Contribution of Sponge Spicules to the Composition of Biogenic Silica in the Ligurian Sea

Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.     

Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.     

Estimate of the optimum measuring time in the synchronous photometry of optical sources

The note shows how to estimate accurately the optimum measuring time in the measurement of a periodical optical source by means of a synchronous photometer affected by phase-tracking error. The procedure used can be easily generalized to sources or signal patterns not considered here. The optimum number of scans to be averaged results to be typicallyN _opt≈0.5r/ɛ for an optical source of Lorentzian signal pattern, wherer is the duty cycle of the pulsed component and ɛ the relative truncation error of the local sync to the source period. Work supported by Consiglio Nazionale delle Ricerche, Gruppo Nazionale di Astronomia, Settore Tecnologie Astronomiche. Trieste Observatory — Instruments and Data Processing Group (4/76).     

Magnetic behavior of trioctahedral micas with different octahedral Fe ordering

This contribution is finalized at the discussion of the magnetic structure of two samples, belonging to phlogopite–annite [sample TK, chemical composition ^IV(Si_2.76Al_1.24) ^VI(Al_0.64Mg_0.72 $ {\text{Fe}}_{1.45}^{2 + } $ Mn_0.03Ti_0.15) (K_0.96Na_0.05) O_10.67 (OH)_1.31 Cl_0.02] and polylithionite–siderophyllite joints [sample PPB, chemical composition ^IV(Si_3.14Al_0.86)^VI(Al_0.75Mg_0.01 $ {\text{Fe}}_{1.03}^{2 + } $ $ {\text{Fe}}_{1.03}^{3 + } $ Mn_0.01Ti_0.01Li_1.09) (K_0.99Na_0.01) O_10.00 (OH)_0.65F_1.35]. Samples differ for Fe ordering in octahedral sites, Fe²⁺/(Fe²⁺?+?Fe³⁺) ratio, octahedral composition, defining a different environment around Fe cations, and layer symmetry. Spin-glass behavior was detected for both samples, as evidenced by the dependency of the temperature giving the peak in the susceptibility curve from the frequency of the applied alternating current magnetic field. The crystal chemical features are associated to the different temperature at which the maximum in magnetic susceptibility is observed: 6?K in TK, where Fe is disordered in all octahedral sites, and 8?K in PPB sample, showing a smaller and more regular coordination polyhedron for Fe, which is ordered in the trans-site and in one of the two cis-sites.     

Gentrification as space domestication. The High Line Art case

In this paper, we critically examine the role of artistic locational choices and practices in the context of gentrification processes in urban renewal contexts. We characterize gentrification as a form of domestication of space, and explore the extent to which artistic choices and practices relate to such process with reference to the deontological dilemma of legitimization within the art system vs. responsible empowerment of vulnerable local constituencies. We illustrate our argument with an analysis of the High Line Art project, and show how this can be considered as a textbook example of art-driven space domestication leading to brutal forms of gentrification. We comment on the threat that this provides to the social credibility of artistic practices as an agency of responsible social change.     

Measured performance of the application of EGNOS in the road traffic sector

European Geostationary Navigation Overlay Service (EGNOS) is a satellite-based system developed to improve the performance of GPS in the European region. It not only enhances the estimated positioning accuracy but also provides an integrity solution. We assess the EGNOS performance through analysis of real measurements, performed in different road user environments. We investigate the use of the integrity concept in future Global Navigation Satellite System (GNSS)-based applications in the road environment, considering both suburban and dense urban areas. The analysis is motivated by the fact that there is an increasing number of road applications, such as billing system, transportation of dangerous goods, remote tracking of trucks and snow plows, fleet management and “pay as you go” car insurances, where the system liability has to be guaranteed. The scope of the analysis is to investigate to which extent the use of the integrity concept can be used for such purpose; the assessment is based on real measurement campaigns in representative environments, providing statistical results in terms of accuracy and integrity, and in a wider sense of the feasibility of the use of EGNOS for augmenting the reliability of GNSS positioning for road applications.     

Low-pH waters discharging from submarine vents at Panarea Island (Aeolian Islands,southern Italy) after the 2002 gas blast: Origin of hydrothermal fluids and implications for volcanic surveillance

A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate (i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and (ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.     

Cell parameters of thermally treated anorthite. Al,Si configurations in the average structures of the high temperature calcic plagioclases

Thermal treatments of anorthite carried out at up to 1,547° C show that the unit cell parameter changes as a function of the treatment temperature. The best fit curve found by non-linear least squares analysis is: =91.419-(0.327·10^-6)T ²+(0.199·10^-12)T ⁴-(0.391·10)T ⁶. The results obtained support significant Al,Si disorder (Al0.10, where Al=t ₁(0)-1/3 [t ₁(m)+t ₂(0)+t ₂(m)], Ribbe 1975), in anorthite equilibrated near the melting point and confirm a high temperature series differentiated from the low temperature series for calcic plagioclases in the An₈₅–An₁₀₀ range also. In the plot vs. An-content the high and low temperature curves intersect at An₈₅ composition and progressively diverge in the An₈₅–An₁₀₀ range. The trends of the high and low temperature curves in this range are interpretable on the basis of the degree of Al, Si order in the average structures of calcic plagioclases.     

Focal mechanism inversion in the Giudicarie–Lessini seismotectonic region (Southern Alps, Italy): Insights on tectonic stress and strain

A set of 41 focal mechanisms (1989–2006) from P-wave first polarities is computed from relocated seismic events in the Giudicarie–Lessini region (Southern Alps). Estimated hypocentral depths vary from 3.1 to 20.8 km, for duration magnitudes (M_D) in the range 2.7–5.1. Stress and strain inversions are performed for two seismotectonic zones, namely G (Giudicarie) and L (Lessini). This subdivision is supported by geological evidence, seismicity distribution, and focal mechanism types. The available number of data (16 in G, 22 in L) does not make possible any further subdivisions. Seismotectonic zones G and L are undergoing different kinematic regimes: thrust with strike-slip component in G, and strike-slip in L. Principal stress and strain axes in each sub-region show similar orientations. The direction of maximum horizontal compressive stress is roughly perpendicular to the thrust fronts along the Giudicarie Belt in zone G, and compatible with right-lateral strike-slip reactivation of the faults belonging to the Schio-Vicenza system in zone L. On the whole, kinematic regimes and horizontal stress orientations show a good fit with other stress data from focal mechanisms and breakouts and with geodetic strain rate axes.     

Time dependence of negative buoyancy and the subduction of continental lithosphere

The time evolution of negative buoyancy of a subducting slab is modelled from the beginning of subduction under various kinematic conditions (dip angle and subduction velocity). The calculations take into account the thermal and density effects of the variations of the thermophysical parameters with temperature and pressure, and of phase transitions. The magnitude of the negative buoyancy increases during subduction of oceanic lithosphere, up to values in the (2–4) × 10¹³ N m⁻¹ range when the tip of the slab reaches a depth of 600–700 km. If continental material arrives at the trench and is subducted, the downward buoyancy decreases by an amount proportional to the volume of the subducted continental crust. Assuming that subduction stops when the buoyancy becomes zero, and that delamination of the continental crust or slab breakoff do not occur, the maximum downdip length of the subductable continental crust is estimated as a function of the dip angle, subduction velocity and geometry of the margin. In most cases, subduction of continental material down to depths of 100–250 km is possible, and continental subduction can continue for times up to 10–15 Ma if the velocity is low. These estimates are not significantly affected by the hypothetical occurrence of a metastable olivine wedge within the slab, and could be lower bounds if the lower continental crust is mafic and transforms to eclogite.