Simulation of Tidal Effects on Contaminant Transport in Porous Media

A one-dimensional numerical model is developed with oscillating velocities and dispersions to simulate the migration process of a contaminant plume within tidally influenced aquifers. Model simulations demonstrate that a major effect the tidal fluctuation has on the migration process of a contaminant plume is the exit concentration discharging to the tidal estuary. Tidal fluctuation causes the exit concentration levels to be significantly diluted by the surface-water body of the estuary. Sensitivity analyses demonstrate that tidal fluctuation hastens the rate of plume migration near the bank of the estuary because of the relatively high advective and dispersive fluxes induced by tides. However, tides affect the migration process only over a short distance from the tidal-water interface (about 40 ft for the parameters used in this study). If the contaminant plume is located far beyond the interface, tidal fluctuations will not affect the rate of plume migration until an existing regional ground-water flow velocity brings the plume to the tidally active zone. With or without tides, the rate of contaminant migration increases with higher regional hydraulic gradient. Furthermore, the effects of tidal fluctuations on the transport process become insignificant with higher regional hydraulic gradients.     

Rocking response of rigid blocks to earthquakes

This investigation deals with the rocking response of rigid blocks subjected to earthquake ground motion. A numerical procedure and computer program are developed to solve the non-linear equations of motion governing the rocking motion of rigid blocks on a rigid base subjected to horizontal and vertical ground motion. The response results presented show that the response of the block is very sensitive to small changes in its size and slenderness ratio and to the details of ground motion. Systematic trends are not apparent: The stability of a block subjected to a particular ground motion does not necessarily increase monotonically with increasing size or decreasing slenderness ratio. Overturning of a block by a ground motion of particular intensity does not imply that the block will necessarily overturn under the action of more intense ground motion. In contrast, systematic trends are observed when the problem is studied from a probabilistic point of view with the ground motion modelled as a random process. The probability of a block exceeding any response level, as well as the probability that a block overturns, increases with increase in ground motion intensity, increase in slenderness ratio of the block and decrease in its size. It is concluded that probabilistic estimates of the intensity of ground shaking may be obtained from its observed effects on monuments, minarets, tombstones and other similar objects provided suitable data in sufficient quantity is available, and the estimates are based on probabilistic analyses of the rocking response of rigid blocks, considering their non-linear dynamic behaviour.     

Geographical distribution and accumulation features of organochlorine residues in bivalves from coastal areas of South Korea

As a part of Mussel Watch Program in Korea, the contamination levels and accumulation features of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were assessed for 82 bivalve samples collected from 66 sites along the entire coast of Korea. The dry weight based ∑PCBs and ∑OCPs ranged from 4.4 ng g⁻¹ to 422.0 ng g⁻¹ (geometric MEAN=36.9 ng g⁻¹) and from 9.95 ng g⁻¹ to 131.37 (34.88) ng g⁻¹, respectively. PCB was predominant in Korean coast, followed by DDTs, HCHs, and Chlordanes. From the observed log normal distribution of PCB and each OCP, low- and high-levels were defined as geometric mean ±1 S.D., respectively. The levels at the sites near urban and/or industrial areas often exceeded the high-levels and the spatial distributions of ∑DDTs and ∑CHLs were correlated with that of ∑PCBs, indicating terrestrial input pathways. Even distribution of ∑HCHs suggested a possibility of atmospheric input pathway of HCHs. The observed isomer ratios of DDTs, HCHs, and CHLs indicated that aging has occurred.     

