Geochemical and oxygen isotope perspective of a new R chondrite Dhofar 1671: Affinity with ordinary chondrites

Dhofar 1671 is a relatively new meteorite that previous studies suggest belongs to the Rumuruti chondrite class. Major and REE compositions are generally in agreement with average values of the R chondrites (RCs). Moderately volatile elements such as Se and Zn abundances are lower than the R chondrite values that are similar to those in ordinary chondrites (OCs). Porphyritic olivine pyroxene (POP), radial pyroxene (RP), and barred olivine (BO) chondrules are embedded in a proportionately equal volume of matrix, one of the characteristic features of RCs. Microprobe analyses demonstrate compositional zoning in chondrule and matrix olivines showing Fa‐poor interior and Fa‐rich outer zones. Precise oxygen isotope data for chondrules and matrix obtained by laser‐assisted fluorination show a genetic isotopic relationship between OCs and RCs. On the basis of our data, we propose a strong affinity between these groups and suggest that OC chondrule precursors could have interacted with a ¹⁷O‐rich matrix to form RC chondrules (i.e., ?¹⁷O shifts from ~1‰ to ~3‰). These interactions could have occurred at the same time as “exotic” clasts in brecciated samples formed such as NWA 10214 (LL3–6), Parnallee (LL3), PCA91241 (R3.8–6), and Dhofar 1671 (R3.6). We also infer that the source of the oxidation and ¹⁷O enrichment is the matrix, which may have been enriched in ¹⁷O‐rich water. The abundance of matrix in RCs relative to OCs, ensured that these rocks would be apparently more oxidized and appreciably ¹⁷O‐enriched. In situ analysis of Dhofar 1671 is recommended to further strengthen the link between OCs and RCs.     

Backward automatic calibration for three-dimensional landslide models

Back-analysis is broadly used for approaching geotechnical problems when monitoring data are available and information about the soils properties is of poor quality.For landslide stability assessment back-analysis calibration is usually carried out by time consuming trial-and-error procedure.This paper presents a new automatic Decision Support System that supports the selection of the soil parameters for three-dimensional models of landslides based on monitoring data.The method considering a pool of possible solutions,generated through permutation of soil parameters,selects the best ten configurations that are more congruent with the measured displacements.This reduces the operator biases while on the other hand allows the operator to control each step of the computation.The final selection of the preferred solution among the ten best-fitting solutions is carried out by an operator.The operator control is necessary as he may include in the final decision process all the qualitative elements that cannot be included in a qualitative analysis but nevertheless characterize a landslide dynamic as a whole epistemological subject,for example on the base of geomorphological evidence.A landslide located in Northeast Italy has been selected as example for showing the system potentiality.The proposed method is straightforward,scalable and robust and could be useful for researchers and practitioners.     

The multiple chronological techniques applied to the Lake Suigetsu SG06 sediment core,central Japan

The varved sediment of Lake Suigetsu (central Japan) provides a valuable opportunity to obtain high‐resolution, multi‐proxy palaeoenvironmental data across the last glacial/interglacial cycle. In order to maximize the potential of this archive, a well‐constrained chronology is required. This paper outlines the multiple geochronological techniques being applied – namely varve counting, radiocarbon dating, tephrochronology (including argon–argon dating) and optically stimulated luminescence (OSL) – and the approaches by which these techniques are being integrated to form a single, coherent, robust chronology. Importantly, we also describe here the linkage of the floating Lake Suigetsu (SG06) varve chronology and the absolute (IntCal09 tree‐ring) time scale, as derived using radiocarbon data from the uppermost (non‐varved) portion of the core. This tie‐point, defined as a distinct (flood) marker horizon in SG06 (event layer B‐07–08 at 1397.4 cm composite depth), is thus derived to be 11 255 to 11 222 IntCal09 cal. years BP (68.2% probability range).     

Performing a new regional geography

In this introduction to the Special Issue ‘Practising a New Regional Geography in Northland’, we call for a new regional geography. We use the experience of a field course to reflect upon the opportunities and challenges associated with doing ‘regional geography’ in the regions, a subdiscipline that has in recent decades been pushed into the backwaters of the discipline. We reinterpret the maxim ‘geography is what geographers do’ in a new way that emphasises pedagogy and research practice. The case of Northland and helping our students to learn experientially about community and environment under the rubric of sustainability allows us to argue the case for a reinterpretation of regional geography in these terms. We position the contributions in this Special Issue in terms of our call.     

