The extended economic zone,the coastal state,and economic development

The recently created exclusive economic zones constitute windfall gains for some coastal states. However, windfall gains, such as the New World's gold for Spain and oil for OPEC, are notoriously difficult to transform into permanent wealth and income streams. These difficulties are discussed in this paper. In addition, a case study of the asset values of fisheries in areas of the NW and W Central Pacific Ocean is presented in detail. For nine countries, the changes in catch, both quantity and value, which resulted from establishment of the EEZ are used as estimators of the windfall gains.     

Natural subsidence of the Venice area during the last 60 Myr

Integrated geohistory analysis performed on high‐resolution stratigraphy of Venezia 1 and Lido 1 wells (Quaternary–Pliocene interval) and low‐resolution stratigraphy of a simulated well extending Lido 1 down to the base of Cenozoic (Palaeocene–Miocene interval) is used to reconstruct the interplay between subsidence and sedimentation that occurred in the Venice area (eastern Po Plain) during the last 60 Myr, and to discuss the relationships between calculated subsidence rates and time resolution of stratigraphic data. Both subsidence and sedimentation are mostly related to the tectonic evolution of the belts that surround the Venice basin, influencing the lithosphere vertical motions and the input of clastic sediments through time. In particular, two subsidence phases are recorded between 40–33.5 and 32.5–24 Myr (0.13 and 0.14 mm year^?1, respectively), coeval with tectonic phases in the Dinaric belt. Vice versa, during the main South‐Alpine orogenic phase (middle–late Miocene), quiescence or little uplift (?0.03 mm year^?1) reflects the location of the Venice area close to the peripheral bulge of the South‐Alpine foreland system. Early Pliocene evolution is characterised by a number of subsidence/uplift events, among which two uplifts occurred between 5–4.5 and 3–2.2 Myr (at ?0.4 and ?0.2 mm year^?1, respectively) and can be correlated with tectonic motions in the Apennines. During the last million years, the Venice area was initially characterised by uplift (?0.6 mm year^?1 rising to ?1.5 mm year^?1 between 0.4 and 0.38 Myr), eventually replaced by subsidence at a rate ranging between 1.6 and 1.0 mm year^?1 up to 0.12 Myr and then decreased to 0.4 mm year^?1, as an average, up to present. Our results highlight that time resolution of the stratigraphic dataset deeply influences the order of magnitude obtained for the calculated subsidence rate. This is because subsidence seems to have worked through short‐lived peaks (in the order of 10⁵ years), alternating with long relatively quiescent intervals. This suggests caution when components of subsidence are deduced by subtracting long‐term to short‐term subsidence rate.     

Seismotectonics of strike–slip earthquakes within the deep crust of southern Italy: Geometry, kinematics, stress field and crustal rheology of the Potenza 1990–1991 seismic sequences (Mmax 5.7)

