Time-varying storm surges on Lorentz’s Wadden Sea networks

We present an idealized network model for storm surges in the Wadden Sea, specifically including a time-dependent wind forcing (wind speed and direction). This extends the classical work by H.A. Lorentz who only considered the equilibrium response to a steady wind forcing. The solutions obtained in the frequency domain for the linearized shallow-water equations in a channel are combined in an algebraic system for the network. The velocity scale that is used for the linearized friction coefficient is determined iteratively. The hindcast of the storm surge of 5 December 2013 produces credible time-varying results. The effects of storm and basin parameters on the peak surge elevation are the subject of a sensitivity analysis. The formulation in the frequency domain reveals which modes in the external forcing lead to the largest surge response at coastal stations. There appears to be a minimum storm duration, of about 3–4 h, that is required for a surge to attain its maximum elevation. The influence of the water levels at the North Sea inlets on the Wadden Sea surges decreases towards the shore. In contrast, the wind shearing generates its largest response near the shore, where the fetch length is at its maximum.     

Observations of the Takata flocculation reaction in serum of normal persons during the total eclipse of the sun,February 15, 1961

Summary Takata tests were performed simultaneously under and outside an iron screen before, during, and after the solar eclipse of 15^th February 1961. Under the screen, the rate of flocculation remained constant throughout the period of observation. Outside the screen it showed higher values before and after the eclipse but decreased during the eclipse reaching the same value as found under the screen.

---

Zusammenfassung Während der Sonnenfinsternis vom 15. Februar 1961 durchgeführte Versuche mit demTakata-Test außerhalb und unter einer Eisenabschirmung ergaben eine unveränderte Flockungszahl unter der Abschirmung vor, während und nach der Sonnenfinsternis, dagegen während der Sonnenfinsternis eine Abnahme der sonst bei Messungen außerhalb der Abschirmung festgestellten höheren Flockungszahl auf den unter der Abschirmung gefundenen Wert.

---

Résumé Lors de l'éclipse de soleil du 15 février 1961, l'auteur a effectué des tests deTakata sous un écran de fer et au-dehors du dit écran. Ces essais ont montré que, sous l'écran, l'indice de flocculation restait constant avant, pendant et après l'éclipse. Au-dehors de l'écran par contre, cet indice a nettement diminué durant l'éclipse. Il est normalement plus élevé au-dehors de l'écran que dessous.

     

The Albano maar lake (Colli Albani Volcano, Italy): recent volcanic activity and evidence of pre-Roman Age catastrophic lahar events

The evaluation of volcanic hazard in the Roman hinterland related to the quiescent Colli Albani Volcano has recently been the subject of renewed attention and several interpretations by many authors. However, very little was known of the recent history of the volcano, making such interpretations rather speculative. The most recent activity of Colli Albani Volcano originated from the Albano polygenetic maar lake, which erupted several phreatomagmatic units, the most recent of which, the Peperino Albano ignimbrite, has been dated at around 25 ka. An area of several square kilometers centered around Albano Lake is presently the site of shallow and frequent seismic activity and gaseous emission as well as hydrothermal activity and is therefore considered the most prone to geologic hazards. This paper presents new stratigraphic and geomorphologic data as well as age determinations that allow rejuvenation of the most recent activity of the Colli Albani Volcano, and particularly the Albano maar lake, to the Holocene. This study allows for the first time to identify a potential hazard related to the Albano maar lake withdrawal interpreted to be related to endogenous causes, namely CO₂ emission. The main results of the study are: (1) the Peperino Albano is not, as is generally believed, the last phreatomagmatic eruption from the Colli Albani Volcano; a previously unrecognized phreatomagmatic surge deposit has been identified overlying the paleosol at the top of the Peperino Albano and related lahar deposits; (2) two lahar deposits separated by paleosols top the stratigraphic succession and are dispersed only to the NW, corresponding to the lowest point of the maar rim, indicating that catastrophic hydrologic events occurred at the Albano Lake in recent times; rapid and substantial lake-level variations and lake withdrawal are reported by Roman historians and recorded by the stratigraphy of the Albano Lake lacustrine sediments; (3) microfracturing related to seismic energy release is linked to sudden variation of CO₂ flow and upwelling of hydrothermal fluids. These occurrences across the lake are the likely causes that triggered during Holocene several episodes of lake withdrawal, rising the water table and probably triggering convective rollover of the lake water.     

