Microstructure measures and the minimum size of a representative volume element: 2D numerical study

In the paper, a numerical study of the size of a representative volume element (RVE) for both the heat flow as well as the linear elasticity problems is presented. A particular two-phase random microstructure is studied and the method is applied to the digital image of reconstructed 2D realization of random media. The minimum size of RVE is determined by the investigation of the convergence of apparent properties as the size of RVE is increasing. Then, two estimates of the minimum RVE size are proposed and it is shown that the estimates are in a good agreement with the results determined by the investigation of the convergence of apparent properties. The minimum size of RVE can be successfully predicted based only on the microstructure morphology. The statistical measures used in this work are: the two-point probability and the linealpath functions.     

Air masses and aerosols chemical components in the free troposphere at the subtropical northeast atlantic region

The dynamics and the aerosol chemistry of the air masses reaching the free troposphere of the subtropical Northeast Atlantic region during the period 1995–98 have been studied. Seven days backward trajectories were calculated daily with HYSPLIT-4 model for Izaña Global Atmospheric Watch (GAW) Observatory (28.3^°N 16.5^°W, 2367 m a.s.l.). These back-trajectories were classified by means of a k-means clustering strategy. The daily air masses have been coded using 16 variables to detect the aerosol load of each one of them. Four clusters were found: Cluster 1, representative of Atlantic oceanic middle troposphere air masses, (OMT), has an average frequency of occurrence of 50.6%. Cluster 2, which includes air masses originated in the African continent (AfD), has been recorded in a 19.8% of time. Cluster 3 represents a mixture at least of two of the next sources: Europe, Africa and Ocean, (EAM), with a frequency of 12.7%. Finally, Cluster 4 includes air masses with a high load of maritime aerosols, (MaA), and it has been detected in a 16.9%. An analysis of four aerosol components: NO₃ ^?, NH₄ ⁺, non-sea-salt-SO₄ ^2?, and mineral dust and its relation with the origin and transport of the air masses have been done. The highest quantities of mineral dust and nss-SO₄ ^2? are linked with African air masses with a mean value of 86.5 and 1.9 μg/m³ respectively. Whereas the highest levels of NO₃ ^?, 1.0 μg/m³, and NH₄ ⁺, 0.4 μg/m³, were obtained for AfD and EAM. The lowest levels were associated with OMT and MaA air masses types: 12.7, 0.6, 0.2, and 0.5 μg/m³ for dust, NO₃ ^?, NH₄ ⁺, and nss-SO₄ ^2? in average for the four studied years. However, it is remarkable that the values of the median for dust are 2.2 and 3.5 μg/m³ in clusters MaA and OMT respectively. Using non-parametric statistical tests the distributions of concentrations in each cluster by year have been compared in order to detect similarities. The results show that the aerosol loads of OMT and MaA air masses are quite similar and the same occurs for AfD and EAM air masses. However, the correlation analysis between the levels of anions and ammonium evidenced important differences among the air mass types. In AfD air masses is clear a low correlation between levels of nss-SO₄ ^2? and NH₄ ⁺ (r ² = 0.08) suggesting that the sulfate speciation was dominated by sulfate species others than ammonium sulfate, such as calcium sulfate. CaSO₄ ?2H₂O (gypsum) is mainly present in the coarse mode, where the radiative effects of sulfate are less important that in the accumulative mode. For OMT air masses is noticeable an important increasing on the correlation between the levels of anions and those of NH₄ ⁺ for the two last years of the study period (1997–1998, r ² = 0.61 –0.85%) with respect to the first ones (1995–1996, r ² = 0.25–0.49%), coinciding with the second strongest ENSO (El Niño Southern Oscillation) event recorded. This behavior indicates a change in the speciation of the aerosol component.     

Patterns of change in sea surface temperature in the North Atlantic during the last three decades: beyond mean trends

Sea surface temperature (SST) is an important indicator of changes in the climate system and a key driver of marine ecosystems. Here we studied the strength and spatial patterns of changes in North Atlantic SST during the last three decades (1982?C2010). Regional and local patterns of change were studied using data derived from the Advanced Very High Resolution Radiometer (AVHRR) sensors. Apart from changes in mean SST, we studied changes in the seasonal cycle, in the spatial patterning of temperature anomalies and in the location of selected isotherms. We quantified the degree of nonlinearity in mean SST as an indicator of the rate at which SST trends changed during the study period. Changes in the timing and intensity of seasonal extremes were explored, and a heuristic method was used to derive the length of the period of stratification and to estimate its variation. Our results were in general coherent with the main impacts predicted by climate change projections, with greatest changes located at northern latitudes and near land. Marked variation in the spatial patterns was also found for different variables, strengthening the view that physical changes could be promoting the arrangement of novel marine biological communities. The observed changes in ocean SST highlighted the need of a more local and regional focus in future climate change studies.     

