Water chemistry of lakes related to active and inactive Mexican volcanoes

Water chemistry of crater lakes, maars and water reservoirs linked to some Mexican volcanoes within and outside the Mexican Volcanic Belt has been determined for several years and examined regarding environmental and volcanic factors. All the analyzed lakes are relatively small with a maximum depth of 65 m, and are located in regions with different climates, from semi-arid to very humid, with altitudes ranging from 100 to more than 4000 m a.s.l. Crater lakes in active volcanoes (El Chichón, Popocatépetl) have very low pH, moderate to high temperatures and major ion concentrations varying with the level of volcanic unrest. Lakes in sub-arid and temperate-arid regions (like maars in Puebla and Guanajuato states) show high alkalinity and pH, with bicarbonate/carbonate, chloride, sodium and magnesium as predominant ions. Lakes located in humid climates (Central Michoacán and Veracruz state) have low mineralization and near-neutral pH values. In general, conservative dissolved ions and conductivity appear to be mostly controlled by precipitation/evaporation and by the ionic concentration of groundwater inputs. Calcium, magnesium, sulfate concentrations and pH are strongly influenced by volcanic-rock or volcanic gas interactions with water. The influence of low-level volcanic activity on crater lakes may be obscured by water–rock interactions, and climatic factors. One of the aims of this paper is to define the relative influence of these factors searching for a reference frame to recognize the early volcanic precursors in volcano-related lakes.     

Origin and evolution of playas and blowouts in the semiarid zone of Tierra de Pinares (Duero Basin, Spain)

A large number of blowouts and playas occur in the marginal sectors of the aeolian deposits located in the southern sector of the Duero Depression (Tierra de Pinares) in Spain. The blowouts are relict landforms that were developed on sand sheets by deflation during dry periods with lower vegetation cover and a deeper water table. The studied blowouts form complexes of NW–SE and NNW–SSE elongated hollows with accompanying dunes up to 4 km long in the leeward margins. Some hollows host lakes or swampy areas related to a shallow water table. The dunes formed by NE–ENE winds show steep windward slopes and gentle leeward slopes. The studied playas, with prevalent NNW–SSE orientations, result from the aeolian excavation of terrace deposits and the underlying marly bedrock. It is probable that the formation of these depressions in an initial stage was related to deflation processes affected preferentially NNW–SSE sandy channels perpendicular to the dominant wind direction. The precipitation of salts in the playas generates aggregates of clay particles (peloids) that are easily removed by the wind. Once the bottom reached the substratum, the deepening of the depressions progressed by the deflation of particles produced by weathering of the argillaceous bedrock.     

Occurrence of PSP-producing dinoflagellate Alexandrium tamiyavanichii in Bingo-Nada, the central coastal water of the Seto Inland Sea, Hiroshima Prefecture, Japan

During surveillance of the distribution of the paralytic shellfish poison (PSP)-producing dinoflagellate in 2003, 2004 and 2005 along the coastlines of the Seto Inland Sea, Hiroshima Prefecture, Japan, some species of toxic phytoplankton were isolated from the eastern coasts, Bingo-Nada, the central regions of the Seto Inland Sea. It was rather unexpectedly revealed from the basis of the morphological characteristics that they were unambiguously identified as Alexandrium tamiyavanichii and Alexandrium catenella. Two strains (ATY041106, ATY051018) of A. tamiyavanichii showed a specific toxicity of 38.7 x 10(-6) and 111.5 x 10(-6)MU/cell, respectively. These values seemed to be several times or much higher than that of A. catenella (AC030816, AC040614), having a specific toxicity of 4.5 x 10(-6) and 4.1 x 10(-6)MU/cell, respectively, isolated in the same area. From the results of HPLC-furuorometric analysis, it revealed that the toxins in ATY041106 exist almost exclusively as beta-epimers (C2, GTX3, GTX4), which accounted for 72.7 mol%. The toxin profiles of this strain are featured by the presence of a large amount of GTX3 (59.1 mol%) and a small amount (20.6%) of C1 and 2 in comparison with the PSP compositions of A. tamarense, which is isolated as the main responsible species in Hiroshima Bay, a western part of coastal sea in Hiroshima Prefecture. On the other hand, it revealed that the toxin profiles of two strains (AC030816, AC040614) of A. catenella exist almost exclusively as beta-epimers (C2, GTX3, GTX4), which accounted for 81.8 and 56.5 mol%, as the same manner. The toxin profiles of these two strains are featured by the presence of a large amount of C2 (80.5 and 46.3 mol%) in comparison with the PSP compositions of A. tamiyavanichii. To our knowledge, this is the first record to show the distribution and harmful influence of A. tamiyavanichii and A. catenella in Bingo-Nada in Hiroshima Prefecture. Though contamination of bivalves with these PSP-producing planktons in this area has not occurred yet so far, attention should be paid to this species as well as the other causative dinoflagellate from the stand point of public health and food hygiene.     

