Further Characterisation of the 91500 Zircon Crystal

This paper reports the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), secondary ion mass spectrometry (SIMS) and laser fluorination analyses. The focus of this initiative was to establish the suitability of this large single zircon crystal for calibrating in situ analyses of the rare earth elements and oxygen isotopes, as well as to provide working values for key geochemical systems. In addition to extensive testing of the chemical and structural homogeneity of this sample, the occurrence of banding in 91500 in both backscattered electron and cathodoluminescence images is described in detail. Blind intercomparison data reported by both LA-ICP-MS and SIMS laboratories indicate that only small systematic differences exist between the data sets provided by these two techniques. Furthermore, the use of NIST SRM 610 glass as the calibrant for SIMS analyses was found to introduce little or no systematic error into the results for zircon. Based on both laser fluorination and SIMS data, zircon 91500 seems to be very well suited for calibrating in situ oxygen isotopic analyses.     

Seasonal patterns of nitrification and denitrification in a natural and a restored salt marsh

Seasonal patterns of microbially-mediated nitrogen cycling via the nitrification-denitrification pathway were compared between a natural and a restored salt marsh. Sedimentary denitrification rates, measured with a modification of the acetylene block technique, were approximately 44 times greater in the natural marsh relative to an adjacent transplanted marsh. Nitrification rates were similar at both sites. The difference in denitrification rates was attributed to oxygen inhibition at low tide and tidal flushing of porewater nutrients at high tide in the coarse sediments of the restored marsh. Denitrification was positively correlated with nitrification throughout the year in the natural marsh with a seasonal fall peak in denitrification corresponding to a maximum in porewater ammonia concentration. A weak correlation existed between the two processes in the restored marsh, where nitrification rates exceeded denitrification rates by a factor of 20. Transplanted marsh denitrification rates exhibited a spring peak, corresponding to elevated porewater ammonia concentrations. Our findings demonstrate functional differences in microbial nitrogen dynamics of a young (0–3 yr) restored marsh relative to a mature (>50 yr) salt-marsh system. *** DIRECT SUPPORT *** A01BY070 00008     

Changes of GPR spectra due to the presence of hydrocarbon contamination in the ground

The location of hydrocarbon contamination in the ground using the GPR method is based mainly on information taken from reflected signals. In the cases investigated in Polish contaminated sites, such signals were very seldom recorded. A long time after spillage, contamination takes the form of plumes with different size and distribution, which depends on geological and hydraulic properties of the ground. In this paper, it is shown that the set of hydrocarbon plumes should be described with a stochastic model, and such plumes may generate the scattered waves which cause changes in the power spectra. It has been observed that the power spectra of GPR signals over contaminated areas are quite different from such spectra over clear ones. These differences were discussed in this paper on the basis of theoretical analysis, numerical modelling and the results of GPR terrain surveys.     

Estimation of aboveground biomass and carbon in a tropical rain forest in Gabon using remote sensing and GPS data

The knowledge of biomass stocks in tropical forests is critical for climate change and ecosystem services studies. This research was conducted in a tropical rain forest located near the city of Libreville (the capital of Gabon), in the Akanda Peninsula. The forest cover was stratified in terms of mature, secondary and mangrove forests using Landsat-ETM data. A field inventory was conducted to measure the required basic forest parameters and estimate the aboveground biomass (AGB) and carbon over the different forest classes. The Shuttle Radar Topography Mission (SRTM) data were used in combination with ground-based GPS measurements to derive forest heights. Finally, the relationships between the estimated heights and AGB were established and validated. Highest biomass stocks were found in the mature stands (223 ± 37 MgC/ha), followed by the secondary forests (116 ± 17 MgC/ha) and finally the mangrove forests (36 ± 19 MgC/ha). Strong relationships were found between AGB and forest heights (R² > 0.85).     

Late Archaean mantle metasomatism below eastern Indian craton: Evidence from trace elements,REE geochemistry and Sr—Nd—O isotope systematics of ultramafic dykes

Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼ 0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; (ΣHREE)_N ∼ 2–3 times chondrite, (Gd/Yb)_N ∼ 1). The ε^Nd(t) values vary from +1.23 to -3.27 whereas δ¹⁸O values vary from +3.16‰ to +5.29‰ (average +3.97‰±0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (± silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable ε^Nd, low Sr_i(0.702) and low δ¹⁸O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.     