We present a revision and a seismotectonic interpretation of deep crust strike–slip earthquake sequences that occurred in 1990–1991 in the Southern Apennines (Potenza area). The revision is motivated by: i) the striking similarity to a seismic sequence that occurred in 2002  140 km NNW, in an analogous tectonic context (Molise area), suggesting a common seismotectonic environment of regional importance; ii) the close proximity of such deep strike–slip seismicity with shallow extensional seismicity (Apennine area); and iii) the lack of knowledge about the mechanical properties of the crust that might justify the observed crustal seismicity. A comparison between the revised 1990–1991 earthquakes and the 2002 earthquakes, as well as the integration of seismological data with a rheological analysis offer new constraints on the regional seismotectonic context of crustal seismicity in the Southern Apennines. The seismological revision consists of a relocation of the aftershock sequences based on newly constrained velocity models. New focal mechanisms of the aftershocks are computed and the active state of stress is constrained via the use of a stress inversion technique. The relationships among the observed seismicity, the crustal structure of the Southern Apennines, and the rheological layering are analysed along a crustal section crossing southern Italy, by computing geotherms and two-mechanism (brittle frictional vs. ductile plastic strength) rheological profiles. The 1990–1991 seismicity is concentrated in a well-defined depth range (mostly between 15 and 23 km depths). This depth range corresponds to the upper pat of the middle crust underlying the Apulian sedimentary cover, in the footwall of the easternmost Apennine thrust system. The 3D distribution of the aftershocks, the fault kinematics, and the stress inversion indicate the activation of a right-lateral strike–slip fault striking N100°E under a stress field characterized by a sub-horizontal N142°-trending σ1 and a sub-horizontal N232°-trending σ3, very similar to the known stress field of the Gargano seismic zone in the Apulian foreland. The apparent anomalous depths of the earthquakes (> 15 km) and the confinement within a relatively narrow depth range are explained by the crustal rheology, which consists of a strong brittle layer at mid crustal depths sandwiched between two plastic horizons. This articulated rheological stratification is typical of the central part of the Southern Apennine crust, where the Apulian crust is overthrusted by Apennine units. Both the Potenza 1990–1991 and the Molise 2002 seismic sequences can be interpreted to be due to crustal E–W fault zones within the Apulian crust inherited from previous tectonic phases and overthrusted by Apennine units during the Late Pliocene–Middle Pleistocene. The present strike–slip tectonic regime reactivated these fault zones and caused them to move with an uneven mechanical behaviour; brittle seismogenic faulting is confined to the strong brittle part of the middle crust. This strong brittle layer might also act as a stress guide able to laterally transmit the deviatoric stresses responsible for the strike–slip regime in the Apulian crust and may explain the close proximity (nearly overlapping) of the strike–slip and normal faulting regimes in the Southern Apennines. From a methodological point of view, it seems that rather simple two-mechanism rheological profiles, though affected by uncertainties, are still a useful tool for estimating the rheological properties and likely seismogenic behaviour of the crust.     

A new late glacial to early Holocene palaeobotanical and archaeological record in the Eastern Pre‐Alps: the Palughetto basin (Cansiglio Plateau,Italy)

A late glacial to early Holocene lacustrine and peat succession, rich in conifer remains and including some palaeolithic flint artefacts, has been investigated in the Palughetto intermorainic basin (Venetian Pre‐Alps). The geomorphological and stratigraphical relationships, ¹⁴C dates and pollen analyses allow a reconstruction of the environmental history of the basin and provide significant insights into the reforestation and peopling of the Pre‐Alps. The onset of peat accumulation is dated to 14.4–14.1 kyr cal. BP, coinciding with reforestation at middle altitudes that immediately post‐dates the immigration of Larix decidua and Picea abies subsp. europaea. Plant macrofossils point to the expansion of spruce about 14.3 kyr cal. BP, so far one of the earliest directly dated in the late glacial period of southern Europe. The previous hypothesis of an early Holocene spruce immigration in the Southern Alps from Slovenia needs reconsideration. Organic sedimentation stopped at the end of the Younger Dryas and was followed by the evolution of hydromorphic soils containing lithic artefacts, anthropic structures and wood charcoal. The typological features of the flint implements refer human occupation of the site to the end of the recent Epigravettian. Charcoals yielded dates either consistent with, or younger than, the archaeological chronology, in the early and middle Holocene. Copyright © 2000 John Wiley & Sons, Ltd.     

Tectonic vs. climate forcing in the Cenozoic sedimentary evolution of a foreland basin (Eastern Southalpine system, Italy)