Fault zone development and strain partitioning in an extensional strike-slip duplex: A case study from the Mesozoic Atacama fault system, Northern Chile

Upper crustal strike-slip duplexes provide an excellent opportunity to address the fundamental question of fault zone development and strain partitioning in an evolving system. Detailed field mapping of the Mesozoic Atacama fault system in the Coastal Cordillera of Northern Chile documents the progressive development of second- and third-order faults forming a duplex at a dilational jog between two overstepping master faults: the sinistral strike-slip, NNW-striking, Jorgillo and Bolfin faults. These are constituted by a meter-wide core of foliated S-C ultracataclasite and cataclasite, flanked by a damage zone of protocataclasite, splay faults and veins. Lateral separation of markers along master faults is on the order of a few kilometers. Second-order, NW-striking, oblique-slip subsidiary fault zones do not show foliated ultracataclasite; lateral sinistral separations are in the range of  10 to 200 m with a relatively minor normal dip-slip component. In turn, third-order, east–west striking normal faults exhibit centimetric displacement. Oblique-slip (sinistral–normal) fault zones located at the southern termination of the Bolfin fault form a well-developed imbricate fan structure. They exhibit a relatively simple architecture of extensional and extensional-shear fractures bound by low displacement shear fractures. Kinematic analysis of fault slip data from mesoscopic faults within the duplex area, document that the NW-striking and the EW-striking faults accommodate transtension and extension, respectively. Examination of master and subsidiary faults of the duplex indicates a strong correlation between total displacement and internal fault structure. Faults started from arrays of en echelon extensional/extensional-shear fractures that then coalesced into throughgoing strike-slip faults. Further displacement leads to the formation of discrete bands of cataclasite and ultracataclasite that take up a significant part of the total displacement. We interpret that the duplex formed by progressive linkage of horsetail-like structures at the southern tip of the Bolfin fault that joined splay faults coming from the Jorgillo and Coloso faults. The geometry and kinematics of faults is compared with that observed in analog models to gain an insight into the kinematic processes leading to complex strike-slip fault zones in the upper crust.     

Characteristics of the burial environment related to quartz SAR-OSL dating at St. Vincent Island, NW Florida, USA

St. Vincent Island, on the northwest Gulf coast of Florida, USA, preserves a well-developed beach ridge plain that began to form 4000 years ago based on inferred ages of pottery artefact assemblages. Seven vibra cores up to 2.88 m in length (uncompacted sediment) were retrieved from six ridges across the island. The single-aliquot regenerative-dose (SAR) procedure was used to obtain two optically stimulated luminescence (OSL) ages per core at different depths within each core.

The geographically youngest ridges gave ages of 370±50–1900±300 years, yielding an inter-ridge accumulation time of 150 years assuming uniform sediment accumulation. The oldest ridge sets yielded ages of 2700±400–2800±300 years. Dating results are evaluated in terms of equivalent dose (D_E) distributions and other characteristics in relation to aspects of the burial environment, including pedogenesis.     

Relative importance of dust inputs and aquatic biological production as sources of lake sediments in an oligotrophic lake in a semi‐arid area

