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171.
Pavel Alexandrov Gilles Ruffet Alain Cheilletz 《Geochimica et cosmochimica acta》2002,66(10):1793-1807
Muscovites from the Blond granite (West French Massif Central) were dated by the 40Ar/39Ar single-grain method. The 40Ar/39Ar ages obtained vary from 305.5 ± 0.3 Ma to 311.3 ± 0.5 Ma, and most of the age spectra are slightly saddle-shaped. The analyzed muscovites show phengitic recrystallization under optical microscope observations, SEM images, and electron microprobe chemical analyses. It is proposed that the saddle-shaped age spectra result from a partial recrystallization, which produced three different isotopic reservoirs in the analyzed white mica single grains: domains of early muscovite, domains of neocrystallized muscovite formed by phengitic and Al-Fe substitutions, and “low-activation energy sites.” 相似文献
172.
173.
Dauvin JC Fisson C Garnier J Lafite R Ruellet T Billen G Deloffre J Verney R 《Marine pollution bulletin》2008,57(1-5):187-201
The scientific teams from the interdisciplinary Seine-Aval (SA) research program and the SA's operational pole, GIPSA (Groupement d'Intérêt Public Seine-Aval) have worked together to create a report card designed to help the Estuary Council (Conseil de l'Estuaire) revitalize its original functions: maintaining functional links between the various estuarine ecosystems, comprehending and managing the estuary's natural habitats and biological populations, and monitoring and improving the physical-chemical quality of the estuarine waters. The report card will be able to synthesize the information obtained from several system performance variables and available operational indicators. This approach, intended to guide the estuary managers, is the oeuvre of several scientific teams; it is particularly important in the context of the Water Framework Directive because it facilitates the elaboration of a group of relevant indicators, which can then be used as operational tools. A report card will provide decision-makers (e.g., political authorities; national, regional and local institutions and industries) with the key indicators for evaluating the system and predicting changes in terms of selected objectives, such as the preservation and restoration of the estuary's environmental functionalities. The final objective of the research is to choose among the available indicators to approximate potential ecological risks. Integrating the socio-economical data will perhaps lead to setting risk acceptability thresholds for the different uses of the Seine estuary. In the end, collaboration between the scientists, the managers, and the GIPSA operational pole will be essential to produce a viable report card about the environmental status of the Seine estuary. To illustrate the research now under way, this article presents the results for three actions undertaken, concerning: (i) physical indicators (i.e., an inventory of the estuary first as a whole, and then section by section); (ii) benthic indicators (i.e., seven indices which show a moderate EcoQ for the lower part of the estuary); and (iii) a eutrophication indicator (i.e., an indicator for coastal eutrophication potential (ICEP), which helps to limit the nutrient fluxes (N or P) that exceed the silica flux delivered by the Seine network, based on the Redfield ratios for algal propagation). 相似文献
174.
Silvana Hidalgo Michel Monzier Eduardo Almeida Gilles Chazot Jean-Philippe Eissen Johannes van der Plicht Minard L. Hall 《Journal of Volcanology and Geothermal Research》2008
The Atacazo–Ninahuilca Volcanic Complex (ANVC) is located in the Western Cordillera of Ecuador, 10 km southwest of Quito. At least six periods of Pleistocene to Holocene activity (N1 to N6) have been preserved in the geologic record as tephra fallouts and pyroclastic flow deposits. New field data, including petrographic and whole-rock geochemical analyses of over forty soil and tephra sections, 100 pumice and lithic samples, and 10 new 14C ages allow us to constrain: (1) the tephra fall isopachs and detailed characteristics of the last two events (N5–N6) including volume estimates of the tephra and pyroclastic flow deposits and the corresponding volcanic explosivity index (VEI); (2) the petrographical and geochemical correlations between domes, tephras, and pyroclastic flow deposits; and, (3) the timing of the last 4 eruptive events and a period of quiescence that endured a few thousand years (1000–4000). 相似文献
175.
