the Cenozoic depocentre of the Patagonian Magallanes basin. We have quantified the magnitude of Eocene heating with thermal models that simultaneously forward model detrital zircon (U–Th)/He dates for best‐fit thermal histories. Our results indicate that 54–45 Ma burial of the Maastrichtian Dorotea Formation produced 164–180 °C conditions and heating to within the zircon He partial retention zone. Such deep burial is unusual for Andean foreland basins and may have resulted from combined effects of high basal heat flow and high sediment accumulation within a rapidly subsiding foredeep that was floored by basement weakened by previous Late Jurassic rifting. In this interpretation, Cenozoic thrust‐related deformation deeply eroded the Dorotea Formation from ca. 5 km burial depths and may be responsible for the development of a basin‐wide Palaeogene unconformity. Results from the Cenozoic Río Turbio and Santa Cruz formations confirm that they contain both Cenozoic first‐cycle zircon from the Patagonian magmatic arc and highly outgassed zircon recycled from older basin strata that experienced burial histories similar to those of the Dorotea Formation.     

Statistical approaches to the discrimination of mantle- and crust-derived low-Cr garnets using major and trace element data

Diamond exploration focuses on geochemical analysis of indicator minerals that are more abundant than diamond itself. Among such indicators, low-Cr (Cr₂O₃ < 1 wt%) garnets from mantle eclogites are problematic since they overlap compositionally with many lower-crust-derived garnets also transported by kimberlite. Misclassification of these garnets may create “false positive” mantle signatures and possible misdirection of exploration efforts. Statistical solutions using major elements in low-Cr garnet (Hardman et al. in J Geochem Explor 186:24–35, 2018) provide improved error rates for the discrimination of low-Cr crustal and mantle garnets recovered from kimberlite. In this study we analysed a large suite of garnets (n = 571) from both crustal and mantle settings, already characterised for major elements, for a wide range of trace elements by laser ablation inductively-coupled plasma mass spectrometry and use these new data along with literature data (n = 169) to evaluate the effectiveness of adding trace elements to garnet-based diamond exploration programs. A new garnet classification scheme, initially using a major-element based filter, uses garnet Sr contents and Eu anomalies to help identify low-Cr garnets that are misclassified using major element methods. Combined with existing methods, our new trace element classifiers offer improvement in classification error rates for low-Cr, crustal and mantle garnets to as low as 4.7% for calibration data.

     

Further observations of quasars in ESO/SERC field 927

We present the spectra and redshifts of 62 quasars, from observations made with the Cerro Tololo Inter-American Observatory (CTIO) 4-m Blanco Telescope. These quasars form part of a total sample of 118 (with 56 having been published previously), which is being used for analysis of structure in the early universe. Quasars of particular interest are noted, including eight broad absorption line (BAL) quasars and two quasars with unusual emission spectra. Finally, we include a short summary of the present status of the large quasar group (LQG) that was discovered by Clowes & Campusano from the earlier observations. The quasars are from an area ∼25.3 deg² of ESO/SERC field 927, which is centred at (1950) 10^h40^m00^s, 05°00'00'.     

Induced Magnetization of Magnetite-titanomagnetite in Alternating Fields Ranging from 400 A/m to 80,000 A/m; Low-field Susceptibility (100 – 400 A/m) and Beyond

For remanence-bearing minerals (RBM) such as magnetite-titanomagnetite, susceptibility to induced magnetism (M) measured in alternating fields (H _AC ) is field-dependent. However, for fields ≤ 400 A/m, measured in an AC induction coil instrument (at 19,100 Hz), susceptibility k ₀ = M/H _AC is sufficiently linear to provide a reproducible rock (or mineral) magnetic characteristic and its anisotropy may be related to arrangements of minerals in rock, or for single mineral grains to their crystalline or shape anisotropy. For any remanence-bearing mineral at higher fields k _HF (= M/H _AC ) is not constant and the term susceptibility is not normally used. This study bridges the responses between traditional low-field susceptibility measurements and those due to high applied fields, for example when studying hysteresis or saturation magnetization of RBM. Where |k _HF | is measured in alternating fields that peak significantly above 400 A/m the M(H _AC ) relation is forced to follow a hysteresis loop in which |k _HF | > k ₀ for small |H _AC | and where |k _HF | decreases to zero for very large fields that achieve saturation magnetization. Hysteresis nonlinearity is due to remanence acquired with one field direction requiring a reverse field for its cancellation. We investigate the transition from initial, traditional “low-field” susceptibility (k ₀ ) measurements at 60 A/m, through 24 different fields from 400 A/m to 40,000 A/m (for very high k ₀ to 80,000 A/m). This reveals M(H _AC ) dependence beyond from conventional k ₀ through the range of hysteresis behavior in fields equal to and exceeding that required to achieve saturation magnetization (M _S ). We show k _HF increases with peak H _AC until the peak field is slightly less than saturation magnetization in natural rock samples rich in magnetite (TM₀ = Fe₃O₄) and TM₆₀ (Fe_2.4Ti_0.6O₄). All sample suites predominantly contain multidomain grains with subordinate pseudo-single domain and single-domain grains. k/k ₀ increases by ≤ 5% for fields up to 2 kA/m. Above 4 kA/m k/ k ₀ increases steeply and peaks, usually between 24 kA/m and 30 kA/m where all grains magnetic moments are activated by H _AC since this exceeds the coercive force of most grains. For higher peak H _AC , k/k ₀ declines sharply as increased H _AC values more effectively flip M with each field-direction switch, leading to the low gradient at distal portions of the hysteresis loop. For M₀-TM₆₀ bearing rocks, susceptibility peaks for fields ~12 kA/m and for magnetite rich rocks up to 24 kA/m. These values are approximately 10% of saturation magnetizations (M _S ) reported for the pure minerals from hysteresis DC field measurements. Both the field at peak k/k ₀ and the peak k/k ₀ value appear to be controlled by the dominant domain structure; multidomain behavior has larger k/k ₀ peaks at lower H _AC . Stacked k/k ₀ versus H _AC curves for each sample suite (n = 12 to n = 39) were successfully characterized at the 95% level by a polynomial fit that requires the cubic form k/k ₀ = a + bH + cH ² + dH ³. Thus, for most M-TM bearing rocks, susceptibility and anisotropy of susceptibility (AMS) measurements made on different instruments would be sufficiently precise for most geological applications, if peak alternating fields are ≤700 A/m.     