Dynamical linkage of tropical and subtropical weather systems to the intraseasonal oscillations of the Indian summer monsoon rainfall. Part II: Simulations in the ENSEMBLES project

We assess the ability of individual models (single-model ensembles) and the multi-model ensemble (MME) in the European Union-funded ENSEMBLES project to simulate the intraseasonal oscillations (ISOs; specifically in 10–20-day and 30–50-day frequency bands) of the Indian summer monsoon rainfall (ISMR) over the Western Ghats (WG) and the Bay of Bengal (BoB), respectively. This assessment is made on the basis of the dynamical linkages identified from the analysis of observations in a companion study to this work. In general, all models show reasonable skill in simulating the active and break cycles of the 30–50-day ISOs over the Indian summer monsoon region. This skill is closely associated with the proper reproduction of both the northward propagation of the intertropical convergence zone (ITCZ) and the variations of monsoon circulation in this band. However, the models do not manage to correctly simulate the eastward propagation of the 30–50-day ISOs in the western/central tropical Pacific and the eastward extension of the ITCZ in a northwest to southeast tilt. This limitation is closely associated with a limited capacity of models to accurately reproduce the magnitudes of intraseasonal anomalies of both the ITCZ in the Asian tropical summer monsoon regions and trade winds in the tropical Pacific. Poor reproduction of the activity of the western Pacific subtropical high on intraseasonal time scales also amplify this limitation. Conversely, the models make good reproduction of the WG 10–20-day ISOs. This success is closely related to good performance of the models in the representation of the northward propagation of the ITCZ, which is partially promoted by local air–sea interactions in the Indian Ocean in this higher-frequency band. Although the feature of westward propagation is generally represented in the simulated BoB 10–20-day ISOs, the air–sea interactions in the Indian Ocean are spuriously active in the models. This leads to active WG rainfall, which is not present in the observed BoB 10–20-day ISOs. Further analysis indicates that the intraseasonal variability of the ISMR is generally underrepresented in the simulations. Skill of the MME in seasonal ISMR forecasting is strongly dependent on individual model performance. Therefore, in order to improve the model skill with respect to seasonal ISMR forecasting, we suggest it is necessary to better represent the robust dynamical links between the ISOs and the relevant circulation variations, as well as the proportion of intraseasonal variability in the individual models.     

Magma chamber growth models in the upper crust: A review of the hydraulic and inertial constraints

Finite volumes of magma moving in confinement, store hydraulic potential energy for the generation,control and transmission of power. The Pascal's principle in a hydraulic jack arrangement is used to model the vertical and lateral growth of sills. The small input piston of the hydraulic jack is equivalent to the feeder dike, the upper large expansible piston equivalent to the magmatic chamber and the inertial force of the magma in the dike is the input force. This arrangement is particularly relevant to the case of sills expanding with blunt tips, for which rapid fracture propagation is inhibited. Hydraulic models concur with experimental data that show that lateral expansion of magma into a sill is promoted when the vertical ascent of magma through a feeder dike reaches the bottom contact with an overlying, flat rigid-layer. At this point, the magma is forced to decelerate, triggering a pressure wave through the conduit caused by the continued ascent of magma further down(fluid-hammer effect). This pressure wave can provide overpressure enough to trigger the initial hydraulic lateral expansion of magma into an incipient sill, and still have enough input inertial force left to continue feeding the hydraulic system. The lateral expansion underneath the strong impeding layer, causes an area increase and thus, further hydraulic amplification of the input inertial force on the sides and roof of the incipient sill, triggering further expansion in a self-reinforcing process. Initially, the lateral pressure increase is larger than that in the roof allowing the sill to expand. However, expansion eventually increases the total integrated force on the roof allowing its uplift into either a laccolith, if the roof preserves continuity, or into a piston bounded by a circular set of fractures. Hydraulic models for shallow magmatic chambers, also suggest that laccolith-like intrusions require the existence of a self-supported chamber roof. In contrast, if the roof of magmatic chambers loses the self-supporting capacity, lopoliths and calderas should be expected for more or less dense magmas, respectively, owing to the growing influence of the density contrast between the host rock and the magma.     

