Diagnostics,deterioration and provenance of stone materials from the Jefferson Page tomb (Non-Catholic Cemetery of Rome,Italy)

The monumental tomb of Jefferson Page, an officer in the American Navy, was built in 1899 and is located in the Non-Catholic Cemetery of Rome (Italy). This study presents complementary diagnostic studies characterizing the stone of the tomb and the weathering and decay phenomena it has undergone. The monument is made of a single type of whitish marble, variously veined and often covered with black patinas. Petrographic, isotopic and LA-ICP-MS analyses attribute the marble to the Carrara district. SEM/EDS and microbiological analyses indicate that the black patinas are due to cyanobacterial autotrophic and fungin heterotrophic colonization. Fourier-transform infrared spectroscopy revealed the presence of organic material on some portions of the tomb, due to undocumented restoration carried out with a mixture of marble powder and a polyester resin.     

Influence of topsoil of pyroclastic origin on microbial contamination of groundwater in fractured carbonate aquifers

The aim of the research was to analyse the influence of a topsoil of pyroclastic origin on microbial contamination of groundwater in a carbonate aquifer and verify the reliability of thermotolerant coliforms and fecal enterococci as bacterial indicators. The research was carried out through hydrogeological and microbiological monitoring at an experimental field site in Italy during two hydrologic years and through column tests in a laboratory. The taxonomic classification of fecal indicators detected in spring water samples was performed using API20 galleries. Fecal enterococci were also identified by means of 16S rRNA gene sequencing. The topsoil of pyroclastic origin significantly retains both thermotolerant coliforms and fecal enterococci. Results of column tests carried out in soil blocks collected randomly within the test site suggest that Escherichia coli was more retained than Enterococcus faecalis, even though this difference is statistically significant in only two out of six soil samples. Thus, a non-uniform difference in retention is expected at field scale. This suggestion is in agreement with the results of the microbiological monitoring. In fact, fecal enterococci were a more reliable indicator than thermotolerant coliforms for detecting contamination at both seasonal springs of the aquifer system, while no significant differences were observed at the perennial spring.     

Palaeoecological constraints on late Glacial and Holocene ice retreat in the Southern Andes (53°S)

Late Glacial to Holocene ice retreat was investigated along a 120 km long fjord system, reaching from Gran Campo Nevado (GCN) to Seno Skyring in the southernmost Andes (53°S). The aim was to improve the knowledge on regional and global control on glacier recession with special emphasis on latitudinal shifting of the westerlies. The timing of ice retreat was derived from peat and sediment cores, using mineralogical and chemical characteristics, and pollen as proxies. Stratigraphy was based on ¹⁴C-AMS ages and tephrochronology. The ice retreat of the Seno Skyring Glacier lobe is marked by an ice rafted debris layer which was formed around 18,300 to 17,500 cal. yr B.P. Subsequently, fast glacier retreat occurred until around 15,000 to 14,000 cal. yr B.P. during which around 84% of Skyring Glacier were lost. This fast recession was probably also triggered by an increase of the Equilibrium Line Altitude (ELA) from 200 to 300 m. Subsequently, the ice surface was lowered below the ELA in an area that previously made up more than 50% of the accumulation area. Much slower retreat and glacier fluctuations of limited extent in the fjord channel system northeast of GCN occurred between around 14,000 to 11,000 cal. yr B.P. during both the Antarctic Cold Reversal and the Younger Dryas. This slow down of retreat indicates a decline in the general warming trend and/or increased precipitation, due to a southward migration of the westerlies. After around 11,000 cal. yr B.P. pollen distribution shows evolved Magellanic Rainforest and similar climate as at present, which lasted throughout most of the Holocene. Only Late Neoglacial moraine systems were formed in the period 1220–1460 AD, and subsequently in the 1620s AD, and between 1870 and 1910 AD. The results indicate that the Gran Campo Nevado ice cap has reacted more sensitive and partly distinct to climate change, compared to the Patagonian Ice Field.     