Gilles Bellefleur Ernst Schetselaar Devin Wade Don White Randolph Enkin Doug R. Schmitt 《Geophysical Prospecting》2020,68(1):313-333
Wireline logs and vertical seismic profile data were acquired in two boreholes intersecting the main mineralized zone at the Cu–Au New Afton porphyry deposit, Canada, with the objectives of imaging lithological contacts, fault zones that may have acted as conduits that channelled the mineralization, and alteration zones. Log data provide physical rock properties for the main lithologies and alteration zones. Calliper logs reveal many faults and caved-in zones generally indicating rocks with low integrity at the borehole wall. The preponderance of these zones, as indicated by the logs, suggests that their response may dominate the seismic-reflection wavefield. Outside fault zones, compressional and shear-wave velocities exhibit significant variability due to porosity, the heterogeneity of volcanic fragmental rocks and alteration. Distributed acoustic sensing was used to acquire vertical seismic profiling data in the two boreholes surveyed with wireline logs. Straight and helically wound fibre-optic cables housed standard fibres and a fibre engineered to increase the intensity of backscattering at the distributed acoustic sensing interrogator. Standard and engineered optical fibres placed in the two boreholes were daisy-chained together to form two 5-km-long continuous fibres that were interrogated at once with two interrogators. A new generation of interrogator connected to the engineered fibres provided field data with lower noise level and higher signal-to-noise ratio. These data with higher signal-to-noise ratio from straight fibre-optic cable were processed and used for depth imaging. Depth images benefitted from new migration weights that account for the directional sensitivity of the straight fibre-optic cable and limit the extent of migration artefacts. Migration results show several reflectors with shallow dips to the northwest, some explained by faults intersecting the surveyed boreholes. The main sub-vertical lithological and alteration contacts at New Afton generated downgoing reflections that were not considered in the migration. 相似文献
176.
Spinel peridotite xenoliths in alkali basalts at Tok, SE Siberian craton range from fertile lherzolites to harzburgites and wehrlites; olivine-rich (70-84%) rocks are dominant. REE patterns in the lherzolites range from nearly flat for fertile rocks (14-17% cpx) to LREE-enriched; the enrichments are positively correlated with modal olivine, consistent with high-permeability of olivine-rich rocks during melt percolation. Clinopyroxene in olivine-rich Tok peridotites typically has convex-upward trace element patterns (La/NdPM < 1 and Nd/YbPM ? 1), which we consider as evidence for equilibration with evolved silicate liquids (with higher REE and lower Ti contents than in host basalts). Whole-rock patterns of the olivine-rich xenoliths range from convex-upward to LREE-enriched (La/NdPM > 1); the LREE-enrichments are positively correlated with phosphorus abundances and are mainly hosted by accessory phosphates and P-rich cryptocrystalline materials. In addition to apatite, some Tok xenoliths contain whitlockite (an anhydrous, halogen-poor and Na-Mg-rich phosphate), which is common in meteorites and lunar rocks, but has not been reported from any terrestrial mantle samples. Some olivine-rich peridotites have generations of clinopyroxene with distinct abundances of Na, LREE, Sr and Zr. The mineralogical and trace element data indicate that the lithospheric mantle section represented by the xenoliths experienced a large-scale metasomatic event produced by upward migration of mafic silicate melts followed by percolation of low-T, alkali-rich melts and fluids. Chromatographic fractionation and fractional crystallisation of the melts close to the percolation front produced strong LREE-enrichments, which are most common in the uppermost mantle and are related to carbonate- and P2O5-rich derivatives of the initial melt. Reversal and gradual retreat of the percolation front during thermal relaxation to ambient geotherm (“retrograde” metasomatism) caused local migration and entrapment of small-volume residual fluids and precipitation of volatile-rich accessory minerals. A distinct metasomatic episode, which mainly produced “anhydrous” late-stage interstitial materials was concomitant with the alkali basaltic magmatism, which brought the xenoliths to the surface. 相似文献
177.
