Water‐quality response to a high‐elevation wildfire in the Colorado Front Range

Water quality of the Big Thompson River in the Front Range of Colorado was studied for 2 years following a high‐elevation wildfire that started in October 2012 and burned 15% of the watershed. A combination of fixed‐interval sampling and continuous water‐quality monitors was used to examine the timing and magnitude of water‐quality changes caused by the wildfire. Prefire water quality was well characterized because the site has been monitored at least monthly since the early 2000s. Major ions and nitrate showed the largest changes in concentrations; major ion increases were greatest in the first postfire snowmelt period, but nitrate increases were greatest in the second snowmelt period. The delay in nitrate release until the second snowmelt season likely reflected a combination of factors including fire timing, hydrologic regime, and rates of nitrogen transformations. Despite the small size of the fire, annual yields of dissolved constituents from the watershed increased 20–52% in the first 2 years following the fire. Turbidity data from the continuous sensor indicated high‐intensity summer rain storms had a much greater effect on sediment transport compared to snowmelt. High‐frequency sensor data also revealed that weekly sampling missed the concentration peak during snowmelt and short‐duration spikes during rain events, underscoring the challenge of characterizing postfire water‐quality response with fixed‐interval sampling. Copyright © 2015 John Wiley & Sons, Ltd.     

Characterising modal metasomatic processes in young continental lithospheric mantle: a microsampling isotopic and trace element study on xenoliths from the Middle Atlas Mountains,Morocco

Clinopyroxene is a major host for lithophile elements in the mantle lithosphere, and therefore it is critical whether we are to understand the constraints that this mineral puts on mantle evolution and melt generation. This study presents a detailed in situ trace element and Sr isotope study of clinopyroxene, amphibole and melt from two spinel lherzolites from the Middle Atlas Mountains, Morocco. The results show that there is limited, but discernable, Sr isotopic variation between clinopyroxene crystals within these xenoliths [⁸⁷Sr/⁸⁶Sr ranging from 0.703416 (±11 2SE) to 0.703681 (±12 2SE)]. Trace element patterns show similar interelement fractionation with LREE enrichment, but there is a considerable range in terms of elemental concentration (e.g. over 100 ppm in Sr concentrations). Observed modal clinopyroxene is far more abundant than that predicted from estimates of melt depletion. This along with isotope and trace element variability found in these xenoliths supports a multistage metasomatic process in which clinopyroxene and amphibole are recent secondary additions to the lithospheric mantle. Elemental systematics indicate that the metasomatic mineral assemblage has most recently equilibrated with a carbonatitic melt prior to inclusion in the host basalt. The clinopyroxene from this study is typical of global off-craton clinopyroxene in terms of Sr isotope composition, suggesting that the majority of clinopyroxene in off-craton settings may have a recent metasomatic origin. These findings indicate that caution is required when using peridotite xenoliths to estimate the degree of elemental enrichment in the subcontinental lithosphere.     

Lead isotope systematics of ore systems of the Macquarie Arc — Implications for arc substrate

The Macquarie Arc of New South Wales hosts several major Au and Cu deposits. We present new Pb isotope results for Cadia, the Copper Hill, Little Copper Hill and Cowal deposits, along with data from the CSIRO database. The results generally plot close to established mantle growth curves and are similar to oceanic basalts. Data for individual deposits mostly have Pb model ages consistent with independent age constraints on mineralization. Intrusions associated with the Early Silurian mineralization at Cadia and Goonumbla have narrow and distinct Pb isotope signatures that we interpret to be the result of partial melting of already LILE-enriched mantle-like sources. The data suggest that deposits of the Macquarie Arc derived Pb from one or more long-lived mantle-like Pb isotope reservoirs without significant contributions of crustal Pb prior to the Benambran Orogeny.Data for the Copper Hill deposits includes unradiogenic, possibly old Pb and supports previous workers who suggested that old MORB-like basalts may occur at depth in the area. The Peak Hill deposit has the most unradiogenic signature and has the lowest ²⁰⁸Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb. These signatures closely match Cambrian MORB-like basalts in the Koonenberry Belt and are unlike Cambrian mafic rocks in Victoria. Similar rocks could form part of the substrate to other parts of the Macquarie Arc.     

Analytical Constraints on the Measurement of the Sulfur Isotopic Composition and Concentration of Trace Sulfate in Phosphorites: Implications for Sulfur Isotope Studies of Carbonate and Phosphate Rocks

The aim of this study was to evaluate the existing methods for extracting trace sulfate from francolite and measuring its concentration and sulfur isotope composition. Phosphatic rocks were chemically and thermally treated to remove non‐structural SO₄^2? in francolite, which would otherwise be inadvertently included in geochemical analyses of the structurally‐bound sulfate. Acetic acid (10% v/v) proved to be effective in removing calcite, dolomite and ankerite without affecting francolite. To remove all ‘easily’ soluble sulfates, such as Ca‐sulfates and adsorbed sulfate, rinsing with 10% v/v NaCl had to be repeated several times for most samples. For subsequent S isotope determination sample combustion at 600 °C was found to be an efficient way to remove non‐francolite S‐bearing phases. From a number of SO₄^2? detection methods tested, ICP‐AES proved to be the most accurate. For francolite‐sulfate recovery, our recommended protocol involved repeated rinsing of powdered phosphorites with 10% NaCl as well as NaOCl, and testing of the filtrate for SO₄^2? in each wash. If only S isotope compositions are needed, combustion at 600 °C with a subsequent de‐ionised water rinse could be undertaken instead of repeated NaOCl rinsing for studies of both francolite and carbonate. Re‐analysis of previously published data, using the new protocol, provided evidence that the use of this protocol considerably improves data quality.     

