铂族元素在地壳中的富集:以布什维尔德杂岩为例

地幔是地壳铂族元素富集的主要源库。铂族元素迁移主要有两个途径:(1)地幔部分熔融物质侵入地壳;(2)地幔板片就位于俯冲/碰撞带。前一途径比后一途径重要得多。地幔物质进入地壳造成铂族元素富集并成为可供开采的主矿产而非副产品,这一过程可包含许多成矿作用机制:(i)基性侵入体中Ni-Cu硫化物矿浆的发育,岩浆冷却与分离结晶作用导致富含Cu,Pt,Pd的硫化物矿浆的形成;(ii)层状侵入体一定层位形成高品位的铂族元素硫化物层,伴生或不伴生铬铁岩;(iii)富铂族元素及硫化物的岩浆沿着层状侵入体的边缘就位;(iv)直至层状侵入体结晶分异作用晚期的硫化物不混溶滞后分离;(v)不发育硫化物不混溶作用的铬铁矿结晶作用;(vi)低程度硫化物浸染带中的热液作用与铂族元素富集;(vii)乌拉尔-阿拉斯加型侵入体重结晶过程中的铂族元素与铬铁矿的次生富集作用,岩体在风化过程中形成砂矿床;(viii)黑色页岩形成过程中Pt的富集。南非布什维尔德火成杂岩蕴藏世界Pt资源的75%,Pd资源的54%,Rh资源的82%,并具有(ii)、(iii)、(iv)、(v)、(vi)成矿作用的实例。在这些作用中,作用(ii)形成的现有经济储量和资源量占90%,作用(iii)占9%。Merensky矿层(占总资源量30%)是一个铂族元素富集层位,它含1~3铬铁矿薄层,在可采宽度内硫化物平均含量为1%~3%(质量分数)。硫化物一般被认为是铂族元素的主要聚集体。该矿层由两个或两个以上含硫化物的基性热岩浆上升汇聚而成。这些岩浆的汇聚造成超镁铁质堆晶岩的厚度(主要是斜方辉石岩,某些地区包括橄榄岩)变化于50cm至数米之间。开采通常集中在厚度不到1m的地带。矿层的成因至今仍存在争议,一些观点认为铂族元素来自下部上升的热液流体,另一些观点认为铂族元素来自上部岩浆的硫化物沉降作用,并形成了Merensky辉石岩。已经知道矿层上覆的辉石岩、苏长岩和斜长岩中矿物来自两种岩浆类型:一种富含MgO(12%,质量分数)和Cr,而贫Al2O3(12%);另一种含典型的粒玄岩成分。UG-2铬铁岩含有全部经济资源量的58%,由一0.6~1m厚的铬铁岩层(有时见辉石岩夹层)和上覆的1~3层由铬铁矿所构成的薄层。虽然硫化物被认为至少是某些情况下对铂族元素的富集起作用,但UG-2的硫化物含量(0.5%~1.5%)显著低于Merensky矿层。UG-2层之下共有13个铬铁岩层位,所有的都含铂族元素,虽然铂族元素总含量和(Pt+Pd)/(Ru+Ir+Os)比值远低于UG-2。UG-2内所含的辉石岩"夹层"具高的87Sr/86Sr比值,说明与顶部熔融岩石的混合促进了铬铁岩和硫化物的形成。作用(iii)的主要实例是Platreef。目前它占总资源量的9%。不过,沿该带正积极开展找矿勘探工作,这一比例将来还会提高。这一矿层的厚度比Merensky和UG-2都要大,目前开采厚度达50多米。Platreef呈带状,上部为斜方辉石岩的堆晶岩;下部为辉石岩、长石辉石岩和苏长岩,它们与页岩、铁矿层和白云岩强烈相互作用,直接形成了底盘岩石。笔者认为Platreef是不同期次岩浆作用的结果,这些作用形成了不同的单元产物,包括布什维尔德主岩浆房的UG-2和Merensky矿层。新的岩浆进入主岩浆房会造成先存岩浆移位、岩浆错动并会冲破岩浆房的壁。圆筒状、带状岩管中的超镁铁岩含极高的Pt品位,在布什维尔德杂岩的下部切穿堆晶层,被认为是热液再活化的产物。它们现在未被开采,只是构成存封的铂族元素资源,对整个杂岩体资源没有重要的贡献。     