香港现代海平面变化及其影响

潮汐站资料分析表明香港地区海平面每年以１ｍｍ的速度上升。然而，在沿海填海地区，由于受长期地面沉陷的影响，下沉速度超过上升速度，导致海平面明显相对上升。受大规模地面沉陷的影响。填海区在台风暴潮期间极易受海水浸淹。为了有助于未来海岸的开发，建议利用现有技术水平的测量方法，包括卫星测高和激光测距方法等，对填海区进行长期连续的地面沉陷监测。对下沉问题提出预警，以便采取措施，如修筑海提，建抽水站等，以抵御海     

Earthquake response of structures with partial uplift on winkler foundation

The effects of transient foundation uplift on the earthquake response of flexible structures are investigated. The structural idealization chosen in this study is relatively simple but it incorporates the most important features of foundation uplift. In its fixed base condition the structure itself is idealized as a single-degree-of-freedom system attached to a rigid foundation mat which is flexibly supported. The flexibility and damping of the supporting soil are represented by a Winkler foundation with spring-damper elements distributed over the entire width of the foundation. Based on the response spectra presented for several sets of system parameters, the effects of foundation-mat uplift on the maximum response of structures are identified. The influence of earthquake intensity, structural slenderness ratio, ratio of foundation mass to structural mass, foundation flexibility and p-δ effects on the response of uplifting structures is also investigated.     

Assessment of tributyltin contamination in a shipyard area using a mussel transplantation approach

Mussels (Mytilus galloprovincialis) were transplanted to seven stations around a large shipyard for 126 days to evaluate tributyltin (TBT) contamination. Although the application of TBT-based paints to ships is totally banned in Korea, butyltin compounds were found to accumulate in mussels following transplantation. Concentrations of TBT and total butyltins in transplanted mussels near the shipyard were in the range of 40-350 ng Sn/g and 74-530 ng Sn/g on a dry weight basis, respectively. Obviously, low TBT concentrations (6.0-53 ng Sn/gdw) were determined in mussels at four stations outside the shipyard. A negative gradient of TBT concentrations and TBT portion to total butyltin concentrations were found in both the surface water and transplanted mussels according to distance from the shipyard. In addition, TBT concentrations in surface water and transplanted mussels showed significant correlation (r(2) = 0.71; p < 0.001). These results indicate that the shipyard still releases fresh TBT into surrounding waters even after TBT regulation in Korea, and mussel transplantation is useful in evaluating TBT contamination in shipyard area.     

Effects of Wastewater-borne Heavy Metals on Mangrove Plants and Soil Microbial Activities

Effects of wastewater-borne heavy metals on growth of young plants (9-month-old Bruguiera gymnorrhiza) and soil microbial activities in mangrove microcosms were evaluated. During the 26-week loading period, each mangrove microcosm received 31.2 litres synthetic wastewater of three strengths: normal, medium (5 times of normal strength) and strong (10 times of normal strength). Normal strength wastewater had Cu, Zn, Cd, Cr and Ni concentrations of 3, 5, 0.2, 2 and 3 mg l⁻¹, respectively. Plant growth and total plant biomass in wastewater-treated microcosms were lower than that in the control, and the maximum reduction was found in microcosms receiving strong wastewater. Alkaline phosphatase activity and ATP contents of the mangrove soils receiving wastewater were also reduced. More than 95% reduction in these two parameters was found in soils loaded with strong wastewater. Microtox test demonstrated that soil elutriates obtained from microcosms receiving strong wastewater were of the greatest toxicity (EC₅₀ was 23%). These results show that high concentrations of heavy metals present in strong wastewater were toxic and posed negative effects to both mangrove plants and soil microbial activities. Microbial activities were generally more sensitive to the toxicity of heavy metals than plants.     

Comet assay for the detection of genotoxicity in blood cells of flounder (Paralichthys olivaceus) exposed to sediments and polycyclic aromatic hydrocarbons

To investigate the genotoxic effect of marine sediments on aquatic organism, sediment samples were collected from 13 sites along the coast of Gwangyang Bay (Korea). Concentrations of polycyclic aromatic hydrocarbons (PAHs) in sediments were determined and the relationship between exposure of flounder blood cells to sediment extracts and DNA single-strand breakage in the blood cells was examined using the comet assay. Levels of DNA damage were proportionally increased by exposure concentration and the highest sediment-associated DNA damage was observed at the station showing the highest PAHs contamination. DNA damage in blood cells exposed to five types of PAHs (benzo[a]pyrene, fluoranthene, anthracene, pyrene and phenanthrene) and in flounder (Paralichthys olivaceus) exposed to benzo[a]pyrene (BaP) for 0, 2 and 4 days were assessed by measuring comet tail length. The tail lengths of five PAHs-exposed groups at 50 and 100 ppb were significantly different from the non-exposed group, and the genotoxic effect of BaP correlated with both concentration and duration of exposure. Throughout the study, significant differences in DNA breakage were recorded between cells exposed to sediment extracts or PAHs and non-exposed control. This study demonstrated the comet assay as a successful tool in monitoring contamination of marine sediments and assessing genotoxicity of PAHs in marine organisms, either in vitro or in vivo.     

