The CaGeO3–Ca3Fe2Ge3O12 garnet join: an experimental study

Germanate garnets are often used as isostructural analogues of silicate garnets to provide insight into the crystal chemistry and symmetry of the less accessible natural garnet solid solutions. We synthesised two series of germanate garnets at 3 GPa along the join^VIIICa₃^VI(CaGe)^IVGe₃O₁₂–^VIIICa₃^VIFe₂^IVGe₃O₁₂ at 900 °C and 1,100 °C. Samples with compositions close to the CaGeO₃ end-member consist of tetragonal garnet with a small amount of triclinic CaGe₂O₅. Samples with nominal compositions between X_Fe=0.4 and 1.0 consist of a mixture of tetragonal and cubic garnets; whereas, single-phase cubic garnets were obtained for compositions with X_Fe>1.2 (X_Fe gives the iron content expressed in atoms per formula unit, and varies between 0 and 2 along the join). Run products which were primarily single-phase garnet were investigated using Mössbauer spectroscopy. Spectra from samples synthesised at 1,100°C consist of one well-resolved doublet that can be assigned to Fe³⁺ in the octahedral site of the garnet structure. A second doublet, present primarily in samples synthesised at 900°C, can be assigned to Fe²⁺ at the octahedral sites of the garnet structure. The relative abundance of Fe²⁺ decreases with increasing iron content. Transmission electron microscopy analyses confirm this tendency and show that the garnets are essentially defect-free. The unit-cell parameters of tetragonal ^VIIICa₃^VI(CaGe)^IVGe₃O₃ garnet decrease with increasing synthesis temperature, and the deviation from cubic symmetry becomes smaller. Cubic garnets show a linear decrease of unit-cell parameter with increasing iron content. The results are discussed in the context of iron incorporation into ^VIIIMg₃^VI(MgSi)^IVSi₃O₃ majorite.     

Morphological,sedimentological and tectonic features of diamante-m. Carpinoso Marine terrace flight (tyrrhenian coast of northern Calabria,Italy)

Marine terrace flights resulting from the interaction of Quaternary glacio-eustatic fluctuations and tectonic uplift are a typical feature of the Tyrrhenian coast of Calabria in Southern Italy; in particular a térrace flight with four orders of terraces is evident in the Diamante area. The lowest terrace levels (fourth order: Diamante-Cirella terrace) are typified by a calcarenitic deposit with Cladocora caespitosa which give a Th/U age > 300,000 years. The third order terrace has a sedimentary cover formed of a basal discontinuous level of well rounded pebbles which underlies a deeply weathered coarse-grained sand horizon. The deposit ends with a paleosol locally cut by erosional scours filled by yellowish tuff deposits. The formation of this terrace dates from the Middle Pleistocene. The second order terrace presents a sedimentary cover composed of two generations of soils and is attributed to Middle Pleistocene age. The first order terrace (M. Carpinoso terrace) presents a wave-cut platform covered by a clastic deposit of marine and continental origin; this deposit consists of superimposed depositional events separated by unconformities, bounded by two diachronous surfaces. The formation of the wave-cut platform could be related to several sea-level stands during a long-lasting slow subsidence phase of the coastal area during the Lower Pleistocene. The uplift following terrace formation displaced the first order terrace most markedly; tectonic lineations controlled the hydrographic pattern and erosion of the surfaces.     

Cost-sensitive rainfall thresholds for shallow landslides

The risk management of rainfall-induced landslides requires reliable rainfall thresholds to issue early warning alerts. The practical application of these thresholds often leads to misclassifications, either false negative or false positive, which induce costs for the society. Since missed-alarm (false negative) and false-alarm (false positive) cost may be significantly different, it is necessary to find an optimal threshold that accounts for and minimises such costs, tuning the false-alarm and missed-alarm rates. In this paper, we propose a new methodology to develop cost-sensitive rainfall thresholds, and we also analyse several factors that produce uncertainty, such as the accuracy of rainfall intensity values at landslide location, the time of occurrence, the minimum rainfall amount to define the non-triggering event, and the variability of cost scenarios. Starting from a detailed mapping of landslides that occurred during five large-scale rainfall events in the Italian Central Alps, we first developed rainfall threshold curves with a ROC-based approach by using both rain gauge and bias-adjusted weather radar data. Then, based on a reference cost scenario in which we quantified several cost items for both missed alarms and false alarms, we developed cost-sensitive rainfall threshold curves by using cost-curve approach (Drummond and Holte 2000). Finally, we studied the sensitivity of cost items. The study confirms how important is the information regarding rainfall intensity at the landslide site for the development of rainfall thresholds. Although the use of bias-corrected radar strongly improves these values, a large uncertainty related to the exact time of landslide occurrence still remains, negatively affecting the analysis. Accounting for the different missed-alarm and false-alarm misclassification costs is important because different combinations of these costs make an increase or decrease of the rainfall thresholds convenient. In our reference cost scenario, the most convenient threshold is lower than ROC-based thresholds because it seeks to minimise the number of missed alarms, whereas the missed-alarm costs are almost seven times greater than false-alarm costs. However, for different cost scenarios, threshold may vary significantly, as much as half an order of magnitude.

