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171.
An asymmetric, Margules-type, solid solution model was used to model the mixing behavior of Fe-Zn sphalerites. The model is based on an analysis of experimental results from fifteen independent data sources. After a careful, stepwise, analysis of the available runs, the solid solution model was constrained using a refined experimental database of 279 experiments which were simultaneously regressed to obtain the excess parameters and a general geobarometric equation. The model indicates that, when pressures are low, the value of γFeSSph, which is always greater than one, is higher at low FeS contents and an increase in temperature causes it to decline. However, for certain compositions γFeSSph values might be slightly less at low T than at high T. This behavior is corrected when pressure increases, regardless of the composition. The excess Gibbs free energy has positive values at any P&T while it is asymmetric. Pressure increases the value of the excess free energy. On the other hand, the Gibbs free energy of mixing is always negative, with a single minimum that tends to move towards Fe-poorer compositions as the pressure goes up. An increase in temperature leads to a more negative Gibbs free energy mixing function suggesting that increasingly Fe-poorer sphalerite would be expected at high temperatures and pressures. The application of the solid solution model to a selection of case-studies provided results which are consistent with independent pressure estimates. However, the pressure determinations for sphalerite + pyrite + pyrrhotite and sphalerite + pyrrhotite assemblages are very sensitive to uncertainties in the composition of the phases involved and, to a lesser extent, to temperature. The results of the application of the model to a field case (scheelite-mineralized Hercynian veins from the Central Pyrenees) were also consistent when compared with independent pressure-constraining silicate assemblages. Thus, the solid solution model described in this paper provides a workable framework with which to compute the pressures of the formation of rocks over a wide range of geological conditions. 相似文献
172.
The Singapore seimic network and the seismicity of Singapore are briefly described,the four tremor events experienced by Singapore are discussed and the ground responses of different stations are compared,The tremor incident standing operation procedure is also prsented. 相似文献
173.
Using chemical potential diagrams and budget calculations, we show that the acquisition of solutes by surface water in granitic rocks under temperate climate corresponds with transformation of primary minerals into kaolinite or halloysite. This mineral controls aluminium solubility. 相似文献
174.
Grald Ouzounian Gil Michard Christian Fouillac Catherine Beaucaire 《Chemical Geology》1980,30(4):317-339
Alkali ion concentrations were studied in hot sulphurated springs in the south of France. Strong correlations between elements (K-Rb, K-Cs and Na-Li) are found. The element concentrations are also closely related with deep temperature as estimated by classical geothermometers. A discussion of the origin of the interelement correlations is presented. Further studies on the behaviour of trace elements during mineral dissolution are needed and can yield interesting methods of investigation in geothermal exploration.
Résumé
L'étude des concentrations des ions alcalins dissous dans les eaux thermales sulfurées du Midi de la France montrent de très nettes corrélations entre éléments (K-Rb, K-Cs et Na-Li) ainsi que des corrélations entre concentrations d'éléments et température profonde estimée à l'aide des géothermomètres classiques. Plusieurs suggestions quant à l'explication des relations observées sont présentées. Une bonne compréhension du comportement des ions en trace lors de la dissolution des minéraux par l'eau aurait certainement des retombées intéressantes en prospection géothermique. 相似文献
175.
Stability constants of hydroxocomplexes of Al(III):Al(OH)2+ and A1(OH)4? have been measured in the 20–70°C temperature range by reactions involving only dissolved species. The stability constant of the first complex ion is studied by measuring pH of solutions of aluminium salts at several concentrations. of aluminate ion is deduced from equilibrium constants of the reaction between the trioxalato aluminium (III) complex ion and Al3+ in acid medium, and between the same complex ion and A1(OH)4? in alkaline medium. The K values and the associated ΔH are and ΔH1 = 11.8 Kcal; and ΔH4 = 42.45 Kcal. These last results are not in agreement with the values of recent tables for and of Al3+ and Al(OH)4?. We suggest a consistent set of data for dissolved and solid Al species and for some aluminosilicates. 相似文献
176.