Ice elevation and areal changes of glaciers from the Northern Patagonia Icefield, Chile

High thinning rates (up to − 4.0 ± 0.97 m a^− 1) have been measured at Campo de Hielo Patagónico Norte (CHN) or Northern Patagonia Icefield, Chile between 1975 and 2001. Results have been obtained by comparing a Digital Elevation Model (DEM) derived from regular cartography compiled by Instituto Geográfico Militar of Chile (IGM) based upon 1974/1975 aerial photographs and a DEM generated from Advanced Space-borne Thermal Emission and Reflection Radiometer (ASTER) satellite images acquired in September 2001. A complete cloud-free Landsat ETM+ satellite image mosaic acquired in March 2001 was used to update the available glacier inventory of the CHN, including all glaciers larger than 0.5 km² (48 new glaciers). A new delineation of ice divides was also performed over the accumulation areas of glaciers sharing the high plateau where the existing regular cartography exhibits poor coverage of topographic information. This updated glacier inventory produced a total ice area for 2001 of 3953 km², which represents a decrease of 3.4 ± 1.5% (140 ± 61 km² of ice) with respect to the total ice area of the CHN in 1979 calculated from a Landsat MSS satellite image. Almost 62% of the total area change between 1979 and 2001 took place in glaciers located at the western margin of the CHN, where the maximum area loss was experienced by Glaciar San Quintín with 33 km². At the southern margin, Glaciar Steffen underwent the largest ice-area loss (12 km² or 2.6% of the 1979 area), whilst at the eastern margin the greatest area loss took place in Glaciares Nef (7.9 km², 5.7% of the 1979 area) and Colonia (9.1 km², 2.7% of the 1979 area). At the northern margin of the CHN the lower debris-covered ablation area of Glaciar Grosse collapsed into a new freshwater lake formed during the late 1990s. The areal changes measured at the CHN are much larger than previously estimated due to the inclusion of changes experienced in the accumulation areas. The CHN as a whole is contributing melt water to global sea level rise at rates  25% higher than previous estimates.     

Influence of carbon dioxide on coal permeability determined by pressure transient methods

The permeability of coal samples from Pittsburgh Seam was determined using carbon dioxide as the flowing fluid. The confining pressure was varied to cover a wide range of depths. The permeability was determined as a function of exposure time of carbon dioxide while the confining stress was kept constant. The porosities of the coal samples were found to be very low and most of the samples had porosities less than 1%. The permeability of these coal samples was very low—less than 1 μD. Since the objective of this study was to investigate the influence of CO₂ exposure on coal permeability, it was necessary to increase the initial permeability of the coal samples by introducing a fracture. A longitudinal fracture was induced mechanically, and CT scans were taken to ensure that the fracture was present throughout the sample and that the sample was not damaged otherwise during the process. In this study, the permeability of coal was determined by using pressure transient methods. Two types of pressure pulses were used: A-spike and Sine-6 pressure transients. It was first established that the permeability of fractured coal samples did not change with exposure time when an inert gas (Argon) was used as the fluid medium in the experiments. However, the permeability of coal samples decreased significantly when carbon dioxide was used as the fluid medium. This reduction can be attributed to the coal swelling phenomenon. The results show that the permeability reduction in fractured coal samples can be over 90% of the original value, and the exposure time for such reductions can range from 1.5 days up to a week, typically about 2 days under laboratory conditions. The permeability decreased significantly with the increase in confining pressure. The higher confining pressure appears to close internal fractures causing a reduction in permeability.     

Blue and infrared light curves of the mysterious pre-main-sequence star V582 Mon (KH 15D) from 1955 to 1970

In recent years, an increasing number of publications have been devoted to the peculiar and mysterious pre-main-sequence star V582 Mon, also known as KH 15D. This extraordinary T Tauri star, located in the young star cluster NGC 2264, appears to be an eclipsing variable. In the present paper, we report a unique and self-consistent set of light curves in the blue and near-infrared (IR) bands, spanning a 15-yr interval (epoch 1955–1970). Our photometric data show clearly that the beginning of the eclipse stage occurred in early 1958 in the blue, and perhaps around 4 yr later in the IR. The light-curve period turns out to be the same reported by recent observations (about 48.3 d), so that no evidence for a period change results. On the other hand, in our data the light-curve shape appears to be sinusoidal and is therefore different from the one displayed today. The photometric behaviour, determined with time-series and colour-index analysis, suggests that V582 Mon (KH 15D) could initially be surrounded by an accretion disc/torus seen edge-on, with subsequent thin dust formation at the beginning of the blue radiation absorption. The dust could then aggregate into larger particles providing the transition between selective and total absorption, accompanied with eclipsing variability in the IR. The minima of the periodic light curve become deeper owing to the increasing dimension and number of dust grains, and then flatten owing to a contraction in the disc.     

