Lavas and their mantle xenoliths from intracratonic Eastern Paraguay (South America Platform) and Andean Domain, NW-Argentina: a comparative review

Protogranular spinel-peridotite mantle xenoliths and their host sodic alkaline lavas of Cretaceous to Paleogene age occur at the same latitude ≈26°S in central eastern Paraguay and Andes. Na- alkaline lavas from both regions display similar geochemical features, differing mainly by higher Rb content of the Paraguayan samples. Sr, Nd, and Pb isotope ratios are also similar with predominant trends from depleted to enriched mantle components. The mantle xenoliths are divided into two main suites, i.e. relatively low in potassium and incompatible elements, and high in potassium and incompatible elements. The suite high in potassium occurs only in Paraguay. Compositions of both suites range from lherzolite to dunite indicating variable “melt extraction”. Clinopyroxenes from the xenoliths display variable trace element enrichment/depletion patterns compared with the pattern of average primitive mantle. Enrichment in LREE and Sr coupled with depletion of Nb, Ti and Zr in xenoliths from both areas are attributed to asthenospheric metasomatic fluids affecting the lithospheric mantle. Metasomatism is apparent in the sieve textures and glassy drops in clinopyroxenes, by glassy patches with associated primary carbonates in Paraguayan xenoliths. Trace element geochemistry and thermobarometric data indicate lack of interaction between xenoliths and host lavas, due to their rapid ascent. Sr and Nd isotope signatures of the Andean and Paraguayan xenoliths and host volcanic rocks plot mainly into the field of depleted mantle and show some compositional overlap. The Andean samples indicate a generally slightly more depleted mantle lithosphere. Pb isotope signatures in xenoliths and host volcanic rocks indicate the existence of a radiogenic Pb source (high U/Pb component in the source) in both areas. In spite of the distinct tectonic settings, generally compressive in the Central Andes (but extensional in a back-arc environment), and extensional in Eastern Paraguay (rifting environment in an intercratonic area), lavas and host xenoliths from both regions are similar in terms of geochemical and isotopic characteristics.     

GALEX catalogs of UV sources: statistical properties and sample science applications: hot white dwarfs in the Milky Way

We describe the content and properties of UV source catalogs from GALEX’s All-Sky Imaging Survey (AIS, 5σ depth ≈19.9(FUV)/20.8(NUV) mag, in the AB system) and Medium-depth Imaging Survey (MIS, 5σ depth ≈22.6(FUV)/22.7(NUV) mag), constructed by Bianchi L., et al.: Mon. Not. R. Astron. Soc. (2010, in press). The catalogs contain 65.3/12.6 million (AIS/MIS) unique UV sources with photometric error in NUV less than 0.5 mag, over 21?435(AIS)/1579(MIS) square degrees. Matched optical data from GSC-II provide additional B, R, I photometry for the brightest sources, and SDSS provides u g r i z photometry over 7325(AIS)/1103(MIS) square degrees overlap areas. We discuss statistical properties that are relevant for understanding sample selection biases and completeness, in potential science applications of these catalogs. The FUV (1344–1786 Å) and NUV (1771–2831 Å) photometry uniquely enable selection of the hottest stellar objects, in particular hot white dwarfs (WD), which are elusive at optical wavelengths because of their hot temperatures and faint luminosities. From the GALEX-SDSS matched sources we selected ～40?000 Milky Way (MW) stars hotter than about 18?000 K (FUV-NUV?相似文献   

A comparison of selected Precambrian Brazilian chromitites: Chromite, PGE-PGM, and Re/Os as parental source indicators