This paper discusses the Cenozoic interaction of regional tectonics and climate changes. These processes were responsible for mass flux from mountain belts to depositional basins in the eastern Alpine retro‐foreland basin (Venetian–Friulian Basin). Our discussion is based on the depositional architecture and basin‐scale depositional rate curves obtained from the decompacted thicknesses of stratigraphic units. We compare these data with the timing of tectonic deformation in the surrounding mountain ranges and the chronology of both long‐term trends and short‐term high‐magnitude (‘aberrant’) episodes of climate change. Our results confirm that climate forcing (and especially aberrant episodes) impacted the depositional evolution of the basin, but that tectonics was the main factor driving sediment flux in the basin up to the Late Miocene. The depositional rate remained below 0.1 mm year^?1 on average from the Eocene to the Miocene, peaking at around 0.36 mm year^?1, during periods of maximum tectonic activity in the eastern Southern Alps. This dynamic strongly changed during the Pliocene–Pleistocene, when the basin‐scale depositional rate increased to an average of 0.26 mm year^?1 (Pliocene) and 0.73 mm year^?1 (Pleistocene). This result fits nicely with the long‐term global cooling trend recorded during this time interval. Nevertheless, we note that the timing of the observed increase may be connected with the presumed onset of major glaciations in the southern flank of the Alps (0.7–0.9 Ma), the acceleration of the global cooling trend (since 3–4 Ma) and climate variability (in terms of magnitude and frequency). All these factors suggest that combined high‐frequency and high‐magnitude cooling–warming cycles are particularly powerful in promoting erosion in mid‐latitude mountain belts and therefore in increasing the sediment flux in foreland basins.     

Energy partitioning during seismic slip in pseudotachylyte-bearing faults (Gole Larghe Fault, Adamello, Italy)

The determination of the earthquake energy budget remains a challenging issue for Earth scientists, as understanding the partitioning of energy is a key towards the understanding the physics of earthquakes. Here we estimate the partition of the mechanical work density into heat and surface energy (energy required to create new fracture surface) during seismic slip on a location along a fault. Earthquake energy partitioning is determined from field and microstructural analyses of a fault segment decorated by pseudotachylyte (solidified friction-induced melt produced during seismic slip) exhumed from a depth of ~ 10 km—typical for earthquake hypocenters in the continental crust. Frictional heat per unit fault area estimated from the thickness of pseudotachylytes is ~ 27 MJ m^− 2. Surface energy, estimated from microcrack density inside clast (i.e., cracked grains) entrapped in the pseudotachylyte and in the fault wall rock, ranges between 0.10 and 0.85 MJ m^− 2. Our estimates for the studied fault segment suggest that ~ 97–99% of the energy was dissipated as heat during seismic slip. We conclude that at 10 km depth, less than 3% of the total mechanical work density is adsorbed as surface energy on the fault plane during earthquake rupture.     

Immunotoxicity of the xenoestrogen 4-nonylphenol to the cockle Cerastoderma glaucum

The in vivo effects of 4-nonylphenol (NP) on functional responses of haemocytes from the cockle Cerastoderma glaucum were investigated after 7 days exposure to sublethal NP concentrations (0, 0+acetone, 0.0125, 0.025, 0.05 and 0.1 mg/l NP). Haemocytes from both controls and exposed cockles were collected, and the effects of NP on total haemocyte count (THC) and volume of circulating cells, intracellular superoxide anion () levels, acid phosphatase and lysozyme-like activities in both haemocyte lysate (HL) and cell-free haemolymph (CFH) were evaluated. Exposure of cockles to 0.1 mg/l NP significantly increased THC (p < 0.05) with respect to controls. Analysis of haemocyte size frequency distribution showed that the haemocyte fraction of about 7–8 μm in diameter and 250 femtolitres in volume increased markedly in cockles exposed to the highest NP concentration tested. Apoptosis resulting in cell volume reduction in NP-exposed animals cannot be excluded. No statistically significant variation in intracellular levels was observed. Conversely, significant increases (p < 0.05) in acid phosphatase activity were observed in CFH from 0.05 and 0.1 mg/l NP-exposed animals; no significant differences in enzyme activity were recorded in HL. Lysozyme-like activity also increased significantly in CFH from cockles exposed to 0.05 mg/l NP (p < 0.05) and 0.1 mg/l NP (p < 0.001). Instead, lysozyme-like activity decreased significantly (p < 0.05) in the HL of animals exposed to 0.05 mg/l NP. Our results suggest that NP induces variations in the functional responses of haemocytes of C. glaucum, mainly by reducing cell membrane stability and promoting cell degranulation.     

