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121.
Juan Carlos Afonso Giorgio Ranalli Manel Fernàndez William L. Griffin Suzanne Y. O'Reilly Ulrich Faul 《Earth and Planetary Science Letters》2010,289(3-4):606-618
We use thermodynamically self-consistent and hybrid methods to analyze the correlation of important physical parameters (e.g. bulk density, elastic moduli) with bulk Mg# and modal composition in mantle peridotites at upper mantle conditions. Temperature (anharmonic and anelastic), pressure and compositional derivatives for all these parameters are evaluated. The results show that the widely used correlations between Vp/Vs and Mg# in peridotites are strictly valid only for garnet-bearing assemblages at temperatures < 900 °C. The correlation breaks down when: i) spinel is the stable Al-rich phase in the assemblage and ii) when anelastic attenuation of seismic velocities becomes important (T ? 900 °C). This implies that the range of applicability of published Vp/Vs–Mg# correlations for the upper mantle is limited to a depth interval between the spinel–garnet phase transition and the 900 °C isotherm. We use numerical simulations to show that this depth interval is virtually nonexistent in lithospheres thinner than ~ 140 km and can comprise up to ~ 50% of the lithospheric mantle in thick (> 220 km) lithospheric domains. In addition, we show that for most of the upper mantle the expected Δ(Vp/Vs) values associated with compositional variations are smaller than the resolution limit of current seismological methods. All these considerations suggest that the Vp/Vs ratio is not a reliable measure of compositional variations and that for large parts of the upper mantle compositional anomalies cannot be separated from thermal anomalies on the basis of seismological studies only. We further confirm that the only reliable indicator of compositional anomalies in a peridotitic mantle is the ratio of density to shear wave velocities (ρ/Vs). Our results demonstrate that geophysical–petrological models (forward or inverse) that model these two fields (i.e. density and Vs) self-consistently within a robust thermodynamic framework are necessary for characterizing the small-scale thermal and compositional structure of the lithosphere and sublithospheric upper mantle. 相似文献
122.
123.
The Finero phlogopite-peridotite massif: an example of subduction-related metasomatism 总被引:13,自引:0,他引:13
Alberto Zanetti Maurizio Mazzucchelli Giorgio Rivalenti Riccardo Vannucci 《Contributions to Mineralogy and Petrology》1999,134(2-3):107-122
The Finero peridotite massif is a harzburgite that suffered a dramatic metasomatic enrichment resulting in the pervasive
presence of amphibole and phlogopite and in the sporadic occurrence of apatite and carbonate (dolomite)-bearing domains. Pyroxenite
(websterite) dykes also contain phlogopite and amphibole, but are rare. Peridotite bulk-rock composition retained highly depleted
major element characteristics, but was enriched in K, Rb, Ba, Sr, LREE (light rare earth elements) (LaN/YbN = 8–17) and depleted in Nb. It has high radiogenic Sr (87Sr/86Sr(270) = 0.7055–0.7093), low radiogenic Nd (ɛNd(270) = −1 to −3) and EMII-like Pb isotopes. Two pyroxenite – peridotite sections examined in detail show the virtual absence of
major and trace element gradients in the mineral phases. In both rock types, pyroxenes and olivines have the most unfertile
major element composition observed in Ivrea peridotites, spinels are the richest in Cr, and amphibole is pargasite. Clinopyroxenes
exhibit LREE-enriched patterns (LaN/YbN ∼16), negative Ti and Zr and generally positive Sr anomaly. Amphibole has similar characteristics, except a weak negative
Sr anomaly, but incompatible element concentration ∼1.9 (Sr) to ∼7.9 (Ti) times higher than that of coexisting clinopyroxene.
Marked geochemical gradients occur toward apatite and carbonate-bearing domains which are randomly distributed in both the
sections examined. In these regions, pyroxenes and amphibole (edenite) are lower in mg## and higher in Na2O, and spinels and phlogopite are richer in Cr2O3. Both the mineral assemblage and the incompatible trace element characteristics of the mineral phases recall the typical
signatures of “carbonatite” metasomatism (HFSE depletion, Sr, LILE and LREE enrichment). Clinopyroxene has higher REE and
Sr concentrations than amphibole (amph/cpxDREE,Sr = 0.7–0.9) and lower Ti and Zr concentrations. It is proposed that the petrographic and geochemical features observed at
Finero are consistent with a subduction environment. The lack of chemical gradients between pyroxenite and peridotite is explained
by a model where melts derived from an eclogite-facies slab infiltrate the overhanging harzburgitic mantle wedge and, because
of the special thermal structure of subduction zones, become heated to the temperature of the peridotite. If the resulting
temperature is above that of the incipient melting of the hydrous peridotite system, the slab-derived melt equilibrates with
the harzburgite and a crystal mush consisting of harzburgite and a silica saturated, hydrous melt is formed. During cooling,
the crystal mush crystallizes producing the observed sequence of mineral phases and their observed chemical characteristics.