Solar Wind Velocity and Anisotropic Coronal Kinetic Temperature Measured with the O Vi Doublet Ratio

Doppler dimming of the Ovi resonance lines (1032 Å, 1037 Å) in an expanding corona is calculated including the pumping effect on the Ovi 1037.61 Å of both Cii lines at 1036.34 Å and 1037.02 Å, and the effect of the width of the absorption profiles of the coronal oxygen ions along the incident radiation. The pumping effect of the Cii line at 1036.34 Å allows us to extend to approximately 450 km s–1 the measurement of solar wind velocities with the Ovi line ratio technique. Since the emissivity ratio of the Ovi doublet depends on the width of the oxygen coronal absorbing profiles, this ratio can provide an accurate measurement of the solar wind velocity in the case that the width of the absorbing profile along the direction of the incident radiation is independently determined. However, if on the one hand the ratio of the emissivities of the Ovi doublet has limitations in probing the wind velocity, on the other hand it can be used as a diagnostics for inferring the velocity distribution of the coronal Ovi ions along the radial, and detecting possible velocity anisotropies. This diagnostics, applied to recent observational results, allows us to infer that the velocity distribution of the oxygen ions is much broader in the direction perpendicular to the magnetic field direction, and that the acceleration of the fast solar wind in the first 2 solar radii is high.     

Integrated use of biomarkers (acetylcholinesterase and antioxidant enzymes activities) in Mytilus galloprovincialis and Mullus barbatus in an Italian coastal marine area

The use of biomarkers to evaluate the biological effects of chemical pollutants in marine organisms represents a recent tool in the monitoring field responding to the need to detect and assess the effects of chemical contaminants on the biota. The aim of the present work was the field application of the integrated use of acetylcholinesterase (AChE) and antioxidant enzymes (catalase--CAT, glutathione peroxidase--GSH-Px), for detecting the possible exposure/effect induced by chemical pollutants in native marine organisms from a coastal marine area, represented by Salento Peninsula (Italy), that shows a coastline of high environmental value, but under constant urban pressure, including agriculture activities, widely diffused in the whole hinterland. Eight sampling stations were chosen: four not urbanized areas considered "uncontaminated" controls and four clearly exposed to anthropogenic impact. The bioindicator species studied were a sessile invertebrate, Mytilus galloprovincialis, and a benthic teleost fish, Mullus barbatus.AChE activity in M. galloprovincialis revealed significant differences among places; the minimum values observed (3.9+/-1.8 nmolmin(-1)mg(-1)) was about 50% reduced with respect to the maximum found (11.4+/-0.9 nmolmin(-1)mg(-1)). The reduction in AChE activity observed in two control stations could be explained by the leaching of pesticides into the sea from the agricultural lands. Moreover, the inhibition of AChE activity by heavy metals besides pesticides, can also explain the reduction of the enzymatic activity observed in an industrialized and harbour area. In M. galloprovincialis AChE activity showed a significant inverse correlation with catalase activity but not with glutathione peroxidase that did not significantly change in animals sampled from the eight stations. Also in M. barbatus AChE activity showed significant differences among places; it was inversely correlated with liver GSH-Px activity, but not with catalase activity, that did not show any significantly variation in animals sampled in the different stations.In conclusion, the integrated use of AChE and antioxidant enzymes (catalase or glutathione peroxidase) in M. galloprovincialis and M. barbatus, two species living in different compartment of marine coastal ecosystem, can find a useful application within the framework of marine coastal environment monitoring programs for detecting the possible exposure/effect induced by chemical pollutants, including pesticides, on living marine organisms.     

Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100°C: the influence of pH and oxygen fugacity

It is well established through field observations, experiments, and chemical models that oxidation (redox) state and pH exert a strong influence on the speciation of dissolved components and the solubility of minerals in hydrothermal fluids. log –pH diagrams were used to depict the influence of oxygen fugacity and pH on monocarboxylate- and dicarboxylate-transport of Pb and Zn in low-temperature (100°C) hydrothermal ore fluids that are related to diagenetic processes in deep sedimentary basins, and allow a first-order comparison of Pb and Zn transport among proposed model fluids for Mississippi Valley-type (MVT) and red-bed related base metal (RBRBM) deposits in terms of their approximate pH and conditions. To construct these diagrams, total Pb and Zn concentrations and Pb and Zn speciation were calculated as a function of log and pH for a composite ore-brine with concentrations of major elements, total sulfur, and total carbonate that approximate the composition of MVT and RBRBM model ore fluids and modern basinal brines. In addition to acetate and malonate complexation, complexes involving the ligands Cl^-, HS^-, H₂S, and OH^- were included in the model of calculated total metal concentration and metal speciation. Also, in the model, Zn and Pb are competing with the common-rock forming metals Ca, Mg, Na, Fe, and Al for the same ligands. Calculated total Pb concentration and calculated total Zn concentration are constrained by galena and sphalerite solubility, respectively. Isopleths, in log –pH space, of the concentration of Pb and concentration of Zn in carboxylate (acetate + malonate) complexes illustrate that the oxidized model fluids of T. H. Giordano (in Organic Acids in Geological Processes, ed. E. D. Pittman and M. D. Lewan, Springer-Verlag, New York, 1994, pp. 319–354) and G. M. Anderson (Econ. Geol., 1975, 70, 937–942) are capable of transporting sufficient amounts of Pb (up to 10 ppm) and Zn (up to 100 ppm) in the form of carboxylate complexes to form economic deposits of these metals. On the other hand, the reduced ore fluid models of D. A. Sverjensky (Econ. Geol., 1984, 79, 23–37) and T. H. Giordano and H. L. Barnes (Econ. Geol., 1981, 76, 2200–2211) can at best transport amounts of Pb and Zn, as carboxylate complexes, that are many orders of magnitude below the 1 to 10 ppm minimum required to form economic deposits. Lead and zinc speciation (mol% of total Pb or Zn) in the model ore fluid was calculated at specific log –pH conditions along the 100, 0.01, and 0.001 ppm total Pb and total Zn isopleths. Along the 100 ppm isopleth conditions are oxidized (∑SO₄ >> ∑H₂S) with Pb and Zn predominantly in the form of chloride complexes under acid to mildly alkaline conditions (pH from 3 to approximately 7.5), while hydroxide complexes dominate Pb and Zn speciation under more alkaline conditions. Sulfide complexes are insignificant under these oxidized conditions. For more reduced conditions along the 0.01 and 0.001 ppm isopleths chloride complexes dominate Pb and Zn speciation in the SO₄ ^2- field and near the SO₄ ^2--reduced sulfur boundary from pH = 4 to approximately 7.5, while hydroxide complexes dominate Pb and Zn speciation under alkaline conditions above pH = 7.5 in the SO₄ ^2- field. In the most reduced fluids (∑H₂S >> ∑SO₄) along the 0.01 and 0.001 isopleths, sulfide complexes account for almost 100% of the Pb and Zn in the model fluid. Acetate (monocarboxylate) complexation is significant only under conditions of chloride and hydroxide complex dominance and its effect is maximized in the pH range 5 to 7, where it complexes 2 to 2.6% of the total Pb and 1 to 1.25% of the total Zn. Malonate (dicarboxylate) complexes are insignificant along all isopleths. The speciation results from this study show that deep formation waters characterized by temperatures near 100°C, high oxidation states and ∑H₂S < 0.03 mg L^-1 (), high chlorinities (~ 100000 mg L^-1), and high but reasonable concentrations of carboxylate anions can mobilize up to 3% of the total Pb and up to 1.3% of the total Zn as carboxylate complexes. Furthermore, these percentages, under the most favorable conditions, correspond to approximately 1 to 100 ppm of these metals in solution; concentrations that are adequate to form economic deposits of these metals. However, the field evidence suggests that all of these optimum conditions for carboxylate complexation are rarely met at the same time. A comparison of the composite ore fluid compositions from this study and modern brine data shows that the ore brines, corresponding to log –pH conditions based on the Anderson (1975) and Giordano (1994) model fluids, are similar in many respects to modern, high trace-metal petroleum-field brines. The principal differences between modern high trace-metal brines and the composite ore fluids of Anderson (1975) and Giordano (1994) relate to their carboxylate anion content. The reported concentrations of monocarboxylate anions (∑monocbx) and dicarboxylate anions (Edicbx) in high trace-metal petroleum-field brines (< 1 to 300 mg L^-1 and < 1 mg L^-1, respectively) are significantly lower than the concentrations assumed in the modelled brines of this study (∑monocbx = 7 700 mg L^-1 and ∑dicbx = 300 mg L^-1). There are also major differences in the corresponding total chloride to carboxylate ratio (∑m _Cl/∑m _cbx) and monocarboxylate to dicarboxylate ratio (∑m _monocbx/∑m _dicbx). Modern high trace-metal brines have much higher ∑m _Cl/∑m _cbx values and, therefore, the contribution of carboxylate complexes to the total Pb and Zn content in these modern brines is likely to be significantly less than the 1 to 3 percent for the composite ore fluids of Anderson (1975) and Giordano (1994). The composite ore-brine based on the Giordano and Barnes (1981) MVT ore fluid is comparable to the high salinity (> 170 000 mg L^-1 TDS) subset of modern brines characterized by low trace-metal content and high total reduced sulfur (∑H₂S). A comparison of the Sverjensky (1984) composite ore-brine with modern petroleum-field brines in terms of ∑H₂S and Zn content, reveals that this ore fluid corresponds to a "border-type" brine, between modern high trace-metal brines and those with low trace-metal content and high ∑H₂S. A brine of this type is characterized by values of ∑H₂S, ∑Zn, and/or ∑Pb within or near the 1 to 10 mg L^-1 range. Based on brine-composition data from numerous references cited in this paper, border-type brines do exist but are rare. The model results and field evidence presented in this study are consistent with other chemical simulation studies of carboxylate complexation in modern petroleum-field brines. Thus, it appears that carboxylate complexation plays a minor, if not insignificant, role as a transport mechanism for Pb and Zn in high salinity Na–Cl and Na–Ca–Cl basinal brines and related ore fluids.     

