Real-time measurement of volcanic SO2 emissions: validation of a new UV correlation spectrometer (FLYSPEC)

A miniaturized, lightweight and low-cost UV correlation spectrometer, the FLYSPEC, has been developed as an alternative for the COSPEC, which has long been the mainstay for monitoring volcanic sulfur dioxide fluxes. Field experiments have been conducted with the FLYSPEC at diverse volcanic systems, including Masaya (Nicaragua), Poás (Costa Rica), Stromboli, Etna and Vulcano (Italy), Villarica (Chile) and Kilauea (USA). We present here those validation measurements that were made simultaneously with COSPEC at Kilauea between March 2002 and February 2003. These experiments, with source emission rates that ranged from 95 to 1,560 t d⁻¹, showed statistically identical results from both instruments. SO₂ path-concentrations ranged from 0 to >1,000 ppm-m with average correlation coefficients greater than r ²=0.946. The small size and low cost create the opportunity for FLYSPEC to be used in novel deployment modes that have the potential to revolutionize the manner in which volcanic and industrial monitoring is performed.     

On the asphericity of nova remnants caused by rotating white dwarf envelopes

The effect of rotating white dwarf envelopes in determining the structure of nova shells is examined. This is achieved by numerical hydrodynamic simulations of the flows around a binary star system. In previous studies of remnant formation, this rotation has not been included.
It is found that the structures formed in the flow are more consistent with observations of nova shells than the previous theoretical studies. The shells produced by the nova become more prolate with increasing white dwarf envelope rotation. Hence the rotation of white dwarf envelopes must be included in any future discussion of remnant formation.
A possible method of identifying the dominant process by which mixing of accreted and white dwarf matter takes place is suggested.     

Correlation of climatic events between East Asia and Norwegian Sea during last deglaciation

Using a high resolution¹⁴C chronology, β¹³C values and organic carbon content, from loess/paleosol and peat profiles in China, we can demonstrate century scale warm-cold East Asian monsoon paleoclimatic fluctuation events and significant precipitation variability within the last deglaciation. The major climatic events recognized are the Bolling (1 300-12 500 a B.P.), Older Dryas (12 500-11 750 a B. P.), Allerod (11 750-11 200 aB.P.) and Younger Dryas (11 200-10 000 aB.P.). The stratigraphic structure of the last deglaciation sediments is characterized by frequent changes in sedimentation phases reflecting climatic instability. These high frequency, rapid climatic events can correlate with fluctuations recorded by sea surface temperatures in the Norwegian Sea. This indicates a pale-oclimate teleconnection between polar, high latitude areas and East Asian monsoon areas through westerlies and the related atmospheric pressure system. Project supported by the National Natural Science Foundation of China, the Foundation of Chinese Academy of Sciences and the National Science Foundation of U.S.A.     

Massive sulfides in a sedimented rift valley, northern Juan de Fuca Ridge

A number of mounds each several hundred meters across and up to sixty meters high have been observed with SeaMARC II acoustic imagery and Seabeam bathymetry in the sediment-filled axial valley at the northern end of the Juan de Fuca Ridge. The mounds are located a few kilometers west of the eastern valley-bounding normal fault scarp where the local sediment fill is approximately 300 m thick. All of the mounds are believed to be of hydrothermal origin, and one is associated with anomalously high heat flow in excess of 1 W m⁻². A piston core collected from that mound comprises coarse clastic sulfide units interbedded with sulfidic muds. Hydrothermal minerals present in the 2.3 m section include pyrrhotite, pyrite, marcasite, sphalerite, chalcopyrite, iss (intermediate solid solution in the CuFeZnS system), chalcopyrrhotite, galena, talc, barite, and amorphous silica. Mineral fabrics of the clasts indicate that the material was precipitated at or near the sea floor by mixing of hot hydrothermal fluids with cold seawater. Low concentrations of Zn, Cu, Cd, and Ag relative to those found in unsedimented ridge hydrothermal deposits, and the presence of pyrrhotite as an early phase mineral indicates that the vent fluids have been modified by reaction with sediments beneath the mound. Rapid sedimentation in a rift valley is clearly conducive to the formation of large hydrothermal mineral deposits like those believed to be present within and beneath these mounds. The relatively impermeable sediment cover insulates the crust, inhibits groundwater recharge, promotes long-lived discharge at a restricted number of sites, provides a substrate for the efficient subsurface precipitation of minerals, and through continued sedimentation, protects surficial deposits from the corrosive effects of seawater. No reliable estimate of the bulk composition of the mounds can be made with existing data, but their size is comparable to major hydrothermal mineral deposits found on land; ancient settings in which many land deposits formed are in many ways similar to the one in which the features described here are currently forming.     