Reconstructed Northern Hemisphere annual temperature since 1671 based on high-latitude tree-ring data from North America

Annual Northern Hemisphere surface temperature departures for the past 300 yr were reconstructed using eleven tree-ring chronologies from high-latitude, boreal sites in Canada and Alaska, spanning over 90 degrees of longitude. This geographic coverage is believed to be adequate for a useful representation of hemispheric-scale temperature trends, as high northern latitudes are particularly sensitive to climatic change. We also present a reconstruction of Arctic annual temperatures. The reconstructions show a partial amelioration of the Little Ice Age after the early 1700's, an abrupt, severe renewal of cold in the early 1800's and a prolonged wanning since approximately 1840. These trends are supported by other proxy data. Similarities and differences between our Northern Hemisphere reconstruction and other large-scale proxy temperature records depend on such factors as the data sources, methods, and degree of spatial representation. Analyses of additional temperature records, as they become available, are needed to determine the degree to which each series represents fluctuations for the entire hemisphere. There appear to be relationships between trends observed in our Northern Hemisphere reconstruction and certain climatic forcing functions, including solar fluctuations, volcanic activity and atmospheric CO₂. In particular, our reconstruction supports the hypothesis that the global warming trend over the past century of increasing atmospheric CO₂ has exceeded the recent level of natural variability of the climate system.Of Columbia University Department of Geological Sciences.     

A comparison of a GCM response to historical anthropogenic land cover change and model sensitivity to uncertainty in present-day land cover representations

This study assesses the sensitivity of the fully coupled NCAR-DOE PCM to three different representations of present-day land cover, based on IPCC SRES land cover information. We conclude that there is significant model sensitivity to current land cover characterization, with an observed average global temperature range of 0.21 K between the simulations. Much larger contrasts (up to 5 K) are found on the regional scale; however, these changes are largely offsetting on the global scale. These results show that significant biases can be introduced when outside data sources are used to conduct anthropogenic land cover change experiments in GCMs that have been calibrated to their own representation of present-day land cover. We conclude that hybrid systems that combine the natural vegetation from the native GCM datasets combined with human land cover information from other sources are best for simulating such impacts. We also performed a prehuman simulation, which had a 0.39 K ~higher average global temperature and, perhaps of greater importance, temperature changes regionally of about 2 K. In this study, the larger regional changes coincide with large-scale agricultural areas. The initial cooling from energy balance changes appear to create feedbacks that intensify mid-latitude circulation features and weaken the summer monsoon circulation over Asia, leading to further cooling. From these results, we conclude that land cover change plays a significant role in anthropogenically forced climate change. Because these changes coincide with regions of the highest human population this climate impact could have a disproportionate impact on human systems. Therefore, it is important that land cover change be included in past and future climate change simulations.     

Early Mesoproterozoic evolution of midcontinental Laurentia: Defining the geon 14 Baraboo orogeny

New geochronologic data from midcontinental Laurentia demonstrate that emplacement of the 1476-1470 Ma Wolf River granitic batholith was not an isolated igneous event,but was accompanied by regional metamorphism,deformation,and sedimentation.Evidence for such metamorphism and deformation is best seen in siliciclastic sedimentary rocks of the Baraboo Interval,which were deposited closely following the1.65-1.63 Ga Mazatzal orogeny.In Baraboo Interval strata,muscovite parallel to slatey cleavage,in hydrothermal veins,in quartzite breccia,and in metamorphosed paleosol yielded ~(40)Ar/~(39)Ar plateau age s of 1493-1465 Ma.In addition,U-Th-total Pb dating of neoblastic overgrowths on detrital monazite gave an age of 1488±20 Ma,and recrystallized hematite in folded metapelite gave a mean U/Th-He age of 1411± 39 Ma.Post-Baraboo,arkosic polymictic conglomerate,which contains detrital zircon with a minimum peak age of 1493 Ma,was intruded by a 1470 Ma granite porphyry at the northeastern margin of the Wolf River batholith.This episode of magmatism,regional deformation and metamorphism,and sedimentation,which is designated herein as the Baraboo orogeny,provides a midcontinental link between the Picuris orogeny to the southwe st and the Pinware orogeny to the northeast,completing the extent of early Mesoproterozoic(Calymmian) orogenesis for 5000 km along the southern margin of Laurentia.This transcontinental orogen is unique among Precambrian orogenies for its great width(～1600 km),the predominance of ferroan granites derived from partial melting of lower continental crust,and the prevalence of re gional high T-P metamorphism related to advective heating by granitic magmas emplaced in the middle to upper crust.     