Plus Martin Dalloyau Sébastien Trut Gilles Auby Isabelle Xavier de Montaudouin Éric Emery Noël Claire Viala Christophe 《Estuarine, Coastal and Shelf Science》2010
The spatial variability of seagrass meadows in Arcachon Bay, was studied between 1988 and 2008 using a combination of mapping techniques based on aerial photographs for intertidal dwarf-grass (Zostera noltii) beds and acoustic sonar for permanently submerged eelgrass (Zostera marina) populations. The results show a severe decline over the period for both species, as well as an acceleration of the decline since 2005 for Z. noltii. The total surface regression over the studied period is estimated to be 22.8 km2 for Z. noltii and 2.7 km2 for Z. marina, which represent declines of 33 and 74% respectively. 相似文献
178.
179.
The effect of temperature on the sorption of cations onto a dioctahedral smectite was investigated by running batch experiments at 25, 40, 80 and 150°C. We measured the distribution coefficient (Kd) of Cs+, Ni2+ and 14 lanthanides (Ln3+) between solutions and the montmorillonite fraction of the MX80 bentonite at various pH and ionic strengths. Up to 80°C we used a conventional experimental protocol derived from Coppin et al. (2002). At 150°C, the experiments were conducted in a PTFE reactor equipped with an internal filter allowing the sampling of clear aliquots of solution.The results show a weak but measurable influence of the temperature on the elements sorption. Kd’s for Ni2+ and Ln3+ increase by a factor 2 to 5 whereas temperature raises from 25 to 150°C. This effect seems higher at high ionic strength. The estimated apparent endothermic sorption enthalpies are 33 ± 10 kJ.mol−1 and 39 ± 15 kJ.mol−1 for Ni2+ and Eu3+, respectively. On the other hand, the temperature effect on Cs+ sorption is only evidenced at low ionic strength and under neutral conditions where the Kd decreases by a factor 3 between 25 and 150°C. Apparent exothermic sorption enthalpy for Cs+ on the montmorillonite is −19 ± 5 kJ.mol−1.Experiments conducted at the four temperatures with the coexistence of all of the cations in the reacting solution (100 ppb of each element in the starting solution) or only one of them, produced similar values of Kd. This suggests the absence of competition between the sorbed cations, and consequently a low degree of saturation of the available sites. A fractionation of the lanthanides spectrum is also observed at high pH and high ionic strength whatever the temperature.The conclusion of this study is that the temperature dependence on sorption reflects, as the fractionation of REE or the pH and ionic strength effects, the chemical process which controls the overall reaction. In the case of an exchange dominated reaction (low pH and low ionic strength), the temperature effect is negligible. In the case of surface complexation (high pH and high ionic strength), the observed increase of Kd with temperature reflects either an increase of the sorption equilibrium constant with temperature or an endothermic property for reactions describing the montmorillonite surface chemistry. 相似文献
180.
Patrice Cannavo René Guénon Gilles Galopin Laure Vidal-Beaudet 《Environmental Earth Sciences》2018,77(18):650
Vegetation in urban areas is generally living in a stress-inducing environment. Sustaining good soil quality is crucial to improve tree development and heath in such (artificial) environment. This study investigates the dynamics of the physico-chemical properties of Technosol, and compares tree development performances in various waste mixtures. A 3-year experiment was conducted with Acer platanoïdes L. grown in three distinct constructed soils, in three replicates, in 0.480-m3 lysimeters in Angers (France). Four combinations of artefacts were studied either as “growing material” (GM) or “structural material” (SM). Three different SMs were used: (1) a mixture of fine mineral material, demolition rubble and green waste (SM-DR/GW), (2) a mixture of fine mineral material, track ballast and sewage sludge (SM-TB/SS), and (3) the SM currently used by Angers city for green space settlements (SM-CT). Waste characteristics and mixing proportions both affected tree development. Physical properties were not a limiting factor for tree development, despite a relatively low soil water reservoir due to high stone content. Moreover, the chemical properties of the materials, more particularly low water pH and CEC, led to poor tree development in SM-CT, whereas the other two SMs did not affect tree development. SM-TB/SS was the most suitable constructed soil after 3 years because it exhibited satisfactory soil nutrient contents that promoted the best tree crown quality. Waste mixtures can sustain soil functions for tree development. As for urban street tree pits that are 2–8 m3 in volume, soil water, and nutrient autonomy should satisfactorily sustain tree development. 相似文献