Sourcing Olive Jars Using U‐Pb Ages of Detrital Zircons: A Study of 16th Century Olive Jars Recovered from the Solomon Islands

We present U‐Pb ages of zircons extracted from olive jars recovered from two sites associated with Alvaro de Mendaña y Neyra's colonising expedition to the Solomon Islands, c. 1595–1596 A.D. The olive jars were previously associated with Panamanian and Peruvian origins based on petrological and geochemical studies. To further define provenance, 143 zircons were extracted from five olive jar sherds, analyzed and dated. The resultant U‐Pb ages range from the Archaean to the Cenozoic (2977.2 ± 29.0–3.2 ± 4.0 Ma), but the dominance of Cretaceous and Palaeogene ages (∼ 90% of the total age population is between ∼ 145 and 23 Ma) supports a Peruvian origin based on comparative geology, with the Coastal Batholith of Peru a prime candidate area of ceramic production. These results are significant for the characterization of 16th Century Peruvian‐made pottery and our understanding of its production and trade.     

Understanding Place as ‘Home’ and ‘Away’ through Practices of Bird-watching

Bird-watching is an increasingly popular leisure activity. Previous research has taken for granted the identity of people who watch birds, often categorised by their level of skilled practice as ‘dude’, ‘birder’ or ‘twitcher’. Feminist geographers encourage us to explore identity work as an outcome of the reciprocal relationships between practices and place. Our feminist approach illustrates that the practices of bird-watching are always much more than categorising birds as species. This paper illustrates how the practices of bird-watching are integral to the making and remaking of sense of place as ‘home’ and ‘away’, to sustain identities beyond accepted categories of ‘dude’, ‘birder’ and ‘twitcher’. The creation and application of different types of ‘bird-lists’ helps to explain the ways in which practices of bird-watching facilitate making sense of place as simultaneously ‘home’, ‘away’ and habitat, as well as the identity work of home-maker, citizen-scientist and tourist. Our insights into these leisure practices of bird-watching are drawn from analysis of data gathered from 21 people who actively bird-watch and reside on the South Coast, New South Wales, Australia by combining research methods of talking, walking, drawing and photography.     

Sedimentation,suspension, and resuspension in Tasman Bay and Beatrix Bay,New Zealand,two contrasting coastal environments which thermally stratify in summer

Abstract

The influence of density stratification on sedimentation, suspension, and resuspension in Tasman Bay and Beatrix Bay, New Zealand, two contrasting coastal environments, was studied with specific reference to the implications for modelling aquaculture sustainability. Tasman Bay, an enhanced scallop (Pecten novaezelandiae Reeve) fishery, is a very large coastal indentation gently shelving to c. 20 m deep c. 10 km from shore and open to the Tasman Sea, whereas Beatrix Bay, an area of intense Greenshell? mussel (Perna canaliculus Gmelin) aquaculture, is a small (22 km² × 30–40 m deep) enclosed embayment off the side of the nearby Pelorus Sound. Sediment trap arrays were used to determine the vertical fluxes of suspended solids and the associated chlorophyll component. Benthic chambers were used to investigate sediment nutrient regeneration. In summer, salinity gradients in both bays are minimal or non‐existent because of low inputs of fresh water and density stratification is mainly controlled by water temperature. The data from mid summer exhibited different spatial distribution patterns for detritus and phytoplankton biomass (as indicated by chlorophyll) in these two very different bays, although they had similar turbulent environments. The density discontinuity at the thermocline had a strong influence on settling of phytoplankton. There was evidence of upwards entrainment of suspended paniculate matter into the upper water column from the thermocline in Beatrix Bay. Benthic resuspension was estimated to contribute up to 90% of the suspended solids caught in sediment traps near the sea floor in both bays. The trapping rate of phytoplankton was thought to be dependent on species dominance. Possible mechanisms of resuspension included turbulence in the benthic boundary layer, and high velocities below the thermocline associated with internal seiches. The presence of a mid water column chlorophyll maximum in Beatrix Bay is discussed in terms of nutrient and light regimes at the thermocline, and species composition. In Tasman Bay, the chlorophyll maximum was thought to be caused by resuspension of benthic microphytes and their subsequent confinement in a thin layer (2–4 m thick) of high turbulence between the thermocline and the seabed.     