Recent change of the global monsoon precipitation (1979–2008)

The global monsoon (GM) is a defining feature of the annual variation of Earth’s climate system. Quantifying and understanding the present-day monsoon precipitation change are crucial for prediction of its future and reflection of its past. Here we show that regional monsoons are coordinated not only by external solar forcing but also by internal feedback processes such as El Ni?o-Southern Oscillation (ENSO). From one monsoon year (May to the next April) to the next, most continental monsoon regions, separated by vast areas of arid trade winds and deserts, vary in a cohesive manner driven by ENSO. The ENSO has tighter regulation on the northern hemisphere summer monsoon (NHSM) than on the southern hemisphere summer monsoon (SHSM). More notably, the GM precipitation (GMP) has intensified over the past three decades mainly due to the significant upward trend in NHSM. The intensification of the GMP originates primarily from an enhanced east–west thermal contrast in the Pacific Ocean, which is coupled with a rising pressure in the subtropical eastern Pacific and decreasing pressure over the Indo-Pacific warm pool. While this mechanism tends to amplify both the NHSM and SHSM, the stronger (weaker) warming trend in the NH (SH) creates a hemispheric thermal contrast, which favors intensification of the NHSM but weakens the SHSM. The enhanced Pacific zonal thermal contrast is largely a result of natural variability, whilst the enhanced hemispherical thermal contrast is likely due to anthropogenic forcing. We found that the enhanced global summer monsoon not only amplifies the annual cycle of tropical climate but also promotes directly a “wet-gets-wetter” trend pattern and indirectly a “dry-gets-drier” trend pattern through coupling with deserts and trade winds. The mechanisms recognized in this study suggest a way forward for understanding past and future changes of the GM in terms of its driven mechanisms.     

Role of the upper ocean structure in the response of ENSO-like SST variability to global warming

The response of El Niño and Southern Oscillation (ENSO)-like variability to global warming varies comparatively between the two different climate system models, i.e., the Meteorological Research Institute (MRI) and Geophysical Fluid Dynamics Laboratory (GFDL) Coupled General Circulation Models (CGCMs). Here, we examine the role of the simulated upper ocean temperature structure in the different sensitivities of the simulated ENSO variability in the models based on the different level of CO₂ concentrations. In the MRI model, the sea surface temperature (SST) undergoes a rather drastic modification, namely a tendency toward a permanent El Niño-like state. This is associated with an enhanced stratification which results in greater ENSO amplitude for the MRI model. On the other hand, the ENSO simulated by GFDL model is hardly modified although the mean temperature in the near surface layer increases. In order to understand the associated mechanisms we carry out a vertical mode decomposition of the mean equatorial stratification and a simplified heat balance analysis using an intermediate tropical Pacific model tuned from the CGCM outputs. It is found that in the MRI model the increased stratification is associated with an enhancement of the zonal advective feedback and the non-linear advection. In the GFDL model, on the other hand, the thermocline variability and associated anomalous vertical advection are reduced in the eastern equatorial Pacific under global warming, which erodes the thermocline feedback and explains why the ENSO amplitude is reduced in a warmer climate in this model. It is suggested that change in stratification associated with global warming impacts the equatorial wave dynamics in a way that enhances the second baroclinic mode over the gravest one, which leads to the change in feedback processes in the CGCMs. Our results illustrate that the upper ocean vertical structure simulated in the CGCMs is a key parameter of the sensitivity of ENSO-like SST variability to global warming.