Iron biomineralization by anaerobic neutrophilic iron-oxidizing bacteria

Minerals formed by bio-oxidation of ferrous iron (Fe(II)) at neutral pH, their association with bacterial ultrastructures as well as their impact on the metabolism of iron-oxidizing bacteria remain poorly understood. Here, we investigated iron biomineralization by the anaerobic nitrate-dependent iron-oxidizing bacterium Acidovorax sp. strain BoFeN1 in the presence of dissolved Fe(II) using electron microscopy and Scanning Transmission X-ray Microscopy (STXM). All detected minerals consisted mainly of amorphous iron phosphates, but based on their morphology and localization, three types of precipitates could be discriminated: (1) mineralized filaments at distance from the cells, (2) globules of 100 ± 25 nm in diameter, at the cell surface and (3) a 40-nm thick mineralized layer within the periplasm. All of those phases were shown to be intimately associated with organic molecules. Periplasmic encrustation was accompanied by an accumulation of protein moieties. In the same way, exopolysaccharides were associated with the extracellular mineralized filaments. The evolution of cell encrustation was followed by TEM over the time course of a culture: cell encrustation proceeded progressively, with rapid precipitation in the periplasm (in a few tens of minutes), followed by the formation of surface-bound globules. Moreover, we frequently observed an asymmetric mineral thickening at the cell poles. In parallel, the evolution of iron oxidation was quantified by STXM: iron both contained in the bacteria and in the extracellular precipitates reached complete oxidation within 6 days. While a progressive oxidation of Fe in the bacteria and in the medium could be observed, spatial redox (oxido-reduction state) heterogeneities were detected at the cell poles and in the extracellular precipitates after 1 day. All these findings provide new information to further the understanding of molecular processes involved in iron biomineralization by anaerobic iron-oxidizing bacteria and offer potential signatures of those metabolisms that can be looked for in the geological record.     

X-ray absorption fine structure study of As(V) and Se(IV) sorption complexes on hydrous Mn oxides

X-ray absorption fine structure (XAFS) spectroscopic analysis at the As, Se, and Mn K-edges was used to study arsenate [As(V)O₄³⁻] and selenite [Se(IV)O₃²⁻] sorption complexes on the synthetic hydrous manganese oxides (HMOs) vernadite (δ-MnO₂) and K-birnessite (nominal composition: K₄Mn₁₄O₂₇ · 9H₂O). No significant changes were observed in sorption complex structure as a function of sorbent, pH (5 to 8), surface coverage (0.04 to 0.73 μmol/m²), or reaction time (5 to 22 h) in the arsenate or selenite systems. In the arsenate/HMO system, extended XAFS parameters indicate an average second-neighbor As(V) coordination of 2.0 ± 0.4 Mn at an average distance of 3.16 ± 0.01 Å, which is consistent with formation of As(V)O₄ sorption complexes sharing corners with two adjacent Mn(IV)O₆ surface species (i.e., bidentate, binuclear). In the selenite/HMO system, selenite surface complexes are surrounded by two shells of Mn atoms, which could represent two different adsorption complexes or a precipitate. The first shell consists of 1.6 ± 0.4 Mn at 3.07 ± 0.01 Å, which is consistent with the selenite anion forming bidentate (mononuclear) edge-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. The second shell consists of 1.4 ± 0.4 Mn at 3.49 ± 0.03 Å, consistent with selenite forming monodentate, corner-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. Pauling bond valence analysis that uses the extended XAFS-derived bond lengths for As(V)-O, Se(IV)-O, and Mn-O bonds indicates that the proposed surface complexes of selenite and arsenate on HMOs should be stable. Although a nearly identical Se(IV) coordination environment is found in a crystalline Mn(II)-Se(IV) precipitate (which has a structure similar to that of MnSeO₃ · H₂O), there are significant differences in the X-ray absorption near-edge structure and extended XAFS spectra of this precipitate and the selenite/HMO sorption samples. These differences coupled with transmission electron microscopy results suggest that if a precipitate is present it lacks long-range order characteristic of crystalline MnSeO₃ · H₂O.     

