Study of fluoride in polluted and unpolluted estuarine environments

Mindhola River estuary, which receives industrial waste containing high concentrations of fluoride, and Purna River estuary, which is free from fluoride contamination, have been investigated. While fluoride behaved conservatively in Purna River estuary, significant deviation from the theoretical dilution line (TDL) in the chlorinity range 0·5–8‰ was observed in Mindhola River estuary due to the externally added fluoride which largely remained in solution. The excess of fluroide over the theoretically calculated value was at a maximum around a chlorinity of 3‰. High natural fluoride content of the river waters resulted in F/Cl ratios exceeding 300 × 10⁻⁵ at low chlorinities. The ratio decreased rapidly with increasing chlorinity and the value near to that of seawater was observed at chlorinities above 14‰.     

A clay mineral investigation of six cores from the Gulf of Mexico

Samples were studied from each color change along six gravity cores from nearshore to deep-sea areas in the Gulf of Mexico. Analytical methods and techniques used to characterize the sediments were X-ray diffraction, differential thermal analysis, cation exchange capacity, particle size distribution and fractionation of the clay-size material with the supercentrifuge.     

Geoacoustic and physical properties of carbonate sediments of the Lower Florida Keys

 Near-surface sediment geoacoustic and physical properties were measured from a variety of unconsolidated carbonate sediments in the Lower Florida Keys. Surficial values of compressional and shear speed correlate with sediment physical properties and near-surface acoustic reflectivity. Highest speeds (shear 125–150 m s^-1; compressional 1670–1725 m s^-1) are from sandy sediments near Rebecca Shoal and lowest speeds (shear 40–65 m s^-1; compressional 1520–1570 m s^-1) are found in soft, silty sediments which collect in sediment ponds in the Southeast Channel of the Dry Tortugas. High compressional wave attenuation is attributed to scattering of acoustic waves from heterogeneity caused by accumulation of abundant shell material and other impedance discontinuities rather than high intrinsic attenuation. Compared to siliciclastic sediments, carbonate sediment shear wave speed is high for comparable values of sediment physical properties. Sediment fabric, rather than changes due to the effects of biogeochemical processes, is responsible for these differences.     

Source regions for recruitment of Calanus finmarchicus to Georges Bank: evidence from molecular population genetic analysis of mtDNA

Molecular population genetic analysis has provided evidence that the copepod, Calanus finmarchicus, of the Labrador Current, Gulf of St Lawrence, Scotian Shelf, Gulf of Maine, and Georges Bank constitute a single, interbreeding population. The DNA sequence of a 350 base pair portion of the mitochondrial large subunit (16S) ribosomal RNA (rRNA) gene was determined for a total of 72 individuals collected in 1992, and 110 individuals collected in 1993 from these regions. There was significant heterogeneity in haplotype frequencies among the samples collected in 1992, but this heterogeneity did not resolve into regional patterns. The only regional differences seen were between pooled samples of the western N. Atlantic and those of the Norwegian Sea. There were no significant differences in haplotype frequencies among the samples collected in 1993, and fewer haplotypes were observed in these samples. Intraspecific molecular variation was typical of other marine species: there were 29 haplotypes among the 182 individuals sequenced. The frequency distribution of the haplotypes was highly skewed: 128 individuals shared one haplotype and 19 individuals were unique. There were 24 variable sites among the 350 bases sequenced; estimated nucleotide diversity was 0.0042. The genetic character of C. finmarchicus populations in the western N. Atlantic was stable over time in that three of the haplotypes (including the most abundant) occurred in both 1992 and 1993. However, haplotype frequencies differed significantly between the two years. The lack of regional structure in the 1992 samples and the genetic homogeneity of samples collected in 1993 across the domain from the Labrador Current to the Gulf of St Lawrence to Georges Bank and the Gulf of Maine indicated that there is significant gene flow across this region. The persistent genetic pattern suggests that the Gulf of St Lawrence may be an important source region for recruitment of C. finmarchicus to Georges Bank. Determination of zooplankton dispersal patterns within high gene flow species will provide information that may not be determined by conventional oceanographic analyses.     

