CARBON AND NITROGEN ABUNDANCES IN SELECTED ACHONDRITES

Total carbon and nitrogen contents are reported for four howardites, three enstatite achondrites and one hypersthene achondrite. The mean value for eucrites is 650 ppm C and howardites 1440 ppm C. The Haraiya eucrite has an anomalously high carbon content The nitrogen contents range between 24 and 66 ppm N. The mean N value for eucrites is 36 ppm N and for the howardites 51 ppm N.     

Construction of an evolutionary deglaciation model for the Irish midlands based on the integration of morphostratigraphic and geophysical data analyses

Alternative, established models for the deglaciation of the midlands of Ireland are tested against an interpretation of a suite of deglacial sediments covering an area of 600 km² in the east central midland area. Interpretation of the sediments is based on geomorphological mapping, lithostratigraphic characterization of exposures and geotechnical data supported by electrical resistivity tomography (ERT) and ground penetrating radar (GPR). GPR depicted small‐scale sedimentological and deformational structures within low‐conductivity soft sediments, such as cross‐bedding, planar bedding, channel‐like features and faulting planes, and revealed the internal architecture of eskers, glaciodeltas, subaqueous fans and raised bogs. ERT data permitted the detection of depth to bedrock and the lithological characterization of unconsolidated sediments. The ten sites presented were surveyed by traditional mapping methods and/or geophysical techniques. This allowed the construction of a local model of the deglaciation of the area which recognized five main stages. An ice sheet covering most of Ireland withdrew as a single body as far as the midlands. At this stage, two main directions of ice retreat are identified from the spatial distribution of meltwater/overflow channels, esker and morainic ridges, and ice‐marginal glaciolacustrine deposits. A pattern of deglacial sedimentation into an expanding ice‐marginal glacial lake is depicted. The glacial lake was dammed to the west by two ice dome fronts, one decaying to the north‐west and another to the south‐west, and by the Shannon Basin watershed to the east. Glacial lake outlets identified along the watershed and the altitude of the topset/foreset interface zone depicted in glaciodeltaic deposits allowed the identification of three lake water levels. The highest level is at 87–89 m Ordnance Datum (OD), the second lake level at 84 m OD and the third at 78 m OD. Copyright © 2012 John Wiley & Sons, Ltd.     

Climate stability during the Eemian – new pollen evidence from the Nidzica site,northern Poland

Bińka, K., Nitychoruk, J. & Dzier?ek, J. 2010: Climate stability during the Eemian – new pollen evidence from the Nidzica site, northern Poland. Boreas, 10.1111/j.1502‐3885.2010.00179.x. ISSN 0300‐9483 Interglacial sediments at Nidzica, northern Poland were investigated by means of pollen and isotope analysis. These deposits accumulated in an extensive basin through most of the Eemian and Early Weichselian, practically without stratigraphic gaps. Continuous subsidence of the basin floor has resulted in the accumulation of a great thickness of lacustrine sediments, consisting mostly of calcareous gyttja. The course of pollen and isotope curves in the interglacial interval does not indicate the abrupt climatic shifts reported from some other continental climatic archives. Particularly important has been the reconstruction of the final stages of the Eemian, a potential analogue for future climatic change in the late Holocene. At Nidzica, this period is registered as a gradual modification of forest composition, devoid of any pulsations in which temperate forest is followed by terminal, boreal pine–birch communities.     

On variations in the fine-structure constant and stellar pollution of quasar absorption systems

At redshifts   z _abs≲ 2  , quasar absorption-line constraints on space–time variations in the fine-structure constant, α, rely on the comparison of Mg  ii and Fe  ii transition wavelengths. One potentially important uncertainty is the relative abundance of Mg isotopes in the absorbers, which, if different from solar, can cause spurious shifts in the measured wavelengths and, therefore, α. Here we explore chemical evolution models with enhanced populations of intermediate-mass (IM) stars, which, in their asymptotic giant branch phase, are thought to be the dominant factories for heavy Mg isotopes at the low metallicities typical of quasar absorption systems. By design, these models partially explain recent Keck/HIRES evidence for a smaller α in   z _abs < 2  absorption clouds than on Earth. However, such models also overproduce N, violating observed abundance trends in high- z _abs damped Lyman-α (DLA) systems. Our results do not support the recent claim of Ashenfelter et al. that similar models of IM-enhanced initial mass functions (IMFs) may simultaneously explain the HIRES varying-α data and DLA N abundances. We explore the effect of the IM-enhanced model on Si, Al and P abundances, finding it to be much less pronounced than for N. We also show that the ¹³C/¹²C ratio, as measured in absorption systems, could constitute a future diagnostic of non-standard models of the high-redshift IMF.     

Carbon and nitrogen in carbonaceous chondrites: Elemental abundances and stable isotopic compositions

Abstract— We have undertaken a comprehensive study of carbon and nitrogen elemental abundances and isotopic compositions of bulk carbonaceous chondrites. A strategy of multiple analyses has enabled the investigation of hitherto unconstrained small‐scale heterogeneities. No systematic differences are observed between meteorite falls and finds, suggesting that terrestrial processing has a minimal effect on bulk carbon and nitrogen chemistry. The changes in elemental abundance and isotopic composition over the petrologic range may reflect variations in primary accreted materials, but strong evidence exists of the alteration of components during secondary thermal and aqueous processing. These changes are reflected within the CM2 and CO3 groups and follow the published alteration scales for those groups. The nitrogen isotope system appears to be controlled by an organic host, which loses a ¹⁵N‐rich component with progressive alteration. This study recommends caution, however, over the use of bulk carbon and nitrogen information for classification purposes; variance in relative abundance of different components in carbonaceous chondrites is significant and reflects intrameteorite heterogeneities.     

DOC budgets of drained peat catchments: implications for DOC production in peat soils

The blocking of drainage ditches in peat has been proposed as a possible mitigation strategy for the widely observed increases in dissolved organic carbon (DOC) concentrations from northern peatlands. This study tested the hypothesis that drain‐blocking could lead to lower DOC concentrations by measuring the DOC export from a series of small peat‐covered catchments over a period of 2 years. Six catchments were chosen: two were pristine that had never been drained; three where drains had been blocked (one in 1995, and two in 2003); and a control peat drain catchment where the drain was left unblocked throughout the study. In the case where drains were blocked as part of thus study, the drains were observed for 2 months before blocking and 2 years after blocking. The results show that: (i) high concentrations of DOC can come from water ponded in the drain; (ii) the DOC export (flux of DOC per area of catchment) from the six study catchments shows a high degree of positive correlation with both catchment size and water yield; (iii) distinctly lower DOC export with water yield was observed for the catchments containing higher‐order channels (>27 500 m²) as opposed to single drain catchments (>7500 m²); (iv) drain‐blocking resulted in a statistically significant decrease in DOC export (average was 39%) but the effect upon DOC concentration explained only 1% of the variance in the data. The results suggest that drain blocking works by decreasing the flow from the drain, not by changing the production of DOC in the peat. The change in export with catchment size implies a considerable removal of DOC from large catchments. Copyright © 2009 John Wiley & Sons, Ltd.