Zooplankton and forage fish species off Peru: Large-scale bottom-up forcing and local-scale depletion

The Humboldt Current System, like all upwelling systems, has dramatic quantities of plankton-feeding fish, which suggested that their population dynamics may ‘drive’ or ‘control’ ecosystem dynamics. With this in mind we analysed the relationship between forage fish populations and their main prey, zooplankton populations. Our study combined a zooplankton sampling program (1961–2005) with simultaneous acoustic observations on fish from 40 pelagic surveys (1983–2005) conducted by the Peruvian Marine Research Institute (IMARPE) and landing statistics for anchoveta (Engraulis ringens) and sardine (Sardinops sagax) along the Peruvian coast from 1961 to 2005. The multi-year trend of anchoveta population abundance varied consistently with zooplankton biovolume trend, suggesting bottom-up control on anchovy at the population scale (since oceanographic conditions and phytoplankton production support the changes in zooplankton abundance). For a finer-scale analysis (km) we statistically modelled zooplankton biovolume as a function of geographical (latitude and distance from the 200-m isobath), environmental (sea surface temperature), temporal (year, month and time-of-day) and biological (acoustic anchovy and sardine biomass within 5 km of each zooplankton sample) covariates over all survey using both classification and regression trees (CART) and generalized additive models (GAM). CART showed local anchoveta density to have the strongest effect on zooplankton biovolume, with significantly reduced levels of biovolume for higher neighbourhood anchoveta biomass. Additionally, zooplankton biovolume was higher offshore than on the shelf. GAM results corroborated the CART findings, also showing a clear diel effect on zooplankton biovolume, probably due to diel migration or daytime net avoidance. Apparently, the observed multi-year population scale bottom-up control is not inconsistent with local depletion of zooplankton when anchoveta are locally abundant, since the latter effect was observed over a wide range of overall anchoveta abundance.     

Proposal for an International Molybdenum Isotope Measurement Standard and Data Representation

Molybdenum isotopes are increasingly widely applied in Earth Sciences. They are primarily used to investigate the oxygenation of Earth's ocean and atmosphere. However, more and more fields of application are being developed, such as magmatic and hydrothermal processes, planetary sciences or the tracking of environmental pollution. Here, we present a proposal for a unifying presentation of Mo isotope ratios in the studies of mass‐dependent isotope fractionation. We suggest that the δ^98/95Mo of the NIST SRM 3134 be defined as +0.25‰. The rationale is that the vast majority of published data are presented relative to reference materials that are similar, but not identical, and that are all slightly lighter than NIST SRM 3134. Our proposed data presentation allows a direct first‐order comparison of almost all old data with future work while referring to an international measurement standard. In particular, canonical δ^98/95Mo values such as +2.3‰ for seawater and ?0.7‰ for marine Fe–Mn precipitates can be kept for discussion. As recent publications show that the ocean molybdenum isotope signature is homogeneous, the IAPSO ocean water standard or any other open ocean water sample is suggested as a secondary measurement standard, with a defined δ^98/95Mo value of +2.34 ± 0.10‰ (2s).     

Petrological and trace element geochemical features of the Okete Volcanics,western North Island,New Zealand

The Okete Volcanics form small volume monogenetic volcanoes situated around the flanks of larger tholeiitic cones of the Plio-Pleistocene Alexandra Volcanics, in the back-arc tectonic environment of western North Island, New Zealand. The lavas and tuffs of the Okete Volcanics have compositions which include basanites, alkali olivine basalts, olivine tholeiites, and hawaiites. Most rocks have Mg numbers >66, >250 p.p.m. Ni, >500 p.p.m. Cr, and often contain ultramafic xenoliths, which indicate that they are very close to being primary magmas. The Okete Volcanics show geochemical trends, from basanite to hawaiite, of progressive depletion of both compatible and incompatible trace elements, progressive increase in Al₂O₃, and heavy REE and Y enrichment with crossingover REE patterns in the hawaiites. These geochemical trends can be accounted for by varying degrees of partial melting of a light REE enriched garnet peridotite with subsequent modification of the melts near source or during ascent by fractional crystallization of olivine and minor clinopyroxene. Mass balance calculations cannot quantitatively constrain the degree of partial melting or fractional crystallization, but nevertheless indicate that the Okete alkali olivine basalts, olivine tholeiites, and hawaiites have been derived by successively larger degrees of partial melting relative to basanites, and have also been progressively more modified by fractional crystallization than have the basanites. Sources of the alkalic melts lay at depths corresponding to >20 kb, and most of the ultramafic xenoliths, apart from some which may be cognate cumulates, are unrelated to the magmas that brought them to the surface. Magmas have changed in composition with time from older smaller-volume volcanoes of basanite or alkali olivine basalt compositions, to younger and more voluminous volcanoes which contain hawaiites. The geochemical trends shown by the Okete Volcanics and their spatial association with voluminous tholeiitic volcanism, are features which are different from those observed elsewhere in the Pliocene to Recent basaltic fields of northern North Island, and may be related to their unique tectonic setting, situated in a distinct structural domain.     

