Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.     

Late Quaternary deformation on the island on Pantelleria: New constraints for the recent tectonic evolution of the Sicily Channel Rift (southern Italy)

Structural observations carried out on the volcanic Island of Pantelleria show that the tectonic setting is dominated by NNE trending normal faults and by NW-striking right-lateral strike-slip faults with normal component of motion controlled by a ≈N 100°E oriented extension. This mode of deformation also controls the development of the eruptive fissures, dykes and eruptive centres along NNE–SSW belts that may thus represent the surface response to crustal cracking with associated magma intrusions. Magmatic intrusions are also responsible for the impressive vertical deformations that affect during the Late Quaternary the south-eastern segment of the island and producing a large dome within the Pantelleria caldera complex. The results of the structural analysis carried out on the Island of Pantelleria also improves the general knowledge on the Late Quaternary tectonics of the entire Sicily Channel. ESE–WNW directed extension, responsible for both the tectonic and volcano-tectonic features of the Pantelleria Island, also characterizes, at a greater scale, the entire channel as shown by available geodetic and seismological data. This mode of extension reactivates the older NW–SE trending fault segments bounding the tectonic troughs of the Channel as right-lateral strike-slip faults and produces new NNE trending pure extensional features (normal faulting and cracking) that preferentially develop at the tip of the major strike-slip fault zones. We thus relate the Late Quaternary volcanism of the Pelagian Block magmatism to dilatational strain on the NNE-striking extensional features that develop on the pre-existing stretched area and propagate throughout the entire continental crust linking the already up-welled mantle with the surface.     

Markovian modeling of seismic damage accumulation

Analysis of civil structures at the scale of life‐cycle requires stochastic modeling of degradation. Phenomena causing structures to degrade are typically categorized as aging and point‐in‐time overloads. Earthquake effects are the members of the latter category this study deals with in the framework of performance‐based earthquake engineering (PBEE). The focus is structural seismic reliability, which requires modeling of the stochastic process describing damage progression, because of subsequent events, over time. The presented study explicitly addresses this issue via a Markov‐chain‐based approach, which is able to account for the change in seismic response of damaged structures (i.e. state‐dependent seismic fragility) as well as uncertainty in occurrence and intensity of earthquakes (i.e. seismic hazard). The state‐dependent vulnerability issue arises when the seismic hysteretic response is evolutionary and/or when the damage measure employed is such that the degradation increment probabilistically depends on the conditions of the structure at the time of the shock. The framework set up takes advantage also of the hypotheses of classical probabilistic seismic hazard analysis, allowing to separate the modeling of the process of occurrence of seismic shocks and the effect they produce on the structure. It is also discussed how the reliability assessment, which is in closed‐form, may be virtually extended to describe a generic age‐ and state‐dependent degradation process (e.g. including aging and/or when aftershock risk is of interest). Illustrative applications show the options to calibrate the model and its potential in the context of PBEE. Copyright © 2015 John Wiley & Sons, Ltd.     

PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

The seismic strength of the earth

Summary The seismic strength (resistance to sudden failure) of the seismically active regions of the crust and upper mantle is estimated and is found to be maximum at depths of 50 to 125 km. The pattern of strength versus depth can be explained in terms of lithospheric plate sinking beneath an ocean trench. The lack of earthquakes at depths larger than 700 km is probably due to decreasing shear stress rather than vanishing seismic strength.

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Résumé Dans cette communication on évalue la résistance à la rupture séismique des matériaux constituant l'écorce et le manteau supérieur de la Terre. Les résultats indiquent la présence d'un maximum à la profondeur de 50–125 km. La distribution de la résistance avec la profondeur peut être expliquée par la résorption de la lithosphère au-dessous d'un fossé océanique. L'absence de séismes dans les zones plus profondes (z>700 km) n'est pas due à la réduction de la résistance séismique, mais très probablement à l'insuffisance des tensions internes dans les matériaux.

     

Seismic behavior of single‐story asymmetric‐plan buildings under uniaxial excitation

The critical parameters that influence the nonlinear seismic response of asymmetric‐plan buildings are identified by evaluating the effects of different asymmetries that may characterize the structure of a building as well as exploring the influence of the ground motion features. First, the main findings reported in the literature on both the linear and nonlinear dynamic response of asymmetric‐plan buildings are presented. The common findings and the conflicting conclusions reached in different investigations are pointed out. Then, the results of comprehensive nonlinear dynamic analyses performed for evaluating the seismic response of systems characterized by different strength and stiffness configurations, representative of a large class of asymmetric‐plan buildings, are reported. Findings from the study indicate that the building response changes when moving from the linear to the nonlinear range, so that the seismic behavior of asymmetric‐plan buildings, apart from the source of asymmetry, can be always classified as irregular. Additionally, it was observed that as the seismic demands cause amplification of system nonlinearity with increasing earthquake intensity, the maximum displacement demand in the different resisting elements tends to be reached with the same deformed configuration of the system. The resultant of the seismic forces producing such a maximum demand is located at the center of resistance and corresponds to the collapse mechanism of the system that provides the maximum lateral strength in the exciting direction of the seismic action. Copyright © 2008 John Wiley & Sons, Ltd.     

Chlorinated compounds and polybrominated diphenyl ethers (PBDEs) in mussels (Mytilus galloprovincialis) collected from Apulia Region coasts

This project was carried out to assess the levels and spatial distribution of organochlorine compounds in the coastal marine environment, using mussels as bioindicators to evaluate the coastal water quality. Levels of polychlorobiphenils (PCB), chlorinated pesticides (DDT isomers, HCH isomers, Aldrin, Dieldrin, alfa-Endosulfan, Hexachlorobenzene, Pentachlorobenzene) and polybrominated diphenyl ethers (PBDEs) were determined in tissues from mussels (Mytilus galloprovincialis) collected along the Apulia Region coasts (Mediterranean Sea). Results indicate that contamination by organochlorine compounds is higher in mussels sampled in the Ionian Sea than in those from the Adriatic Sea, with PCB levels up to seven times higher in mussels from Ionian than from the Adriatic Sea. Although PCB levels were above the maximum values indicated by both European Community (EC) and National regulation in several sample sites, the PCB concentrations were particularly high in some stations, suggesting that these locations require a much specific attention. Conversely, results on the mussel contamination by PBDEs highlight their ubiquitous environmental distribution, and underline the need to establish the maximum level for these compounds in foodstuff, according to European Regulations.