On the monitoring of the thermal state of the upper ocean

This paper discusses some problems related to the development of systems of global monitoring of the sea surface temperature (SST). The characteristics of the operational SST data are considered and estimations of their accuracy are given. The applications of varoous models to the computation of SST in relation to the development of an oceanographic data assimilation system are reviewed briefly.Translated by Mikhail M. Trufanov.     

Radioelement distribution in river,beach, and offshore areas and their significance to Chavara placer deposit,Southern Kerala Coast of India

The radioelement and heavy mineral distribution in river, beach and innershelf areas of the southern Kerala coast is related to placer mineral concentration on the beaches at Chavara. Southern Kerala rivers—Neyyar, Karamana and Vamanapuram—transport higher amounts of radioactive elements than the larger Kallada River due to higher radioactive minerals in the hinterland rocks. Coastal configurations and the seasonal longshore current pattern seems to control along-shore distribution of minerals. The proposed model for placer concentration suggests that the energy difference and seasonal current direction along this coast is important.     

A calibration of the Bagnold beach equation

A simple sand trap is used to measure swash and backwash bedload transport rates on intertidal profiles. Data from sixty-eight beach experiments are used to calculate a mean value of 12.78 kg m^?4s^?2 for the calibration coefficient in the Bagnold beach equation.     

Effects of organic pollutants on methanogenesis,sulfate reduction and carbon dioxide evolution in salt marsh sediments

Anaerobic salt marsh sediments were amended with a variety of organic pollutants and the effects on methanogenesis, sulfate reduction and carbon dioxide evolution were examined. Addition of 1000 μg g^?1 (dry weight sediment) Arochlor 1221, lindane, endrin, benzene and phenanthrene resulted in no significant effects on the activities studied. Methanogenesis was inhibited by 1000 μg g^?1toxaphene, PCP, chlordane, naphthalene, DDT, Kepone and heptachlor and by 100 μg g^?1 PCP and toxaphene. At 1000 μg g^?1 naphthalene and toxaphene and 100 μg g^?1 PCP, a period of initial inhibition of methanogenesis was followed by stimulation relative to controls. Arochlor 1254 (1000 μg g^?1) and Temik (500 and 10 μg g^?1) stimulated methanogenesis from the outset. Temik at 500 μg g^?1 gave the greatest stimulation of methanogenesis (900% of controls) of any of the compounds studied. Sulfate reduction was inhibited by 1000 μg g^?1 PCP, toxaphene, naphthalene and chlordane and by 500 μg g^?1 atrazine and 100 μg g^?1 heptachlor. Sustained inhibition of sulfate reduction by naphthalene, toxaphene and PCP may have contributed to the stimulation of methanogenesis. Carbon dioxide evolution was not significantly affected by most of the compounds studied except for 100 μg g^?1 PCP and 1000 μg g^?1 aphthalene, each of which gave significant inhibition in only one of three experiments.Concentrations of individual organic pollutants required to cause observable effects were high. It is concluded that, except for highly polluted sediments, methanogenesis, sulfate reduction and CO₂ evolution would not be affected by the compounds studied here at concentrations typically found in the environment.     

Deep sea navigation techniques

Accurate navigation forms an essential part of all research at sea and the deep ocean imposes it's own unique problems. This chapter discusses several of the techniques in current use on the research vessels of the Natural Environment Research Council (NERC), concentrating on those systems which provide global navigation facilities, as opposed to the more localised, coastal aids. Whilst most of the systems rely on surface propagation of radio waves, the use of acoustics and sea-bed mapping instruments constitute accurate alternatives for some sub-sea applications.     

Approaches to the study of cheniers along the coastline of the Soviet Union

With the very extensive coastline in the north and northeast and the relatively shorter coastlines in the south, cheniers in the USSR can occur in a great variety of climatological conditions ranging from subarctic to subtropical. Cheniers in the USSR have been studied since approximately 1900, the investigations being mainly concerned with the palaeogeographical aspects. Since the 1960's, investigations have focussed on contemporary morphodynamics. Chenier formation appears to depend largely on the relative influence that marine and fluvial factors have on the formation of marginal deltaic plains. Research in this field is briefly reviewed.