Effect of the soil–pile–structure interaction in seismic analysis: case of liquefiable soils

The design of earthquake-resistant structures depends greatly on the soil–foundation–structure interaction. This interaction is more complex in the presence of liquefiable soils. Pile and rigid inclusion systems represent a useful practice to support structures in the presence of liquefiable soils in seismic zones. Both systems increase the bearing capacity of soil and allow reducing the settlements in the structure. Numerical models with a 3-storey reinforced concrete frame founded on inclusions systems (soil–inclusion–platform–structure) and pile systems (soil–pile–structure) were analyzed. Finite difference numerical models were developed using Flac 3D. Two different soil profiles were considered. A simple constitutive model for liquefaction analysis that relates the volumetric strain increment to the cyclic shear strain amplitude was utilized to represent the behavior of the sand, and the linear elastic perfectly plastic constitutive model with a Mohr–Coulomb failure criterion was used to represent the behavior of the earth platform. Two earthquakes were used to study the influence of the different frequency of excitation in the systems. The results were presented in terms of maximum shear forces distribution in the superstructure and spectrum response of each system. The efforts and displacements in the rigid elements (piles or rigid inclusions) were compared for the different systems. The bending and buckling failure modes of the pile were examined. The results show that the pile system, the soil profile and the frequency of excitation have a great influence on the magnitude and location of efforts and displacements in the rigid elements.

     

Assessment of pollution risk ascribed to Santa Margarida Military Camp activities (Portugal)

Santa Margarida Military Camp (S.M.M.C.) is the only one Portuguese military training area, including firing ranges for tactical military manoeuvres of mechanised divisions. For this reason, various negative effects on the environment were expected due to the military activities, as the Military Camp’s area is classified as a high vulnerability area to pollution of its multilayer porous aquifers. The aim of this study was to identify and characterise local/regional geochemical impacts caused by the continuing military training activities performed at S.M.M.C. in the course of 52 years. An overview of the geochemical research issues as a basis for risk assessment is presented. A special attention has been put on the quality of local and regional surface waters, shallow groundwaters and groundwaters. Local soils and sediments as well as fragments of shells and bullets were sampled and analysed. The results so far obtained, indicated that none pollution effects were a consequence of the military training activities. Till now, the geochemical signatures such as, high levels of K, Cl and NO₃ in waters, detected in particular sites, should be faced as tracers of diffuse pollution ascribed to urban waste disposal and cattle breading.     

Unusual Carbonatite Lavas from Active Volcano, Oldoinyo Lengai

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Unusual Carbonatite Lavas from Active Volcano, Oldoinyo Lengai     

Tangled up in folds: tectonic significance of superimposed folding at the core of the Central Iberian curve (West Iberia)

The amalgamation of Pangea during the Carboniferous produced a winding mountain belt: the Variscan orogen of West Europe. In the Iberian Peninsula, this tortuous geometry is dominated by two major structures: the Cantabrian Orocline, to the north, and the Central Iberian curve (CIC) to the south. Here, we perform a detailed structural analysis of an area within the core of the CIC. This core was intensively deformed resulting in a corrugated superimposed folding pattern. We have identified three different phases of deformation that can be linked to regional Variscan deformation phases. The main collisional event produced upright to moderately inclined cylindrical folds with an associated axial planar cleavage. These folds were subsequently folded during extensional collapse, in which a second fold system with subhorizontal axes and an intense subhorizontal cleavage formed. Finally, during the formation of the Cantabrian Orocline, a third folding event refolded the two previous fold systems. This later phase formed upright open folds with fold axis trending 100° to 130°, a crenulation cleavage and brittle–ductile transcurrent conjugated shearing. Our results show that the first and last deformation phases are close to coaxial, which does not allow the CIC to be formed as a product of vertical axis rotations, i.e. an orocline. The origin of the curvature in Central Iberia, if a single process, had to be coeval or previous to the first deformation phase.