Experimental petrology of alkalic lavas: constraints on cotectics of multiple saturation in natural basic liquids

Experimental study of natural alkalic lava compositions at low pressures (pO₂QFM) reveals that crystallization of primitive lavas often occurs in the sequence olivine, plagioclase, clinopyroxene, nepheline without obvious reaction relation. Pseudoternary liquidus projections of multiply saturated liquids coexisting with plagioclase (±olivine±clinopyroxene±nepheline) have been prepared to facilitate graphical analysis of the evolution of lava compositions during hypabyssal cooling. Use of (TiAl₂)(MgSi₂)_–1 and Fe³⁺ (Al)_–1 exchange components is a key aspect of the projection procedure which is succesful in reducing a wide range of compositions to a systematic graphical representation. These projections, and the experiments on which they are based, show that low pressure fractionation plays a significant role in the petrogenesis of many alkalic lava suites from both continental and oceanic settings. However, the role of polybaric fractionation is more evident in the major element chemistry of these lava suites than in many tholeiitic suites of comparable extent. For example, the lavas of Karisimbi, East Africa, show a range of compositions reflecting a polybaric petrogenesis from primitive picrites at 1360° C/18 kb and leading to advanced low pressure differentiates. Evolved leucite-bearing potassic members of this and other suites may be treated in a nepheline-diopside-kspar (+olivine+leucite) projection. Compositional curvature on the plagioclase+clinopyroxene+olivine+leucite cotectic offers a mechanism to explain resorption of plagioclase in alkalic groundmass assemblages and the incompatibility of albite and leucite. This projection is useful for evaluating the extent of assimilation of the alkalic portions of crustal granulites. Assimilation appears to have played some role in the advanced differentiates from Karisimbi.     

Production and pelagic dissolution of biogenic silica in the Southern Ocean

Vertical distributions of particulate silica, and of production and dissolution rates of biogenic silica, were determined on two N-S transects across the Pacific sector of the Antarctic Circumpolar Current during the austral spring of 1978. Particulate silica profiles showed elevated levels in surface water and near the bottom, with low (35–110 nmol Si · 1^?1) and vertically uniform values through the intervening water column. Both the particulate silica content of the upper 200 m and the production rate of biogenic silica in the photic zone increased from north to south, reaching their highest values near the edge of the receding pack ice. A significant, but variable, fraction (18–58%) of the biogenic silica produced in the surface layer was redissolving in the upper 90–98 m. Net production of biogenic silica in the surface layer (production minus dissolution) was proceeding at a mean rate of ca. 2 mmol Si · m^?2 · day^?1. This is ca. 4 times greater than the most recent estimate of the mean accumulation rate of siliceous sediments beneath the ACC. We estimate, based on mass balance, that the mean dissolution rate of biogenic silica in subsurface water column in the Southern Ocean is 1.2–2.9 mmol Si · m^?2 · day^?1.     

40Ar39Ar and KAr dating of altered glassy volcanic rocks: the Dabi Volcanics,P.N.G.

KAr and ${}^{40}\text{Ar}{}^{39}\text{Ar}$ ages have been determined for altered submarine tholeiitic and boninite (high-Mg andesite) lavas from the Dabi Volcanics, Cape Vogel Peninsula, Papua New Guinea. ${}^{40}\text{Ar}{}^{39}\text{Ar}$ whole rock total fusion and plateau ages identify a Late Paleocene age for the tholeiitic lavas (58.9 ± 1.1 Ma) and also for the boninitic lavas (58.8 ± 0.8 Ma). Apparent KAr ages for the same samples range from 27.2 ± 0.7 to 63.9 ± 4.5 Ma, and young KAr ages for glassy boninites are probably due to variable radiogenic ⁴⁰Ar (⁴⁰Ar¹) loss. These new ages effectively reconcile previously ambiguous age data for the Dabi Volcanics and indicate contemporaneous tholeiitic and boninitic volcanism occurring in southeast PNG during the Late Paleocene.Smectites, developed as alteration products after glass in oceanic lavas commonly do not retain ³⁹Ar during or subsequent to irradiation, but in some cases may contain ⁴⁰Ar1. In the absence of other factors modifying K and Ar contents, samples which have not lost ⁴⁰Ar¹ from smectite and suffer ³⁹Ar loss only, are interpreted to have been altered immediately subsequent to the crystallization of the lava; whereas samples which have lost ⁴⁰Ar¹ as well as ³⁹Ar may be the result of either recent alteration, or of continuous ⁴⁰Ar¹ loss since the time of crystallization.     