Fast Solar Wind Velocity in a Polar Coronal Hole during Solar Minimum

We present a study of the outflow velocity of the fast wind in the northern polar coronal hole observed on 21 May 1996, during the minimum of solar activity, in the frame of a joint observing program of the SOHO (Solar Heliospheric Observatory) mission. The outflow velocity is inferred from an analysis of the Doppler dimming of the intensities of the Ovi 1032, 1037 and Hi L 1216 lines observed between 1.5 R and 3.5 R with the Ultraviolet Coronagraph Spectrometer (UVCS), operating onboard SOHO. The analysis shows that for a coronal plasma characterized by low density, as derived for a polar hole at solar minimum by Guhathakurta et al. (1999), and low temperature, as directly measured at the base of this coronal hole by David et al. (1998), the oxygen outflow speed derived spectroscopically is consistent with that implied by the proton flux conservation. The hydrogen outflow is also consistent with flux conservation if the deviation from isotropy of the velocity distribution of the hydrogen atoms is negligible. Hence, for this cool and tenuous corona, the oxygen ions and neutral hydrogen atoms flow outward roughly at the same speed, which increases from 40 km s^–1 at 1.5 R to 360 km s^–1 at 3.1 R , with an average acceleration of the order of 4.5×10³ cm s^–2. The highly anisotropic velocity distributions of the Ovi ions found in the analysis confirm that the process which is heating the oxygen ions acts preferentially across the magnetic field.     