Unravelling the morphogenesis of coastal terraces at Cape Laundi (Sumba Island,Indonesia): Insights from numerical models

The morphology of coastal sequences provides fundamental observations to unravel past sea level (SL) variations. For that purpose, converting morphometric observations into a SL datum requires understanding their morphogenesis. The long-lasting sequence of coral reef terraces (CRTs) at Cape Laundi (Sumba Island, Indonesia) could serve as a benchmark. Yet, it epitomizes a pitfall that challenges the ultimate goal: the overall chronology of its development remains poorly constrained. The polycyclic nature of the terraces, involving marine erosion and reoccupation of old coral colonies by more recent ones hinders any clear assignment of Marine Isotope Stages (MIS) to specific terraces, in particular the reference datum corresponding to the last Interglacial maximum (i.e., MIS 5e). Thus, to overcome these obstacles, we numerically model the genesis of the sequence, testing a range of eustatic SL (ESL) reconstructions and uplift rates, as well as exploring the parameter space to address reef growth, erosion and sedimentation. A total of 625 model runs allowed us to improve the morpho-chronological constraints of the coastal sequence and, more particularly, to explain the morphogenesis of the several CRTs associated with MIS 5e. Our results suggest that the lowermost main terrace was first constructed during the marine transgression of MIS 5e and was later reshaped during the marine regression of MIS 5e, as well as during the MIS 5c and MIS 5a highstands. Finally, we discuss the general morphology of the sequence and the implications it may have on SL reconstructions. At Cape Laundi, as elsewhere, we emphasize the necessity of addressing the development of CRT sequences with a dynamic approach, that is, considering that a CRT is a landform built continuously throughout the history of SL oscillations, and not simply during a singular SL maximum.     

Comparison of Stainless Steel vs. PTFE Miniwells for Monitoring Halogenated Organic Solute Transport

Field tests of organic solute transport behavior have often been monitored using small-diameter wells (miniwells). To determine if experimental results could be significantly biased by sorption to, desorption from, or diffusion through sampling lines, dissolved concentrations of tetrachloroethene and carbon tetrachloride were measured in ground water samples collected simultaneously from the same spatial location during a forced-gradient test in the Borden aquifer using polytetrafluoroethene (PTFE) and stainless steel miniwells (1/8-inch O.D.).
A semiautomated organic analytical system was used on-site to obtain real-time results, which avoided sample holding problems and permitted optimizing sampling times. The breakthrough curves (plots of concentration vs. time) for both organic compounds indicate that under the conditions of this experiment (low organic solute concentrations, short exposure time of sampling lines to the plume, adequate flushing of sampling lines) there is no significant difference between concentration histories (breakthrough curves) collected using a polytetrafluoroethene sampling line and those collected using a stainless steel sampling line. This suggests that organic solute tailing seen in this and also in a similar transport experiment previously conducted at the site is the result of transport processes in the aquifer rather than an artifact introduced by the PTFE miniwells.     

The role of land use and environmental factors on microbial pollution of mountainous limestone aquifers

Limestone aquifers in Southern Italy are often affected by bacterial contamination produced by pasture and agriculture. The main goals of this study were (1) to analyze the role of land use and environmental factors on microbial contamination and, (2) to identify, at field scale, the most suitable indicator of fecal pollution, by comparing fecal coliforms and fecal enterococci. Analyzing surface and spring water, it was noted that both fecal indicators showed a significant decrease during the period characterized by freezing and/or freeze-thaw intervals. The data analysis shows that fecal coliforms are characterized by a significant decrease in population (3 orders of magnitude, at least) during the freezing period, while fecal enterococci are temporarily inhibited. A taxonomic classification of fecal enterococci detected in spring water samples was performed by the API 20 Strep system and by sequencing of the ribosomal 16S DNA genes. The results showed that freezing conditions did not cause any significant change on the set of enterococcal species.