The dustfall (DF) and mass sedimentation rate (MSR) in Lake Alchichica, Central Mexico, were studied from June 2006 to June 2008. DF ranged between 0·11–0·93 g m^?2 d^?1 in the warm and rainy season and 0·54–1·21 g m^?2 d^?1 in the cold and dry season. MSR varied from 0·52–2·40 g m^?2 d^?1 in the stratification season to 1·14–5·07 g m^?2 d^?1 in the circulation season. The timing of the highest fluxes of DF and MSR is most likely a product of several factors coinciding during the cold and dry season: (a) availability of dust sources and the presence of strong winds (>7·5 m s^?1) in the DF case, and (b) the circulation period of the lake and the availability of nutrients in the MSR case. As expected, the DF in Alchichica was high and similar to that found in other arid and semi‐arid areas. However, the MSR was higher than that reported for other oligotrophic lakes. Particles captured in the aerial traps consisted mainly of detrital minerals; in contrast, particles found in the water traps were mostly biogenic and, to a lesser extent, detrital minerals. The MSR was one to seven times higher than the DF. In spite of the oligotrophic status of Lake Alchichica, the large size of the settled phytoplankton (autochthonous, waterborne) is what leads to the high MSR, which surpasses the DF (allochthonous, airborne) derived from whirlwinds originating in easily eroded terrains that are characteristic of arid/semi‐arid areas. Our results indicate that caution must be taken in considering that the DF amount measured through DF collectors located at the lake shore does actually represent the DF entering into the lake. Copyright © 2010 John Wiley & Sons, Ltd.     

Exact solution for granular flows

In this paper, we present the exact solution of the Riemann problem for the nonlinear one‐dimensional so‐called shallow‐water or Saint‐Venant equations with friction proposed by SAVAGE and HUTTER to describe debris avalanches. This model is based on the depth‐averaged thin layer approximation of granular flows over sloping beds and takes into account a Coulomb type friction law with a constant friction coefficient. A particular configuration of the Riemann problem corresponds to a dam of infinite length in one direction from which granular material is released from rest at a given time over an inclined rigid or erodible bed. We solve analytically and numerically the depth‐averaged long‐wave equations derived in a topography‐linked coordinate system for all the possible Riemann problems. The detailed mathematical proof of the derivation of the analytical solutions and the analysis of their structure and properties is intended, first of all, for geophysicists, mathematicians, and physicists because of the possible extension of this study to more complex problems (geometries, friction laws, …). The numerical solution of the first‐order finite‐volume method based on a Godunov‐type scheme is compared with the proposed exact Riemann problem solution. This solution is used to solve the dam‐break problem and analyze the influence of the thickness of the erodible bed on the speed of the granular front. Comparison with existing experimental results shows that, for an erodible bed, the equations lack fundamental physical significance to reproduce the observed dynamics of erosive granular flows. Copyright © 2012 John Wiley & Sons, Ltd.     

The black-hole candidate XTE J1817-330 as seen by XMM-Newton and INTEGRAL

The new black hole candidate XTE J1817-330, discovered on 26 January 2006 with RXTE, was observed with XMM-Newton and INTEGRAL in February and March 2006, respectively. The X-ray spectrum is dominated by the thermal emission of the accretion disk in the soft band, with a low absorption column density (N _H=1.77(±0.01)×10²¹ cm⁻²) and a maximum disk temperature kT _max=0.68(±0.01) keV, plus a power law component, with the photon index decreasing from 2.66±0.02 to 1.98±0.07 between the two observations. Several interstellar absorption lines are detected in the X-ray spectrum, corresponding to O I, O II, O III, O VII and Fe XXIV. We constrain the distance to the system to be in the range 1–5 kpc.      

Optically stimulated luminescence age of the Old Cedar midden, St. Joseph Peninsula State Park, Florida

We report optically stimulated luminescence (OSL) dating results from the Old Cedar midden in St. Joseph Peninsula State Park, located between the Gulf of Mexico and St. Joseph Bay near Port St. Joe, FL, USA. The Old Cedar site (8GU85) is located on top of a relict beach ridge which is actively eroding into St. Joseph Bay. Old Cedar is noted for its conch shell tool assemblage, otherwise rare at northwest Florida archaeological sites, and is believed to have been utilized during the Late Woodland Weeden Island and possibly the Fort Walton periods [Benchley, E.D., Bense, J.A., 2001. Archaeology and history of St. Joseph Peninsula State Park: Phase I investigations. Report of Investigations, No. 89, University of West Florida Archaeology Institute]. After removing surficial erosion deposits, we extracted OSL core samples from both the midden layer and the underlying beach ridge. The resulting OSL age is compared with the age of another beach ridge on St. Joseph Peninsula. We hope that this study will aid in the investigation and conservation of Old Cedar specifically and other Weeden Island sites in the St. Joseph Bay area.