     

Stromboli Island (Italy): Scenarios of Tsunamis Generated by Submarine Landslides

Stromboli is an Italian volcanic island known for its persistent state of activity, which leads to frequent mass failures and consequently to frequent tsunamis ranging from large (and rare) catastrophic events involving the entire southern Tyrrhenian Sea to smaller events with, however, extremely strong local impact. Most of tsunamigenic landslides occur in the Sciara del Fuoco (SdF) zone, which is a deep scar in the NW flank of the volcano, that was produced by a Holocene massive flank collapse and that is the accumulation area of all the eruptive ejecta from the craters. Shallow-water bathymetric surveys around the island help one to identify submarine canyons and detachment scars giving evidence of mass instabilities and failures that may have produced and might produce tsunamis. The main purpose of this paper is to call attention to tsunami sources in Stromboli that are located outside the SdF area. Further, we do not touch on tsunami scenarios associated with gigantic sector collapses that have repeat times in the order of several thousands of years, but rather concentrate on intermediate size tsunamis, such as the ones that occurred in December 2002. Though we cannot omit tsunamis from the zone of the SdF, the main emphasis is on the elaboration of preliminary scenarios for three more possible source areas around Stromboli, namely Punta Lena Sud, Forgia Vecchia and Strombolicchio, with the aim of purposeful contributing to the evaluation of the hazard associated with such events and to increase the knowledge of potential threats affecting Stromboli and the nearby islands of the Aeolian archipelago. The simulations show that tsunami sources outside of the SdF can produce disastrous effects. As a consequence, we recommend that the monitoring system that is presently operating in Stromboli and that is focussed on the SdF source area be extended in order to cover even the other sources. Moreover, a synoptic analysis of the results from all the considered tsunami scenarios leads to a very interesting relation between the tsunami total energy and the landslide potential energy, that could be used as a very effective tool to evaluate the expected tsunami size from estimates of the landslide size.     

A test-bed implementation of an acquisition system for indoor positioning

Indoor GNSS signals are typically received with poor signal-to-noise ratio, which impairs the acquisition stage of common global positioning system (GPS) receivers. Extending the coherent integration time increases the acquisition sensitivity, but the data-bit-rate limits the maximum achievable performance. Non-coherent processing also improves the detection performance, but indoor signals require a large amount of accumulations resulting in significant squaring loss. Moreover, both strategies have high computational complexity which fixes demanding requirements for stand alone mass-market terminals operating in real time. A sensitivity–complexity trade-off is therefore mandatory. Assisted-GPS, which is included in 3GPP specifications, reduces the overall acquisition complexity and enhances sensitivity. In this paper we describe a low-complexity-assisted data-wipe-off technique that enables the high-sensitivity acquisition of GPS signals. The method is based on the acquisition of the strongest signal in order to obtain information that eases the acquisition of the weaker ones. The analysis also addresses sources of sensitivity loss, such as Doppler effects and local oscillator inaccuracies. A test campaign with real signals and integration times up to 2 s validates the method, demonstrating the effectiveness of the proposed technique in indoor environments.     

Non-invasive Geophysical Surveys in Search of the Roman Temple of Augustus Under the Cathedral of Tarragona (Catalonia,Spain): A Case Study

An integrated geophysical survey has been conducted at the Tarragona’s Cathedral (Catalonia, NE Spain) with the aim to confirm the potential occurrence of archaeological remains of the Roman Temple dedicated to the Emperor Augustus. Many hypotheses have been proposed about its possible location, the last ones regarding the inner part of the Cathedral, which is one of the most renowned temples of Spain (twelfth century) evolving from Romanesque to Gothic styles. A geophysical project including electrical resistivity tomography (ERT) and ground probing radar (GPR) was planned over 1 year considering the administrative and logistic difficulties of such a project inside a cathedral of religious veneration. Finally, both ERT and GPR have been conducted during a week of intensive overnight surveys that provided detailed information on subsurface existing structures. The ERT method has been applied using different techniques and arrays, ranging from standard Wenner–Schlumberger 2D sections to full 3D electrical imaging with the advanced Maximum Yield Grid array. Electrical resistivity data were recorded extensively, making available many thousands of apparent resistivity data to obtain a complete 3D image after a full inversion. In conclusion, some significant buried structures have been revealed providing conclusive information for archaeologists. GPR results provided additional information about shallowest structures. The geophysical results were clear enough to persuade religious authorities and archaeologists to conduct selected excavations in the most promising areas that confirmed the interpretation of geophysical data. In conclusion, the significant buried structures revealed by geophysical methods under the cathedral were confirmed by archaeological digging as the basement of the impressive Roman Temple that headed the Provincial Forum of Tarraco, seat of the Concilium of Hispania Citerior Province.     

Flow dynamics at the continental scale: Streamflow correlation and hydrological similarity

Streamflow variability in space and time critically affects anthropic water uses and ecosystem services. Unfortunately, spatiotemporal patterns of flow regimes are often unknown, as discharge measurements are usually recorded at a limited number of hydrometric stations unevenly distributed along river networks. Advances in understanding the physical processes that control the spatial patterns of river flows are therefore necessary to predict water availability at ungauged locations or to extrapolate pointwise streamflow observations. This work explores the use of the spatial correlation of river flows as a metric to quantify the similarity between hydrological responses of two catchments. Following a stochastic framework, 340,000 cross‐correlations between pairs of daily streamflows time series are predicted at a seasonal timescale across the contiguous United States using 413 catchments of the MOPEX dataset. Model predictions of streamflow correlation obtained in absence of run‐off information are successfully used to identify catchment outlets sharing similar discharge dynamics and flow regimes across a broad range of geomorphoclimatic conditions, without relying on calibration. The selection of reference streamgauges based on predicted streamflow correlation generally outperforms the selection based on spatial proximity, especially as the density of available gauged sections decreases. Interestingly, correlated outlets share a broad spectrum of hydrological signatures (mean discharge, flow variability, and recession properties), suggesting that catchments forced by analogous frequency and intensity of effective rainfall events might exhibit common geomorphoecological traits leading to similar hydrological responses. The proposed framework provides a physical basis to assist the regionalization of flow dynamics and to interpret the spatial variability of flow regimes along stream networks.