泥盆系弗拉阶/法门阶之交事件沉积和海平面变化

在华南板块南部被动大陆边缘和西伯利亚板块南部活动大陆边缘弗拉阶/法门阶之交识别出7种物理事件相: 细粒钙屑浊积岩相、钙质角砾岩相、软变形灰岩相、含微球粒的粒泥灰岩相、凝灰质砾岩相、黑色页岩相和火山喷溢相.它们在法门阶下Palmatolepis triangularis带底部和/或上Palmatolepis rhenana带底部具有广泛的分布, 可能是两次陨击事件记录, 是良好的高分辨率年代地层对比标志.弗拉期/法门期之交的海平面变化不具有同步性和一致性, 可分辨出2种型式(阶跃型和渐进型) 和5种状态(弗拉期最末期下降→法门期最初期上升、弗拉期最末期上升→法门期最初期下降、弗拉期最末期上升→法门期最初期上升、弗拉期最末期下降→法门期最初期下降、弗拉期最末期与法门期最初期海平面变化不明显).弗拉阶/法门阶之交生物的阶梯状绝灭可能与从上Palmatolepis rhenana带底部至Palmatolepis crepida带不均匀分布的6次陨击事件密切相关.      

Decrepitation Thermometry and Compositions of Fluid Inclusions of the Damoqujia Gold Deposit,Jiaodong Gold Province,China:Implications for Metallogeny and Exploration

The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.     

Pore-water geochemistry in methane-seep sediments of the Makran accretionary wedge off Pakistan: Possible link to subsurface methane hydrate

Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.     

南海和冲绳海槽沉积物的生物标记化合物

本文对南海深海和冲绳海槽二个柱状样进行了正构烷烃、甾烷和萜烷生物标记化合物分布特征的研究。由于它们所处的沉积环境和生源母质上的差异,反映在正构烷烃的CPI值、C_(17)和C_(18)的含量、轻重烃比值、化合物构型的转化、有机质的成熟度和17α(H)-22,29,30-三降藿烷与18α(H)-22,29,30-三降新藿烷的比值等地球化学参数上的差别。冲绳海槽沉积物的多源性决定了其有机组分的特殊性,如生物来源的C_(17)和C_(18)量占有优势,有机碳含量(1.0—1.3％)高于南海样(0.3—1.0％),重排甾烷量少,生物构型的ββ藿烷已转变成地质构型的αβ藿烷和βα型莫烷化合物。     

露天生物质燃烧对地面PM2.5浓度的影响评估

利用MODIS火点、土地类型、植被覆盖、生物质载荷和排放因子等数据产品,开发了露天生物质燃烧排放模型,并将其嵌入空气质量模式WRF-CUACE,通过敏感性试验定量评估了露天生物质燃烧对中国地面PM_2.5浓度的影响。研究设计了3种模拟方案,比较模式评估结果发现修订后的方案能更好地模拟PM_2.5浓度。结果表明:2014年10月露天生物质燃烧主要集中在我国东北、华南和西南地区,其对PM_2.5月平均浓度的贡献达30～60μg·m³,局地甚至超过100μg·m³;华北、华东和华南地区生物质燃烧对PM_2.5月平均浓度的贡献达5～20μg·m³。从相对贡献看,东北大部分地区生物质燃烧对地面PM_2.5浓度的贡献超过50%,华南地区达20%～50%,西南局部地区甚至超过60%;华北、华中以及华东地区相对较低,平均相对贡献达10%～20%。生物质燃烧越严重的地区,其产生的PM_2.5中二次气溶胶的贡献占比越小,反...     

记贵州顶效中三叠世一新的海生爬行动物

在贵州兴义顶效绿荫村西大约150m绿荫水泥厂南面采石场出露的中三叠统杨柳并组（拉丁阶）灰黑色中薄层灰岩中发现一新的海生爬行动物－绿荫顶效龙Dingxiaosaurus luyinensisgen.et sp.nov。它的肢骨形态和结构颇为独特，股骨，胫，腓骨以及跗骨的形状和结构相似于原始的鱼龙，而趾骨形状和数目有些相似于最早的蛇颈龙，但又与所有已知的鱼龙和蛇颈类类的属种均明显不同，它是早期海生爬行动脉进化的一个比较原始而孤立的新种类，它的发现对早期海生爬行动物进化多样性的认识具有十分重要的科学意义。     

黄土高原风成沉积物磁化率各向异性研究

中国黄土高原粉尘堆积以往注重从物源区携带粉尘的古风向,对粉尘沉积→固结期的古风向缺乏研究.本文评述了近年来应用黄土高原黄土、红粘土磁化率各向异性研究古季风风向变迁所取得的一些重要进展并指出磁化率各向异性最大轴和最小轴的方位和倾伏均与沉积→固结期风向变化密切相关.黄土磁组构结果与利用各种统计方法计算出的古风向在多个剖面与现代夏季风方向相似,由此推论黄土是冬季风带来的沙尘在经历夏季风携带的降雨洗礼后才固结而成.而在黄土之下的红粘土地层中的初步研究发现磁组构显示明显的西风带沉积特征,指出这一现象将在今后研究中继续深入探讨.     

新疆库尔勒市空气质量等级及首要污染物时空变化研究

城市空气质量与经济建设及人民生活息息相关,是政府和人民关注的重大社会问题。利用库尔勒市2014年9月1日-2015年8月31日州政府、棉纺厂、开发区三个环境监测站逐时观测资料,分析了库尔勒市空气质量等级和首要污染物的时空分布,并分析了污染天气发生的日变化特征。结果表明：（1）三站污染天气出现频率分别为49.4%、40.9%和34.7%,符合州政府＞棉纺厂＞开发区的分布规律。三站污染天气均是春季出现频率最高,分别占到44.7%,39.4%和48.5%,其次为秋季、冬季和夏季;（2）库尔勒市首要污染物中, PM10的频率最高,其次为PM2.5,CO、NO2、O3及SO2出现频率均低于10.0%。PM10作为首要污染物在春季出现频率最高,三站出现频率为33.9%-36.3%,PM2.5则是冬季出现频率最高,三站出现频率为59.1%-86.4%;（3）库尔勒市污染天气和重污染天气发生频率符合傍晚与夜间高,白天低的变化规律。污染天气发生频率最高值出现在0:00时,最低值出现在6:00-7:00时,重污染天时延迟到9:00时。上述结果表明库尔勒市春季周边自然污染源的排放与输送对该市的空气质量影响巨大。     

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.