Devonshire marbles: history of the industry and the geology of these classic British ornamental stones

Devonshire ‘marbles’ come from Mid– to Late Devonian limestones of south Devon, UK. They are not true marbles in the geological sense but were nonetheless tectonically buried during the Variscan orogenesis. They retain abundant palaeontological and sedimentological characters, overstamped by limited to extensive veining, deformation and brecciation. Recent work has revealed how these marbles have been used to decorate a wealth of buildings in Britain and overseas. There were two distinct industries, one that produced decorative marble for architectural use, and one that produced portable artefacts such as specimen marble tables and ornaments. The stones used in these two sister industries can be very different, a result of different sourcing of the same Devonshire limestones. A third industry sought to slice and polish local limestone pebbles to reveal their diverse coral, stromatoporoid and other fossil contents, and was aimed at tourists, collectors and museums. The history and early development of the marble industry are explored and the distinct characteristics of the stones used in Devonshire marble inlay are explained. The stones used in the parallel architectural trade are analysed elsewhere.     

Chemical and oxygen isotopic properties of ordinary chondrites (H5, L6) from Oman: Signs of isotopic equilibrium during thermal metamorphism

Mean bulk chemical data of recently found H5 and L6 ordinary chondrites from the deserts of Oman generally reflect isochemical features which are consistent with the progressive thermal metamorphism of a common, unequilibrated starting material. Relative differences in abundances range from 0.5–10% in REE (Eu = 14%), 6–13% in siderophile elements (Co = 48%), and >10% in lithophile elements (exceptions are Ba, Sr, Zr, Hf, U = >30%) between H5 and L6 groups. These differences may have accounted for variable temperature conditions during metamorphism on their parent bodies. The CI/Mg‐normalized mean abundances of refractory lithophile elements (Al, Ca, Sm, Yb, Lu, V) show no resolvable differences between H5 and L6 suggesting that both groups have experienced the same fractionation. The REE diagram shows subtle enrichment in LREE with a flat HREE pattern. Furthermore, overall mean REE abundances are ~0.6 × CI with enriched La abundance (~0.9 × CI) in both groups. Precise oxygen isotope compositions demonstrate the attainment of isotopic equilibrium by progressive thermal metamorphism following a mass‐dependent isotope fractionation trend. Both groups show a ~slope‐1/2 line on a three‐isotope plot with subtle negative deviation in ?¹⁷O associated with δ¹⁸O enrichment relative to δ¹⁷O. These deviations are interpreted as the result of liberation of water from phyllosilicates and evaporation of a fraction of the water during thermal metamorphism. The resultant isotope fractionations caused by the water loss are analogous to those occurring between silicate melt and gas phase during CAI and chondrule formation in chondrites and are controlled by cooling rates and exchange efficiency.     

A mesh deformation algorithm for free surface problems

Employing the simple iterative technique of adjusting the element positions using computed potentials to locate the free surface can lead to finite elements with large aspect ratios as the free surface drops towards the base of the mesh. In particular, free surface modelling of earth dams with base drains suffer from this problem. The paper suggests a number of steps which can be taken to alleviate mesh distortion problems and improve the numerical stability of the iterative finite element analysis. This leads to a mesh deformation algorithm which adjusts element widths in a simple fashion depending on the free surface height as the iterations proceed. The algorithm is specialized to the sloped earth dam problem, but may find application to other geometries. © 1997 by John Wiley & Sons, Ltd.     

Imaging Hydrological Processes in Headwater Riparian Seeps with Time‐Lapse Electrical Resistivity

Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km²) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.     