177.
A. Gil de Paz J. Gallego J. Zamorano A. Alonso-Herrero A. Argón-Salamanca 《Astrophysics and Space Science》1998,261(1-4):147-150
We present results from a spectroscopic survey of Paβ & Brγ emission in a sample of T Tauri stars, mostly in the Taurus-Auriga
complex. Velocity resolved spectra (Δv ∼ 15 km s-1) show that, of the 41 stars observed in Paβ emission, 34% display IPC redshifted absorptions, while, of the 29 stars observed
in Brγ emission, 21% display IPC redshifted absorptions. The lines are broad (FWHM ∼ 200 km s-1) and lack blueshifted absorptions. These observations are consistent with the near infrared hydrogen lines forming predominantly
in infalling material, as suggested by magnetospheric accretion column models. Radiative transfer calculations of the Paβ
and Brγ line profiles in a very simplified, spherically symmetric situation are discussed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
178.
Lucia Fanning Robin Mahon Patrick McConney Jorge Angulo Felicity Burrows Bisessar Chakalall Diego Gil Milton Haughton Sherry Heileman Sergio Martínez L’ouverture Ostine Adrian Oviedo Scott Parsons Terrence Phillips Claudia Santizo Arroya Bertha Simmons Cesar Toro 《Marine Policy》2007
A large marine ecosystem (LME) governance framework, developed from a need to effectively address the sustainable management of the shared living marine resources of the Caribbean, is proposed. The framework is based on four propositions and focuses on a linked examination of two well-known components of LME-level governance: the policy cycle process by which decisions are made and the multi-level nature of LMEs. It accommodates the diversity of policy cycles at multiple levels and the linkages among them required for effective governance of LMEs. The framework takes into account of factors such as context, purpose, jurisdictional scale, capacity and complexity and provides a means to identify critical areas for intervention. 相似文献
179.
The region under study is located in the active “transition zone” from the Eurasian continent to the Pacific Ocean. The zone occupies not only the continent-ocean border area (continental coastline, marginal seas, island arcs, and deep-sea trenches) but also the margins of intracontinental regions of the Eurasian continent with different structures and regimes of development. The transition zone is a natural buffering and damping regulator of the interaction between the Eurasian and Pacific plates and is characterized by intense orogenesis, contemporary volcanism, active seismicity, diverse geothermal regime, and highly nonuniform measured heat-flow values. Available geothermal data for the region are not sufficiently generalized. After the latest maps compiled in the 1990s, new data have been obtained and new geoinformation technologies have been developed. In the study presented in this paper, available geothermal information has been generalized and a detailed heat flow distribution map has been compiled and used to calculate Moho temperatures, to determine the thickness of the “geothermal” lithosphere, and to construct distribution maps of these parameters. 相似文献
180.
Gil Penha-Lopes Fabrizio Bartolini Samwel Limbu Stefano Cannicci Erik Kristensen Jos Paula 《Marine pollution bulletin》2009,58(11):1694-1703
The effect of different organic-rich sewage concentration (0%, 20% and 60% diluted in seawater) and absence or presence of mangrove trees on the survival, bioturbation activities and burrow morphology of fiddler crabs species was assessed. After 6 months, males of both species always showed higher survival (80%) when compared to females (20%). Crabs inhabiting pristine conditions achieved higher survival (67–87%) than those living in sewage-exposed mesocosms (40–71%). At 60% sewage loading, fiddler crabs processed less sediment (34–46%) during feeding and excavated slightly more sediment (45–80%) than at pristine conditions. While percent volume of the burrow chambers increased (13–66%) at contaminated mesocosms for both vegetation conditions, burrows were shallower (33%) in bare cells loaded with sewage. The results show that fiddler crabs presented moderate mortality levels in these artificial mangrove wetlands, but mainly in sewage impacted cells. However, they still function as ecosystem engineers through bioturbation activities and burrow construction. 相似文献