In this context pyroxenites are regions of higher concentration of the melt in equilibrium with the harzburgite and not passage-ways
through which exotic melts percolated. Only negligible chemical gradients can appear as an effect of the crystallization process,
which also accounts for the high amphibole/clinopyroxene incompatible trace element ratios. The major element refractory composition
is explained by an initially high peridotite/melt ratio. The apatite, carbonate-bearing domains are the result of the presence
of some CO2 in the slab-derived melt. The CO2/H2O ratio in the peridotite mush increased by crystallization of hydrous phases (amphibole and phlogopite) locally resulting
in the unmixing of a late carbonate fluid. The proposed scenario is consistent with subduction of probably Variscan age and
with the occurrence of modal metasomatism before peridotite incorporation in the crust.
Received: 20 July 1998 / Accepted: 28 October 1998 相似文献
124.
Abstract— Accompanied by loud thunder at about 1.30 pm (local time) on 3 February 1974, a single stone weighing approx. 480 g was seen to fall and was recovered near the Jolomba village, Huambo District, Angola. The stone is strongly brecciated, has dark-greyish angular fragments within a lighter matrix and does not exhibit any chondritic textures. Jolomba consists of olivine (Fa 31), orthopyroxene (Fs 25), sodic plagioclase (An 11), sulphides (troilite), very scarce nickel-iron (Ni up to 56%), oxides (chromite and ilmenite) and apatite. Pervasive fracturing of silicates suggests that Jolomba suffered strong brecciation and partial recrystallization. Mineralogy and bulk chemical analysis indicate that Jolomba belongs to the LL group of chondrites (amphoterites). Uniform olivine and pyroxene composition, well-crystallized plagioclase and textural features in general indicate that Jolomba belongs to the petrologic type 6. 相似文献
125.
Giorgio Rivalenti Maurizio Mazzucchelli Vicente Antonio Vitorio Girardi Giancarlo Cavazzini Cristina Finatti Maria Adelaide Barbieri Wilson Teixeira 《Lithos》1998,43(4):235-265
Paleoproterozoic basaltic, andesitic and rhyolitic dykes crosscut the Archaean Carajás basement. Basalts are distinguished into a high and a low TiO2 group (HTi and LTi), each group consisting of geochemically distinct NE- and NW-trending swarms. The HTi dykes are evolved transitional basalts having essentially EMORB-type geochemistry. The LTi basalts are tholeiites (NE-trending swarm) and high-Al basalts (NW-trending swarm) displaying incompatible trace elements patterns with variably negative Nb anomaly, enrichment in Rb, Ba, K (LILE) and La, Ce and Nd (LREE) and positive Sr anomaly. With respect to orogenic analogues, andesites have lower Al2O3, CaO and Ni, higher FeO, LILE, LREE, Nb, Zr and Ti and negative Sr anomaly. Rhyolites have geochemical characteristics comparable with those of A-type granites. At 1.8 Ga,
ranges from 0.700 to 0.705 in the HTi basalts and from 0.700 to 0.704 in the LTi group. Andesites define an isochron of 1874±110 Ma (Sro=0.7038±0.0010). Rhyolites from Southern and Northern Carajás define two isochrons of 1802±130 Ma (Sro=0.7062±0.0046) and 1535±82 Ga (Sro=0.7625) respectively, the younger date being interpreted as resetting of the Rb–Sr isotopic system. We propose a petrogenetic model relating LTi basalts with melting of lithospheric mantle metasomatized by acid melts derived from incipient melting of eclogites, representing in turn the subsolidus product of basaltic batches trapped in the mantle. The HTi basalts are explained by melting of the lithospheric mantle containing the complementary residual eclogite. Andesite petrogenesis is consistent with crystal fractionation from a high-Mg andesite parent derived from a mantle source more extensively metasomatized by eclogite-derived melts. Rhyolite composition is consistent with low melting degree of the basement rocks. The basalt–andesite–rhyolite dykes may represent the effects of crustal extension and arching in Carajás, which produced the anorogenic acid to intermediate magmatism (Uatumã group) and affecting a large part of the Amazon craton between 1.85 and 1.7 Ga. 相似文献
126.