Surfactant-enhanced remediation of contaminated soil: a review

Extracting aqueous solutions with or without additives are employed to solubilize contaminants in soil. Since water solubility is the controlling removing mechanism, additives are used to enhance efficiencies. These additives can reduce the time to treat a site compared to the use of water alone. Additives must be of low toxicity and biodegradable. The research in this area has focussed mainly on halogenated volatile organic compounds (VOCs) and is still quite limited for metal removal. Additives include surfactants, organic and inorganic acids, sodium hydroxide, which can dissolve organic soil matter, water-soluble solvents such as methanol, displacement of cations with nontoxic ones, complexing agents such as EDTA, acids in combination with complexing agents or oxidizing/reducing agents. Cationic, anionic and nonionic surfactants are particularly used for soil washing or flushing. They contain both hydrophobic and hydrophilic portions, making them ideal for solubilization of hydrophobic compounds. Numerous studies have indicated that surfactants enhance recoveries of non-aqueous phase liquids (NAPLs). There have also been indications that pretreatment of soil with surfactant washing to solubilize hydrophobic compounds such as PAHs enhances biodegradation of these contaminants. A few in situ field studies have been performed with surfactants. Large-scale treatment has been done mostly for organic removal. Soil pH, soil type, cation exchange capacity (CEC), particle size, permeabilities and contaminants all affect removal efficiencies. High clay and organic matter contents are particularly detrimental. Understanding the chemistry of the binding of the contaminant and the hydrogeology of the site are very important. Once the water is pumped from the soil, it must be extracted and then treated to remove the hydrocarbons and metals. Several technologies exist such as sodium hydroxide or sodium sulfide precipitation, ion exchange, activated carbon adsorption, ultrafiltration, reverse osmosis, electrodialysis and biological processes. Recycling of the surfactants is desired to decrease treatment costs.

This paper will provide an overview of the laboratory research, field demonstration and full-scale application of surfactants for the remediation of contaminated soil. The majority of pilot scale in situ flushing tests, particularly in the United States, have involved the use of surfactants and co-solvents. There are only a few full-scale projects however. Recent laboratory scale efforts by the authors concerning the use of biosurfactants, biologically produced surfactants, to enhance the removal of copper, cadmium and zinc from contaminated soils and sediments are discussed. Three types of biosurfactants were evaluated for their effectiveness. They included a lipopeptide called surfactin from Bacillus subtilis, a rhamnolipid from Pseudomonas aeruginosa and a sophorolipid from Torulopsis bombicola. The results indicated the feasibility of removing the metals with the anionic biosurfactants even though the exchangeable fractions were not significant.     

A physical basis for Pauling's definition of bond strength

 The average strength, s, of the bonded interactions comprising a cation containing oxide anion coordination polyhedron and the value of the electron density, ρ(r _c ), at the bond-critical points are inversely correlated with bond length. In each case, the observed bond lengths, R, were modeled with power-law expressions defined in terms of s/r and ρ(r _c )/r, respectively, where r is the Periodic Table row number of the cation involved in the bonded interaction. On the basis of the close connection between bond strength and the value of the electron density at the bond-critical point, we conclude that bond strength is a direct measure of bond type; the greater its value, the greater the localization of electron density in the binding region and the greater the shared–electron covalent character of the bonded interaction. Received: 15 October 2002 / Accepted: 17 February 2003 Present address:G. V. Gibbs in care of M. Spackman Department of Chemistry, University of New England, Armidale 2351, Australia Acknowledgements The NSF is thanked for supporting this study with grant EAR–9627458. The paper was written while GVG was a Visiting NSF Scholar at The University of Arizona. The faculty and graduate students of the Department of Geosciences and Bob Downs and Marelina Stimpf in particular are thanked for making the visit great fun.     

SiSSi and SiOSi bonds in molecules and solids: A comparison

Ab initio STO-3G molecular orbital calculations completed for various silicon sulfide molecules have reproduced bridging bond length and angle variations of molecular and solid state thiosilicates. Calculated potential energy curves for SiSSi and SiOSi bonds conform with the narrow range of angles (106°–115°) observed for thiosilicates and the wide range (120°–180°) observed for silicates. In addition, the limited range of angles of the SiSSi bond agrees with the limited range of topologies and configurations exhibited by molecular and solid thiosilicates as compared to the wider range of angles, topologies and configurations exhibited by siloxanes and silicates. Quadratic stretching and bending force constants calculated for the silicon sulfide molecules agree with experimental values. The close correspondence of bond length and angle variations in molecular and solid thiosilicate systems indicates that the local bonding forces in both systems are practically the same notwithstanding the long range forces of the solid.