Holocene sea-level changes along the Strait of Magellan and Beagle Channel,southernmost South America

Radiocarbon-dated marine sediments from five coastal sites along the Strait of Magellan and Beagle Channel in southernmost Chile permit construction of a curve of relative sea-level fluctuations during the Holocene. Morphologic and stratigraphic data point to coastal submergence during the early Holocene as the sea rose to a maximum level at least 3.5 m higher than present about 5000 yr ago. Progressive emergence then followed during the late Holocene. Data from widely separated localities define a smooth curve, the form of which is explainable in terms of isostatic and hydroisostatic deformation of the crust resulting from changing ice and water loads. Apparently anomalous data from one site located more than 100 km behind the outer limit of the last glaciation may reflect isostatic response to deglaciation. The sea-level curve resembles one derived by Clark and Bloom (1979, In “Proceedings of the 1978 International Symposium on Coastal Evolution in the Quaternary, Sao Paulo, Brasil,” pp. 41–60. Sao Paulo) using a spherical Earth model, both in amplitude and in the timing of the maximum submergence.     

Defining and estimating global marine fisheries bycatch

Unselective fishing catches non-target organisms as ‘bycatch’—an issue of critical ocean conservation and resource management concern. However, the situation is confused because perceptions of target and non-target catch vary widely, impeding efforts to estimate bycatch globally. To remedy this, the term needs to be redefined as a consistent definition that establishes what should be considered bycatch. A new definition is put forward as: ‘bycatch is catch that is either unused or unmanaged’. Applying this definition to global marine fisheries data conservatively indicates that bycatch represents 40.4 percent of global marine catches, exposing systemic gaps in fisheries policy and management.     

Estimation of chlorophyll fluorescence under natural illumination from hyperspectral data

This paper reports a series of laboratory and field measurements of spectral reflectance under artificial and natural light conditions which demonstrate that effects of natural chlorophyll fluorescence are observable in the reflectance red edge spectral region. These are results from the progress made to link physiologically-based indicators to optical indices from hyperspectral remote sensing in the Bioindicators of Forest Sustainability Project. This study is carried out on twelve sites of Acer saccharum M. in the Algoma Region, Ontario (Canada), where field measurements, laboratory-simulation experiments, and hyperspectral CASI imagery have been carried out in 1997, 1998, 1999 and 2000 campaigns. Leaf samples from the study sites have been used for reflectance and transmittance measurements with the Li-Cor Model 1800 integrating sphere apparatus coupled to an Ocean Optics Model ST1000 fibre spectrometer in which the same leaves are illuminated alternatively with and without fluorescence-exciting radiation. A study of the diurnal change in leaf reflectance spectra, combined with fluorescence measurements with the PAM-2000 Fluorometer show that the difference spectra are consistent with observed diurnal changes in steady-state fluorescence. Small canopies of Acer saccharum M. have been used for laboratory measurements with the CASI hyperspectral sensor, and under natural light conditions with a fibre spectrometer in diurnal trials, in which the variation of measured reflectance is shown experimentally to be consistent with a fluorescence signature imposed on the inherent leaf reflectance signature. Such reflectance changes due to CF are measurable under natural illumination conditions, although airborne experiments with the CASI hyperspectral sensor produced promising but less convincing results in two diurnal experiments carried out in 1999 and 2000, where small variations of reflectance due to the effect of CF were observed.     

Short‐term rock surface expansion and contraction in the intertidal zone

Transverse micro‐erosion meter (TMEM) stations were installed in rock slabs from shore platforms in eastern Canada. The slabs were put into artificial sea water for 1, 6 or 11 hours, representing high, mid‐ and low tidal areas, respectively. The TMEMs were used to record changes in surface elevation as the rocks dried during the remainder of the 12 h of a semi‐diurnal tidal cycle. A similar technique was used on the same rock types at intertidal TMEM stations in the field, as the rocks dried during low tide. Argillite and basalt surface contraction was from 0 to 0·04 mm: there was little surface expansion. Sandstones contracted by up to 0·03 mm in the field, but there was almost no contraction in the laboratory. Argillite and basalt contraction tended to be greatest in the upper intertidal zone, and to increase with rates of longer‐term surface downwearing, but there was little relationship with rock hardness or air temperature and humidity. Changes in elevation at the same points at TMEM stations in the laboratory and field were quite consistent from one tidal cycle to the next, but there were considerable variations within single tidal cycles between different points within each station. The data suggest that contraction within the elevational zone that is normally submerged twice a day by the tides is by alternate wetting and drying. Short‐term changes in elevation are generally low compared with annual rates of downwearing owing to erosion, but they may generate stresses that contribute to rock breakdown. Copyright © 2007 John Wiley & Sons, Ltd.     

Ocean-bottom seismograph observations on the Mid-Atlantic Ridge near 45°N — further results

Summary. Analysis of data from events well recorded by ocean-bottom seismographs on the Mid-Atlantic Ridge near 45° N, indicates that most activity is centrally placed beneath the median valley floor. The results suggest a lithospheric thickness of 8 km under the median valley floor. The spatial and temporal behaviour of the largest swarm observed is indicative of active magma intrusion.