A numerical study on seismic damage of masonry fortresses

Studies oriented to restoration and conservation of historical monumental buildings have recourse to structural analysis as a way to investigate the genuine structural features of the construction, to better understand its present condition and actual causes of existing damage, to estimate its safety conditions and to determine necessary remedial measures. Based on this background, this paper discusses on the seismic vulnerability of masonry fortresses by means of an analysis methodology based on three different analytical procedures, according to an increased knowledge of the structure. As a relevant case study the Albornoz fortress, a 14th stone masonry construction located in central Italy, was selected. Initially, the strategy proposed to perform this task was aimed at testing and developing an expeditious and non-destructive procedure to evaluate both the seismic vulnerability and the main mechanical properties of the different masonry typologies. The macroscale structural behavior of the fortress was then evaluated through a nonlinear static analysis (pushover) and a more simple approach based on the kinematic theorems of the limit analysis. From this point of view, by comparing the capacity of the construction to withstand lateral loads with the expected demands resulting from seismic actions, these methods provided a highly effective means of verifying the safety of the masonry structure and its vulnerability to extensive damage and collapse.     

Surface electrical resistivity tomography and hydrogeological characterization to constrain groundwater flow modeling in an agricultural field site near Ferrara (Italy)

A portion of an unconfined alluvial aquifer located in the Padana Plain (Italy) was characterized following an integrated hydro-geophysical approach. Initially an electrical resistivity tomography (ERT) survey was employed to localize the boundaries of a modest paleo-channel body and to design the installation of a groundwater monitoring network. Multilevel slug-tests were performed to estimate the aquifer’s saturated hydraulic conductivities. Determined permeability values together with electrical resistivity data were correlated. The correlation resulted in a site specific bi-logarithmic linear relationship. Based on this relationship, punctually determined hydraulic conductivities were spatially extended over the studied flow domain. Finally, continuously measured piezometric heads were used to calibrate a 3D flow model. Sensitivity analysis was performed to confirm the reliability of the reconstructed permeability field, as well as, to assess the minimum number of direct measurements needed to safely characterize the selected aquifer portion. The integration of the ERT survey results with the classical hydrogeological tests can be conveniently applied to constrain the permeability field during flow model calibration. Although the applicability of the determined relationship is site specific, the followed procedure is useful especially when there is a need to optimize the available resources and in case of small-scale pilot studies.     

Ab-initio structure, energy and stable Fe isotope equilibrium fractionation of some geochemically relevant H-O-Fe complexes

The hexa-aqua complexes [Fe(H₂O)_6−m−n(OH)_n]⁽²⁻ⁿ⁾⁺n = 0 → 3, m = 0 → 6 − n; [Fe(H₂O)_6−m−n(OH)_n]⁽³⁻ⁿ⁾⁺n = 0 → 4, m = 0 → 6 − n were investigated by ab-initio methods with the aim of determining their ground-state geometries, total energies and vibrational properties by treating their inner solvation shell as part of their gaseous precursor¹ (or “hybrid approach”). After a gas-phase energy optimization within the Density Functional Theory (DFT), the molecules were surrounded by a dielectric representing the Reaction Field through an implicit Polarized Continuum Model (PCM). The exploration of several structural ligand arrangements allowed us to quantify the relative stabilities of the various ionic species and the role of the various forms of energy (solute-solvent electronic interaction, cavitation, dispersion, repulsion, liberation free energy) that contribute to stabilize the aqueous complexes. A comparison with experimental thermochemistries showed that ab-initio gas-phase + solvation energies are quite consistent with experimental evidence and allow the depiction of the most stable form in solution and the eventual configurational disorder of water/hydroxyl species around central cations. A vibrational analysis performed on the ⁵⁴Fe, ⁵⁶Fe, ⁵⁷Fe and ⁵⁸Fe isotopomers indicated important separative effects systematically affected by the extent of deprotonation. The role of the system’s redox state (fO₂) and acidity (pH) on the isotopic imprinting of the aqueous species in solution was investigated by coupling the separative effects with speciation calculations. The observed systematics provided a tool of general utility in the interpretation of the iron isotopic signature of natural waters. Applications to the interpretation of isotopic fractionation in solution dictated by redox equilibria and to the significance of the Fe-isotopic imprinting of Banded Iron Formations are given.