Mineralogical and geochemical studies were carried out in chromitites belonging to the mafic–ultramafic bodies of Niquelândia, Luanga, and Campo Formoso, which are, respectively, included in the Goiás Massif and the Amazon and São Francisco cratons. The main platinum-group minerals (PGM) included or associated with chromite grains are laurite in Niquelândia and Campo Formoso and sperrylite and braggite in Luanga. The most common primary base metal sulfides (BMS) are pentlandite, chalcopyrite, and minor pyrrhotite. Also present are base metal alloys (BMA), such as awaruite, and the BMS millerite, pyrite, and copper as secondary mineral phases linked to later alteration process. The Luanga chromites display the lowest Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios. The chondrite-normalized profiles are strongly enriched in the platinum PGE subgroup (PPGE, Pt, Pd, Rh). The average Pd/Ir ratio (24.2) and ¹⁸⁷Os/¹⁸⁸Os values (0.17869–0.18584) are very high. Niquelândia chromites have higher Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios than Luanga. Its PGE contents are low and chondrite-normalized profiles depleted, mainly in the PPGE subgroup. The average Pd/Ir ratio (0.45) and ¹⁸⁷Os/¹⁸⁸Os values (0.12598–0.12777) are low. Campo Formoso chromites have the highest Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios; its average Pd/Ir ratio (0.72) and chondrite-normalized profiles (except the pronounced Ru spike) are closer to those of Niquelândia. The remarkable differences in terms of chromite bulk-composition, PGE contents and patterns, Pd/Ir ratios, and ¹⁸⁷Os/¹⁸⁸Os values associated with probable distinctions in the inferred geochemical compositions of the respective parental magmas indicate that the Luanga and Niquelândia complexes originated from distinct parental sources. Geochemical and isotopic features indicate that Luanga chromitites and associated rocks are consistent with a parental magma, either originated from an enriched mantle reservoir or strongly contaminated, whereas Niquelândia derives from a depleted mantle source, which displays a slightly positive Os anomaly.     

Evidence of mantle metasomatism and heterogeneity from peridotite inclusions of northeastern Brazil and Paraguay

Textural-petrographic features, major and trace elements and mineral chemistry are reported for spinel-peridotite xenoliths from northeastern Brazil (NE-suite) and Paraguay (PY-suite).Variation trends defined by bulk rock and mineral chemistry are consistent with the effects of variable degree of high-pressure melting for both suites.The PY-suite strongly differs from the NE-suite by its very high contents of incompatible elements. This different whole-rock chemistry is related to the presence of glassy-microcrystalline blebs which are interpreted as remains of pre-existing hydrous phases of metasomatic origin. The difference between the two suites is also recorded in the chemistry of pyroxenes and spinels, which develop along different variation patterns.Although the suites partially overlap in their ranges ofmg_opx (Mg/(Fe²⁺ + Fe³⁺) ratio in orthopyroxenes), the PY-suite is, on the average, moremg_opx rich (residual) than the NE-suite. Within the PY-suite a rough positive correlation exists between degree of residuality and degree of metasomatic effects.The sharp differences between the NE-suite and the PY-suite imply mantle heterogeneity on regional scale, whereas the variability within each suite is essentially related to different degrees of melting and/or metasomatism and imply mantle heterogeneity on local scale.     

The growth and contamination mechanism of the Cana Brava layered mafic-ultramafic complex: new field and geochemical evidences

Mineralogy and Petrology - The Cana Brava complex is the northernmost of three layered complexes outcropping in the Goiás state (central Brasil). New field and geochemical evidences suggest...     

The Direct Determination of Rare Earth Elements in Basaltic and Related Rocks using ICP-MS: Testing the Efficiency of Microwave Oven Sample Decomposition Procedures

Tests are described showing the results obtained for the determination of REE and the trace elements Rb, Y, Zr, Nb, Cs, Ba, Hf, Ta, Pb, Th and U with ICP-MS methodology for nine basaltic reference materials, and thirteen basalts and amphibolites from the mafic-ultramafic Niquelândia Complex, central Brazil. Sample decomposition for the reference materials was performed by microwave oven digestion (HF and HNO₃, 100 mg of sample), and that for the Niquelândia samples also by Parr bomb treatment (5 days at 200°C, 40 mg of sample). Results for the reference materials were similar to published values, thus showing that the microwave technique can be used with confidence for basaltic rocks. No fluoride precipitates were observed in the microwave-digested solutions. Total recovery of elements, including Zr and Hf, was obtained for the Niquelândia samples, with the exception of an amphibolite. For this latter sample, the Parr method achieved a total digestion, but not so the microwave decomposition; losses, however, were observed only for Zr and Hf, indicating difficulty in dissolving Zr-bearing minerals by microwave acid attack.