The stabilizing effect of viscosity on magnetic wind flows from accretion discs

Magnetically channelled winds are believed to be a feature of most accretion discs. It has been shown that such flows can remove significant amounts of angular momentum from the disc and make a major contribution to driving the inflow. For a suitable range of poloidal magnetic field bending, only a small fraction of the disc mass is lost in the wind flow, so most material reaches the inner region of the disc. However, discs driven purely by such a process are prone to a field-bending instability which can lead to runaway mass loss. It is shown here that a small amount of disc viscosity can quench such an instability and allow steady disc-wind models to be constructed. The effects of perturbations to the coupling between the radial and vertical structures are allowed for, with the thermal balance having particular relevance. Runaway increases in field bending are prevented by increases in the disc temperature and magnetic diffusivity mainly caused by viscous dissipation.     

Modelling of shallow landslides with machine learning algorithms

This paper introduces three machine learning(ML)algorithms,the‘ensemble'Random Forest(RF),the‘ensemble'Gradient Boosted Regression Tree(GBRT)and the Multi Layer Perceptron neural network(MLP)and applies them to the spatial modelling of shallow landslides near Kvam in Norway.In the development of the ML models,a total of 11 significant landslide controlling factors were selected.The controlling factors relate to the geomorphology,geology,geo-environment and anthropogenic effects:slope angle,aspect,plan curvature,profile curvature,flow accumulation,flow direction,distance to rivers,water content,saturation,rainfall and distance to roads.It is observed that slope angle was the most significant controlling factor in the ML analyses.The performance of the three ML models was evaluated quantitatively based on the Receiver Operating Characteristic(ROC)analysis.The results show that the‘ensemble'GBRT machine learning model yielded the most promising results for the spatial prediction of shallow landslides,with a 95%probability of landslide detection and 87%prediction efficiency.     

Isolated olivines in the Yamato 82042 CM2 chondrite: The tracing of major condensation events in the solar nebula

Abstract— Yamato 82042 is an unusual CM2 chondrite consisting mainly of phyllosilicates, a few olivines and carbonates, very minor sulphides and trace metal. Olivine occurs: (1) as isolated grains dispersed in the phyllosilicate matrix, (2) as constituents of mineral aggregates or accretionary fragments associated with abundant phyllosilicates and minor sulphides, and (3) as objects which resemble barred olivine chondrules also associated with phyllosilicates. Olivine, from all occurrences, ranges in composition from 0.26 to 22.6 weight % FeO, but generally contains less than 1.25 wt.% FeO. Minor element contents, particularly Ca, Al, and Cr, are relatively high and are generally correlated, as reported for olivines in other carbonaceous chondrites. However, we report here uncorrected trends for the same minor elements which occur in distinct areas (volumes) within the same olivines. These compositional trends may be due to condensation of olivine from a vapor of non-solar composition and partial mobilization of Ca during later annealing. If this is the case, the data may be used to trace changes in the Ca/Al ratio of the parent medium during the formation of these olivines, provided that it is possible to distinguish the effects of any post-formation annealing which could have redistributed the minor elements. Some isolated olivines show distinctive minor element zoning which severely limits the possibility of any post-formation redistribution of these elements. Accordingly, these isolated olivines indeed retain evidence of early condensation processes in the solar nebula, though non-classic conditions are implied for their formation.     

Use of an Artificial Sweetener to Identify Sources of Groundwater Nitrate Contamination

The artificial sweetener acesulfame (ACE) is a potentially useful tracer of waste water contamination in groundwater. In this study, ACE concentrations were measured in waste water and impacted groundwater at 12 septic system sites in Ontario, Canada. All samples of septic tank effluent (n = 37) had ACE >6 µg/L, all samples of groundwater from the proximal plume zones (n = 93) had ACE >1 µg/L and, almost all samples from the distal plume zones had ACE >2 µg/L. Mean mass ratios of total inorganic nitrogen/ACE at the 12 sites ranged from 680 to 3500 for the tank and proximal plume samples. At five sites, decreasing ratio values in the distal zones indicated nitrogen attenuation. These ratios were applied to three aquifers in Canada that are nitrate‐stressed and an urban stream where septic systems are present nearby to estimate the amount of waste water nitrate contamination. At the three aquifer locations that are agricultural, low ACE values (<0.02‐0.15 µg/L) indicated that waste water contributed <15% of the nitrate in most samples. In groundwater discharging to the urban stream, much higher ACE values (0.2‐11 µg/L) indicated that waste water was the likely source of >50% of the nitrate in most samples. This study confirms that ACE is a powerful tracer and demonstrates its use as a diagnostic tool for establishing whether waste water is a significant contributor to groundwater contamination or not.