Identifying the spatial pattern and importance of hydro‐geomorphic drainage impairments on unpaved roads in the northeastern USA

Roads have been widely studied as sources of runoff and sediment and identified as pollutant production sources to receiving waters. Despite the wealth of research on logging roads in forested, upland settings, little work has been conducted to examine the role of extensive networks of rural, low‐volume, unpaved roads on water quality degradation at the catchment scale. We studied a network of municipal unpaved roads in the northeastern US to identify the type and spatial extent of ‘hydro‐geomorphic impairments’ to water quality. We mapped erosional and depositional features on roads to develop an estimate of pollutant production. We also mapped the type and location of design interventions or best management practices (BMPs) used to improve road drainage and mitigate water quality impairment. We used statistical analyses to identify key controls on the frequency and magnitude of erosional features on the road network, and GIS to scale up from the survey results to the catchment scale to identify the likely importance of unpaved roads as a pollutant source in this setting. An average of 21 hydro‐geomorphic impairments were mapped per kilometer of road, averaging 0.3 m³ in volume. Road gradient and slope position were key controls on the occurrence of these features. The presence of BMPs effectively reduced erosion frequency. Scaled up to the watershed and using a conservative estimate of road–stream connectivity, our results for the Winooski River watershed in the northeastern US suggest that roughly 16% and 6% of the average annual sediment and phosphorus flux, respectively, of the Winooski River may be derived from unpaved roads. Our study identifies an under‐appreciated source of water quality degradation in rural watersheds, provides insights into identifying ‘hot spots’ of pollutant production associated with these networks, and points to effectiveness of design interventions in mitigating these adverse impacts on water quality. Copyright © 2017 John Wiley & Sons, Ltd.     

Connectivity as an emergent property of geomorphic systems

Connectivity describes the efficiency of material transfer between geomorphic system components such as hillslopes and rivers or longitudinal segments within a river network. Representations of geomorphic systems as networks should recognize that the compartments, links, and nodes exhibit connectivity at differing scales. The historical underpinnings of connectivity in geomorphology involve management of geomorphic systems and observations linking surface processes to landform dynamics. Current work in geomorphic connectivity emphasizes hydrological, sediment, or landscape connectivity. Signatures of connectivity can be detected using diverse indicators that vary from contemporary processes to stratigraphic records or a spatial metric such as sediment yield that encompasses geomorphic processes operating over diverse time and space scales. One approach to measuring connectivity is to determine the fundamental temporal and spatial scales for the phenomenon of interest and to make measurements at a sufficiently large multiple of the fundamental scales to capture reliably a representative sample. Another approach seeks to characterize how connectivity varies with scale, by applying the same metric over a wide range of scales or using statistical measures that characterize the frequency distributions of connectivity across scales. Identifying and measuring connectivity is useful in basic and applied geomorphic research and we explore the implications of connectivity for river management. Common themes and ideas that merit further research include; increased understanding of the importance of capturing landscape heterogeneity and connectivity patterns; the potential to use graph and network theory metrics in analyzing connectivity; the need to understand which metrics best represent the physical system and its connectivity pathways, and to apply these metrics to the validation of numerical models; and the need to recognize the importance of low levels of connectivity in some situations. We emphasize the value in evaluating boundaries between components of geomorphic systems as transition zones and examining the fluxes across them to understand landscape functioning. © 2018 John Wiley & Sons, Ltd.     

Improved structural interpretation of legacy 3D seismic data from Karee platinum mine (South Africa) through the application of novel seismic attributes

Seismic detection of faults, dykes, potholes and iron-rich ultramafic pegmatitic bodies is of great importance to the platinum mining industry, as these structures affect safety and efficiency. The application of conventional seismic attributes (such as instantaneous amplitude, phase and frequency) in the hard-rock environment is more challenging than in soft-rock settings because the geology is often complex, reflections disrupted and the seismic energy strongly scattered. We have developed new seismic attributes that sharpen seismic reflections, enabling additional structural information to be extracted from hard-rock seismic data. The symmetry attribute is based on the invariance of an object with respect to transformations such as rotation and reflection; it is independent of the trace reflection amplitude, and hence a better indicator of the lateral continuity of thin and weak reflections. The reflection-continuity detector attribute is based on the Hilbert transform; it enhances the visibility of the peaks and troughs of the seismic traces, and hence the continuity of weak reflections. We demonstrate the effectiveness of these new seismic attributes by applying them to a legacy 3D seismic data set from the Bushveld Complex in South Africa. These seismic attributes show good detection of deep-seated thin (∼1.5 m thick) platinum ore bodies and their associated complex geological structures (faults, dykes, potholes and iron-rich ultramafic pegmatites). They provide a fast, cost-effective and efficient interpretation tool that, when coupled with horizon-based seismic attributes, can reveal structures not seen in conventional interpretations.