A conduit-related genesis of the Lengshuiqing intrusive assemblage (Sichuan,SW China)

Lengshuiqing is part of the late Proterozoic igneous province from the western margin of the Yangtze craton. The Lengshuiqing area comprises five ultramafic–mafic intrusions, emplaced in the late Proterozoic Yanbian Group. The intrusions from Lengshuiqing contain cumulate ultramafic zones (peridotite + olivine pyroxenite), with cumulus olivine and Cr-spinel, and intercumulus pyroxenes, hornblende, phlogopite and plagioclase. Ni–Cu ore (pyrrhotite + pentlandite + chalcopyrite) is hosted in the ultramafic zones. Olivine-free diorite–quartz diorite ± gabbro and granite zones commonly occur above the ultramafic rocks. The genesis of the intrusions (conduit-related accumulation or differentiation from stagnant magma) was investigated. The amount of sulphides in the intrusions from Lengshuiqing is one order of magnitude bigger than the sulphides that can be dissolved by a volume of mafic magma similar with the volume of the intrusions. Most intrusions from Lengshuiqing have bulk composition (peridotite ± diorite ± granite) more magnesian (MgO = 21–22%; Mg# > 78) than the deduced composition of their parental magma (MgO = 9–11%; Mg# = 64–67). This indicates the accumulation of sulphide and mafic silicates from a volume of magma much bigger than the volume of the intrusions, which can be explained by the fractionation from magma ascending through the intrusions to shallower depths. A continuous supply and vent of magma is consistent with the lack of chilled margins, the melting of the wall rocks and the generation of high-temperature mineral assemblages (K-feldspar, diopside, and sillimanite) in the Yanbian Group. The intrusions from Lengshuiqing are seen as microchambers on conduits draining olivine-, Cr-spinel-, and sulphide-bearing mafic magma from a larger staging chamber.     

Natural aggregates in the performance and durability of concrete: chemical characteristics

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.     

A MEG study of the olivine and spinel forms of Mg2SiO4

In this paper we present a theoretical investigation of the structures and relative stability of the olivine and spinel phases of Mg₂SiO₄. We use both a purely ionic model, based on the Modified Electron Gas (MEG) model of intermolecular forces, and a bond polarization model, developed for low pressure silica phases, to investigate the role of covalency in these compounds. The standard MEG ionic model gives adequate structural results for the two phases but incorrectly predicts the spinel phase to be more stable at zero pressure. This is mainly because the ionic modeling of Mg₂SiO₄ only accounts for 95 percent of the lattice energy. The remainder can be attributed to covalency and many-body effects. An extension of the MEG ionic model using “many-body” pair potentials corrects the phase stability error, but predicts structures which are in poorer agreement with experiment than the standard ionic approach. In addition, calculations using these many-body pair potentials can only account for 10 percent of the missing lattice energy. This model predicts an olivine-spinel phase transition of 8 GPa, below the experimental value of 20 GPa. Therefore, in order to understand more fully the stability of these structures we must consider polarization. A two-shell bond polarization model enhances the stability of both structures, with the olivine structure being stabilized more. This model predicts a phase transition at about 80 GPa, well above the observed value. Also, the olivine and spinel structures calculated with this approach are in poorer agreement with experiment than the ionic model. Therefore, based on our investigations, to properly model covalency in Mg₂SiO₄, a treatment more sophisticated than the two-shell model is needed.     

Spongy pahoehoe in Hawaii: A study of vesicle-distribution patterns in basalt and their significance

A well-defined pahoehoe lava type that is very common medially and distally in Hawaii is characterized by a high concentration and fairly uniform distribution of spherical or near-spherical vesicles. Measurements of vesicle sizes and concentrations have been made on ten of these spongy pahoehoe lava flow-units. The vesicles increase in size toward the middle, accompanied by a moderate increase in lava porosity. The close approach to bilateral symmetry on either side of the horizontal median plane and the common occurrence of a median gas blister shows that no significant upward movement of vesicles occurred, suggesting that the lava possessed a yield strength and was more or less static. Olivine phenocrysts when present are, however, concentrated in the lower half of the same flow units, showing that the lava previously lacked a significant yield strength. The vesicles are regarded as early, inherited from the vent, but the size characteristics of the vesicle population are a late-formed feature. Vesicles grew in static lava mostly by coalescence, and it is postulated that coalescence was promoted by the presence of abundant diktytaxitic voids which punctured the walls of contiguous vesicles. Zones in which the vesicle concentration is lower and the vesicles are larger and strongly deformed interrupt the symmetry of some spongy pahoehoe units, and gas blisters higher than the median plane occur in many examples. These zones are interpreted to result from late-stage shearing, and point to a mechanism by which vesicles may be eliminated from a lava.