Quantimet image analysis of soil pore geometry: Comparison with tracer breakthrough curves

The relationships between two-dimensional image analysis of soil thin-sections and tracer breakthrough curves has been studied for a silty clay loam brown earth soil under saturated conditions. Initial tracer breakthrough is well in advance of one pore volume. Discrepancies between Quantimet image analysis and breakthrough curve characterization were related by inference to the role of infrequently occurring macropores not necessarily sampled on the two-dimensional images. A fundamental difficulty found in the use of image analysis is the uncertain nature of the relationship between the two-dimensional image and the three-dimensional pore system. Caution is needed in using Quantimet image analysis to describe gross properties of the three-dimensional pore system.     

Tectonic systems and the deposition of iron-formation

The iron-formation group of chemically precipitated cherty iron-rich sediments ranges in age from Early Precambrian to Recent and is composed of a variety of lithological facies. Iron-formations are classified as Lake Superior and Algoma types to emphasize the contrasting conditions in the spectrum of sedimentary-tectonic environments in which they formed. Thick stratigraphic units of Lake Superior type iron-formation, which form the most extensive iron ranges of the world, are part of sedimentary-tectonic systems that developed along the margins of cratons or continental platforms and were deposited over extended periods of time under relatively stable tectonic conditions. The Algoma type iron-formations were deposited with volcanic rocks and greywacke in various tectonic-volcanic systems, formed under more dynamic tectonic conditions, but are otherwise comparable to present day spreading ridges on the ocean floor. The thick sequences of Lake Superior type iron-formation deposited between 2.7 and 2.0 Ga form part of major sedimentary-tectonic systems that extended along the margins of continents. Direct biogenic factors and the composition of the atmosphere probably had only limited influence on the precipitation of these chemical sediments.     

Chironomid-based paleosalinity records in southern British Columbia, Canada: a comparison of transfer functions

Chironomid remains from Big Lake, British Columbia were analysed and paleosalinities were estimated using a pre-existing transfer function and several developed using new regression methods. A two component partial-least-squares model (PLS-2) had the highest coefficient of determination (R² _(Jackknifed) = 0.75) and lowest root-mean-squared error-of-prediction (RMSEP). As compared to the pre-existing model, it was also less sensitive to the influence of rare taxa. Nevertheless, the marginally larger R² _(Jackknifed) and lower RMSEP do not clearly identify a single best model. The models were applied to Big, Mahoney and Kilpoola lakes, revealing the sensitivity of paleosalinity inferences to model selection. A synopsis of chironomid-based paleosalinities in British Columbia and their correspondence with other paleoclimatic data are presented and discussed.     

Carbon reduction, 'the public' and renewable energy: engaging with socio-technical configurations

In the context of challenging targets for renewable energy generation, this paper draws out social implications of moves towards low carbon energy systems. As renewable energy develops as a heterogeneous category, many potential forms of social relation between 'publics' and technologies are emerging. Utilising perspectives from science and technology studies, we outline five modes in which renewable energy has been implemented in the UK and how these involve different configurations of technology and social organisation. We argue that a multiplicity of roles for 'the public' are implicated across this increasingly complex landscape, cutting across established categories and raising questions of meaning, differentiation, interrelation and access. Policy assumptions and conceptions are questioned, highlighting that dominant characterisations of public roles have been part of a concentration on particular socio-technical pathways to the exclusion of others.     

Geomorphic constraints on the active tectonics of southern Taiwan

Taiwan is a region of rapid active tectonics, yet the study of the tectonic processes that shape the interior of the island is difficult due to the high rates of erosion and dense vegetation. We use digital topography to look for indications of active deformation preserved in the local geomorphology. In particular, anomalies in the regional pattern of drainage are used to infer zones of enhanced tectonic activity. The apparent anticlockwise rotation of major river systems in plan view indicates the presence of a diffuse zone of left-lateral shear running down the southeastern side of Taiwan. Asymmetries in the catchments of individual drainage basins show the influence of varying rates of uplift across southern Taiwan, with the most rapid uplift close to Taitung at the indentation point of the Luzon arc with the Chinese continental margin. Our interpretations, though based predominantly on remote-sensing observations, are consistent with the available field evidence. This study demonstrates the usefulness of drainage basins as tectonic markers in the quantification of regional strain and uplift, which may have wider applicability in other deforming parts of the world.