Giorgio Matt Enrico Costa Marco Feroci Tomaso Belloni Marco Tavani 《New Astronomy Reviews》1998,42(9-10)
Results from a BeppoSAX observational campaign on GRS 1915+105, performed in October/November 1996, are presented. The source was observed 10 times (nine 10 ksec snapshots, one 100 ksec long observation). The broad band spectral analysis reveals a complex spectrum, including Compton reflection and an iron emission line, probably originating from a relativistic disc. 相似文献
127.
On the Lagrangian and Eulerian Time Scales of Turbulence Within a Two-Dimensional Array of Obstacles
Di Bernardino Annalisa Monti Paolo Leuzzi Giovanni Querzoli Giorgio 《Boundary-Layer Meteorology》2022,184(3):375-379
Boundary-Layer Meteorology - Fields of Lagrangian ( $$T^{L}$$ ) and Eulerian ( $$T^{E}$$ ) time scales of the turbulence within a regular array of two-dimensional obstacles of unit aspect ratio... 相似文献
128.
Luisa?Frati Giorgio?Brunialti Stefano?LoppiEmail author 《Journal of Atmospheric Chemistry》2005,52(3):221-230
The results of a transplant experiment with the fruticose lichen Evernia prunastri aimed at monitoring the trends of trace elements deposition in a repeated biomonitoring study are reported. Data comparability
between the two surveys and interpretation of the results were addressed in this study. The ratio between the concentration
of each element after the exposure and in control samples prior to exposure (exposed-to-control ratio, EC ratio), as well
as an appropriate interpretative scale, were adopted as a means of determining the temporal trends of element accumulation
by lichen transplants. The results showed that the method adopted is indeed a reliable tool, pinpointing a Zn smelting plant
and an oil refinery as principal pollution sources in the area, which indicate that elements associated with the former were
similarly accumulated in both 2002 and 2003, while elements associated with the latter tended to decrease in 2003. 相似文献
129.
Fulvio?TononEmail author Armando?Mammino Daniele?Vanni Pier?Giorgio?Borghi Alessandro?Bertero 《Geotechnical and Geological Engineering》2005,23(5):487-518
The Pretunnel technology allows the final or preliminary lining to be built ahead of a tunnel face. The paper shows how this technology has been used for mechanizing the full-face excavation of large tunnels in difficult ground conditions with minimum settlements. Analytical methods are presented for the analysis of the lining both in deep and shallow applications. Fields of applicability are established using results of parametric studies based on the methods proposed. 相似文献
130.
Giorgio?RivalentiEmail author Alberto?Zanetti Maurizio?Mazzucchelli Riccardo?Vannucci Carlos?A.?Cingolani 《Contributions to Mineralogy and Petrology》2004,147(6):647-670
Amphibole ± phlogopite ± apatite-bearing mantle xenoliths at Gobernador Gregores display modal, bulk-rock and phase geochemical characteristics held as indicators of carbonatitic metasomatism. However, part of these xenoliths has high TiO2/Al2O3 and those displaying the most pronounced carbonatitic geochemical markers modally trend towards harzburgite. Bulk-rock, clinopyroxene and amphibole show Zr, Hf and Ti negative anomalies, which increase at decreasing Na2O and high field strength elements (HFSE) concentrations. Steady variation trends between xenoliths which have and do not have carbonatitic characteristics suggest a control by reactive porous flow of only one agent, inferred to be initially a ne-normative hydrous basalt (because of the presence of wehrlites) evolving towards silica saturation. Variation trends exhibit cusps when amphibole appears in the mode. Appearance of amphibole may explain the Ti anomaly variations, but not those of Zr and Hf. Numerical modelling [Plate Model (Vernières et al. in J Geophys Res 102:24771–24784, 1997)] gives results consistent with the observed geochemical features by assuming the presence of loveringite. Modest HFSE anomalies in the infiltrating melt may be acquired during percolation in the garnet-facies.In memory of Carlo Rivalenti 相似文献