Numerical exploration of the dynamics of Self-Adjoint S-Type Riemann ellipsoids

A Riemann ellipsoid is a self-gravitating fluid whose velocity field is a linear function of the position coordinates. Though the theory of the equilibrium and stability is thoroughly developed, scarse attention has been paid to the dynamical behaviour.In this paper we present a numerical exploration of the phase-space structure for the Self-Adjoint S-Type Riemann ellipsoids via Poincaré surfaces of section, which reveal a rich and complex dynamical behaviour.Both the occurrence of chaos for certain values of the parameters of the system as well as the existence of periodic orbits are observed.We also considered ellipsoids embedded in rigid, homogeneous, spherical halos, obtaining evidence of the stabilizing effect of halos even in the case of finite-amplitude oscillations.Moreover, we show that the approximated equations of motion derived by Rosensteel and Tran (1991) fail to describe properly the phase-space structure of the problem.     

Can pseudotachylytes be used to infer earthquake source parameters? An example of limitations in the study of exhumed faults

Tectonic pseudotachylytes might be used to constrain earthquake source parameters, such as dynamic shear stress resistance, average dynamic friction and slip-weakening distance. Estimation of dynamic shear stress resistance and dynamic friction from field studies is based on the assumption that the volume of melt produced during coseismic slip is proportional to the frictional work converted to heat on the fault surface. Conditions conducive to a realistic estimate of dynamic shear resistance are: (i) the presence of large outcrop exposures that allow for estimation of the volume of pseudotachylyte; (ii) the presence of structural markers offset by faults in order to relate the displacement accommodated by the fault with the volume of melt produced; (iii) data that provide an estimate of the initial melt temperature; and (iv) determination of host-rock temperature and pressure conditions that may have existed during seismic faulting. An independent indication that steady-state friction in the presence of melts might be achieved during coseismic slip arises from the dependence of the fractal dimension of the fault profile (intersection of the fault surface with the outcrop surface) with displacement. This relation could also indicate the slip-weakening distance (Hirose, T., Shimamoto, T., 2003. Fractal dimension of molten surfaces as a possible parameter to infer the slip-weakening distance of faults from natural pseudotachylytes. Journal of Structural Geology 25, 1569–1574).The above conditions are all satisfied in the case of the Gole Larghe Fault Zone, which consists of hundreds subparallel strike-slip faults that cut tonalites of the Adamello batholith (Italy). The thickness of pseudotachylyte-bearing faults increases with displacement. From displacement/thickness ratios and energy balance calculations, we determined the dynamic shear resistance for several pseudotachylyte-bearing faults. In the same faults, the fractal dimension of the fault profile increases from 1.0 to 1.16 with displacement. This was also observed in experiments where steady-state friction in the presence of melt was achieved (Hirose, T., Shimamoto, T., 2003. Fractal dimension of molten surfaces as a possible parameter to infer the slip-weakening distance of faults from natural pseudotachylytes. Journal of Structural Geology 25, 1569–1574). However, we will show that the estimate of the dynamic shear stress resistance, average dynamic friction and slip-weakening distance in the studied faults is limited by the uncertainties to attribute the measured displacement to a single seismic rupture. Since many pseudotachylytes in the upper seismogenic crust overprint preexisting cataclasites, it is suggested that future field and experimental work should be addressed to determine microstructural indicators (i.e. evolution of cataclastic fabric with displacement) within cataclasites, which might constrain the contribution of the cataclastic, pre-pseudotachylyte displacement to the total displacement accommodated by the fault.