Early fracturing and impact residue emplacement: Can modelling help to predict their location in major craters?

Abstract— Understanding the nature and composition of larger extraterrestrial bodies that may collide with the Earth is important. One source of information lies in the record of ancient impact craters, some of which have yielded chemical information as to the impacting body. Many deeply eroded craters have no remaining melt sheet or ejecta yet may contain impactor residue within basement fractures. The emplacement mechanism for fractionated siderophile residues is likely to be gaseous, although, melt droplets and some solid materials may survive. For breccia‐ and melt‐filled fractures to contain extraterrestrial material, they must form very early in the impact process. Most current numerical models do not dwell on the formation and location of early major fractures, although, fractures in and around small craters on brittle glass exposed to hypervelocity impact in low Earth orbit have been successfully simulated. Modelling of fracture development associated with larger craters may help locate impact residues and test the models themselves.     

Constraints on Jupiters from observations of Galactic bulge microlensing events during 2000

We present observations of eight Galactic bulge microlensing events taken with the 1.0-m Jacobus Kapteyn Telescope (JKT) on La Palma during 2000 June and July. The JKT observing schedule was optimized using a prioritizing algorithm to automatically update the target list. For most of these events we have sampled the light curves at times where no information was available from the OGLE alert team. We assume a point-source point-lens (PSPL) model and perform a maximum likelihood fit to both our data and the OGLE data to constrain the event parameters of the fit. We then refit the data assuming a binary lens and proceed to calculate the probability of detecting planets with mass ratio   q = 10⁻³  . We have seen no clear signatures of planetary deviations on any of the eight events and we quantify constraints on the presence of planetary companions to the lensing stars. For two well-observed events, 2000BUL31 and 2000BUL33, our detection probabilities peak at ∼30 and ∼20 per cent respectively for   q = 10⁻³  and   a ∼ R _E  for a  Δχ²  threshold value of 60.     

Keck AO observations of Io in and out of eclipse

We present adaptive optics (AO) observations of Io taken with the W.M. Keck II telescope on 18 December 2001 (UT) before the satellite went into eclipse, and while it was in Jupiter's shadow. Making these kind of Io-in-eclipse observations, as well as the associated data reduction and analysis are challenging; hence one focus of the paper is to explain the methods and tools used for these data sets. For the sunlit images Io itself was used as the wavefront reference source, while nearby Ganymede was used as reference ‘star’ when Io was in eclipse. Observations were obtained in K′-, L′-, and M-bands. The sunlit images have been deconvolved using MISTRAL. The Io-in-eclipse data were deconvolved with IDAC and MISTRAL. The former gives better results, both in absolute photometry and in matching the original images. We determined the flux densities of the hot spots from the original Io-in-eclipse data with StarFinder, as well as from the deconvolved images by integrating the intensity over the relevant areas. We determined the highly anisoplanatic PSF via a FFT method from the original data, and used this in StarFinder and as a starting PSF for IDAC and MISTRAL. We derived temperatures and areal coverage of all 19 spots detected in both K′- and L′-band images of Io-in-eclipse. We also determined temperatures and areal coverage of the hot spots visible on the L′- and M-band images of sunlit Io. Most volcanoes contain a compact hot ‘core’ (?10 km² at 600-800 K) within a larger area at lower temperatures (e.g., ∼10²-10⁴ km² at 300-500 K). The total heat flow contributed by these active volcanoes is 0.2 W m⁻², ∼8% of the average global heat flow measured at 5-20 μm by Veeder et al. [J. Geophys. Res. 99 (1994) 17095].     

Statistical approaches to the discrimination of mantle- and crust-derived low-Cr garnets using major and trace element data

Diamond exploration focuses on geochemical analysis of indicator minerals that are more abundant than diamond itself. Among such indicators, low-Cr (Cr₂O₃ < 1 wt%) garnets from mantle eclogites are problematic since they overlap compositionally with many lower-crust-derived garnets also transported by kimberlite. Misclassification of these garnets may create “false positive” mantle signatures and possible misdirection of exploration efforts. Statistical solutions using major elements in low-Cr garnet (Hardman et al. in J Geochem Explor 186:24–35, 2018) provide improved error rates for the discrimination of low-Cr crustal and mantle garnets recovered from kimberlite. In this study we analysed a large suite of garnets (n = 571) from both crustal and mantle settings, already characterised for major elements, for a wide range of trace elements by laser ablation inductively-coupled plasma mass spectrometry and use these new data along with literature data (n = 169) to evaluate the effectiveness of adding trace elements to garnet-based diamond exploration programs. A new garnet classification scheme, initially using a major-element based filter, uses garnet Sr contents and Eu anomalies to help identify low-Cr garnets that are misclassified using major element methods. Combined with existing methods, our new trace element classifiers offer improvement in classification error rates for low-Cr, crustal and mantle garnets to as low as 4.7% for calibration data.