Assessing subcontinental lithospheric mantle sources for basalts: Neogene volcanism in the Pacific Northwest,USA as a test case

Many objections have been raised as to the ability of subcontinental lithospheric mantle to produce voluminous amounts of basalt, because this upper part of the mantle is thought to be refractory, and the geotherm is rarely above the peridotite solidus at these depths under continents. However, in the Pacific Northwest of the USA during the Neogene, the subcontinental lithospehric mantle has been proposed as a key source for basalts erupted within the northern Basin and Range, and for the Columbia River flood basalts erupted on the Columbia Plateau. An alternative explanation to melting in the subcontinental lithospheric mantle, which equally well explains the chemical compositions thought to originate there, is that these magmas were contaminated by crust of varying ages. Calc-alkaline lavas, which occupy the Blue Mountains in the center of this region, hold clues to the latter process. Their elevated trace element ratios (e.g., Ba/Zr, K₂O/P₂O₅), coupled with differentiation indicators such as Mg? [molar Mg/(Mg?+?Fe)], and Sr, Nd, and Pb isotopic compositions, can most reasonably be explained by crustal contamination. Appraisal of continental peridotite xenolith data indicates that high trace element ratios such as Ba/Zr in continental basalts cannot result from melting in the subcontinental lithospheric mantle. Instead, as with the calc-alkaline lavas, these high ratios in the tholeiites most likely indicate crustal contamination. Furthermore, the peridotite xenoliths do not have a relative depletion in Nb and Ta that is observed in most of the lavas within the region. Relatively minor volumes of tholeiites erupted in late Neogene times in the northern Basin and Range (Hi-Mg olivine tholeiites) and Columbia Plateau (Saddle Mountains basalts), are the only lavas which have trace element and isotopic compositions consistent with being derived from, or largely interacting with a subcontinental lithospheric mantle in the Pacific Northwest. In contrast to the prior studies, we suggest that the mantle sources for most of the basalts in this region were ultimately beneath the lithospheric mantle.     

MEG Investigation of Low Pressure Silica — Shell model for polarization

We present a two-shell polarization model for the α-quartz and α-cristobalite structures. By allowing for polarization, we correct problems encountered in purely ionic bonding treatments of tetrahedrally coordinated silica phases. The shell model predicts zero pressure structures in very good agreement with experiment using no empirical parameters. The behavior of the shell model α-quartz lattice upon compression shows dramatic improvement over the distorted, rigid lattice given by the ionic model.     

Cultural sediment analyses and transitions in early fishing activity at Langenesværet,Vesterålen,Northern Norway

The development of specialized and commercial fishing activity in the island archipelago of Lofoten and Vesterålen in northern Norway is a critical foundation from which to understand the subsequent spread of commercial fishing across the north Atlantic region during the medieval and early modern period. One little understood aspect of this development is the relationship between medieval commercial fishing stations (fiskevaer) and earlier fishing activity. In this article, cultural sediment deposits at Langenesværet, Vesterålen, Northern Norway provide an opportunity to examine this relationship and its implications for current historical models of fishing development in northern Norway and the north Atlantic region. Conventional and AMS radiocarbon dating techniques are used to establish a chronology for the deposits, while activities associated with the sediments are characterized using thin‐section micromorphology supported by proton induced X‐ray emission spectrometry (PIXE). The results suggest that the site commenced formation as early as ca. 3000 B.C. and that the site was first used for specialized fishing activity from the early centuries A.D. The medieval commercial fiskevaer settlement at Langenesværet was introduced to an area that had a longstanding tradition of specialised fishing activity. © 2000 John Wiley & Sons, Inc.