据地貌声图判读研究海底地貌和底质类型

侧向扫描声呐这项新技术方法及其在海洋地质调查中的应用问题,最近作者已作过介绍。1975年,我们应用侧向扫描声呐(侧扫声呐)、精密回声探测、海底采样等方法,对中国南海某浅海区进行了海底地质调查,了解海底地貌和底质类型及其包括砂矿等的分布。     

Automatic change detection of buildings in urban environment from very high spatial resolution images using existing geodatabase and prior knowledge

The updating of geodatabases (GDB) in urban environments is a difficult and expensive task. It may be facilitated by an automatic change detection method. Several methods have been developed for medium and low spatial resolution images. This study proposes a new method for change detection of buildings in urban environments from very high spatial resolution images (VHSR) and using existing digital cartographic data. The proposed methodology is composed of several stages. The existing knowledge on the buildings and the other urban objects are first modelled and saved in a knowledge base. Some change detection rules are defined at this stage. Then, the image is segmented. The parameters of segmentation are computed thanks to the integration between the image and the geodatabase. Thereafter, the segmented image is analyzed using the knowledge base to localize the segments where the change of building is likely to occur. The change detection rules are then applied on these segments to identify the segments that represent the changes of buildings. These changes represent the updates of buildings to be added to the geodatabase. The data used in this research concern the city of Sherbrooke (Quebec, Canada) and the city of Rabat (Morocco). For Sherbrooke, we used an Ikonos image acquired in October 2006 and a GDB at the scale of 1:20,000. For Rabat, a QuickBird image acquired in August 2006 has been used with a GDB at the scale of 1:10,000. The rate of good detection is 90%. The proposed method presents some limitations on the detection of the exact contours of the buildings. It could be improved by including a shape post-analysis of detected buildings. The proposed method could be integrated into a cartographic update process or as a method for the quality assessment of a geodatabase. It could be also be used to identify illegal building work or to monitor urban growth.     

Sea level response to wind field fluctuation around the tip of the Izu Peninsula

The mechanism of a characteristic sea level response (barotropic coastal ocean response) to wind field fluctuation around the tip of the Izu Peninsula observed during the middle of December 2000 to the middle of January 2001 was investigated based on three types of numerical experiments using the Princeton Ocean Model with various parameters. The response was characterized by the relaxation of sea level falling (rising) during eastward upwelling (westward downwelling) favorable wind regime. Analyses of quasi-realistic numerical model results in terms of the vertically integrated momentum balances and vorticity balance for the barotropic mode revealed that: 1) development/abatement of two anomalous circulations generated around the tip of the Izu Peninsula controls the sea level response through the acceleration/deceleration of a quasi-geostrophic barotropic coastal current between the circulations; 2) nonlinear vorticity advection by the Kuroshio Current and by the coastal current, coupled with vorticity diffusion, decelerates the quasi-geostrophic coastal current in the latter half of the wind regimes, which induces the relaxation of sea level rise/fall. The results of the quasi-realistic numerical experiment suggest that an analysis of the vorticity balance for the barotropic mode contributes to a better understanding of sea level responses to wind in coastal regions with strong currents and complex topography. In addition, a numerical experiment with idealized spatially uniform density stratification and a quasi-realistic wind field shows that if the Kuroshio Current had been shifted far offshore from the Izu Peninsula during the observation period, westward propagating continental shelf waves would have controlled the coastal sea level response.     

Impact of environmental variables on spatial and seasonal internal phosphorus loading in a mesoeutrophic lake

Strzeszynskie Lake was formerly a slightly eutrophic (meso-eutrophic) water body. The aim of the current research was to define variables on both spatial and seasonal internal phosphorus loading from bottom sediments at five stations located in zones varying in depth, oxygenation, macrophyte presence, and uses of the neighboring catchment area. Ex situ experiments done with the use of intact bottom sediment cores have shown that the highest phosphorus release occurred in the deepest part of the lake and reached 3.6?mg?P/m²d under anoxic conditions during summer thermal stratification. In turn, the internal loading from littoral sediments, which were well aerated all year round, was clearly lower. Furthermore, phosphorus accumulation in the bottom sediment was observed to reach a maximum of 1.45?mg?P/m² d in autumn. A comparison of the internal loading intensity in lake zones with different land uses of the neighboring catchment area has shown slightly higher values at stations adjacent to the forest catchment area than those used for recreation. Changes in the land use of the catchment area of Strzeszynskie Lake, especially the increase in impermeable surfaces, have led to an increased inflow of external loads after heavy rains, resulting in deterioration in water quality and a delayed increase in internal loading.     

Nonlinear behaviour of scoria soil sediments evaluated from borehole records in eastern Shizuoka prefecture,Japan

We evaluate the non-linear behaviour of soil sediments, analysing five weak and four strong motions observed at depths of 1 m and 28 m, in eastern Shizuoka prefecture, Japan. We identify S-wave velocities and frequency-dependent damping factors by minimizing the residual between observed and theoretical spectral ratios, based on a linear one-dimensional model. We find that S-wave velocities identified from strong motions, whose peak ground acceleration are 440, 210, 176, and 140 cm/s², are significantly smaller than those identified from weak motions. The shear modulus reduction ratios estimated from identified S-wave velocities become clear above an effective shear strain of 10^-4 and agree with laboratory test results below an effective shear strain of 8×10^-4. The differences of damping factors between weak and strong motions are not clear below this effective shear strain, as the laboratory test suggested. The equivalent linear one-dimensional model, with frequency-dependent damping factors, is confirmed to be valid to simulate strong motions at least an effective shear strain of less than 4×10^-4. © 1997 John Wiley & Sons, Ltd.