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51.
Ben K. Odhiambo Virginia Brown Gayle Armentrout Leanna C. Giancarlo Chelsea Wegner 《Environmental Earth Sciences》2013,69(6):2103-2117
Damming of the North Anna River in 1972 created Lake Anna, a cooling water source for the Dominion nuclear power plant as well as a popular recreation site in Spotsylvania and Orange counties, Virginia, USA. Previously dated (210-Pb) sediment cores from seven locations within the lake and three locations in the adjoining Waste Heat Treatment Facilities (WHTF) were analyzed for trace metals (Al, Ba, Zn, Cd, Cu, Fe, Mn and Pb) and polychlorinated biphenyls (PCBs) to examine the environmental evolution of the reservoir system. The reservoir has a history of mining activities in its watershed and unusually elevated concentrations of PCBs were found in fish tissues from previous studies. Therefore, dated sediment cores provided the framework for both the temporal and spatial analysis of possible sources and flux histories for both trace metals and PCBs. The trace metals results suggest that, though the upper reaches are relatively less impacted, the old mine tailings from the now ceased mining activities in the watershed of Contrary Creek tributary continue to dominate the sediment chemistry of the lower portion of the lake basin, signified by sediment enrichment of Pb, Cd, Cu, and Zn. Lagoon-2 of the WHTF also seems to be receiving unusually high loadings of Cd (12.5 ± 1.07 μg/g) that is probably associated with waste materials from the nuclear power plant that maintains the lagoons. PCB sediment concentrations were relatively low in the lower sections of the basins with values typically being <3.5 ng/g. The upper reaches of the basin had several PCB hotspots, with the surface sediments of Terry’s Run tributary having values as high as 53.13 ng/g. The spatial distribution of PCBs seems to suggest the upper reaches of the basin as the probable source, with the unusually high concentrations near bridges suggesting a possible link between the PCBs and old bridge fill materials. The oldest lacustrine sediments also had relatively high trace metals and PCB values signifying a probable role of soil disruption and sediment reconcentration during reservoir construction. 相似文献
52.
High‐P tectono‐metamorphic evolution of mylonites from the Variscan basement of the Northern Apennines,Italy
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Deborah Lo Pò Roberto Braga Hans‐Joachim Massonne Giancarlo Molli Alessandra Montanini Giuseppe M. Bargossi 《Journal of Metamorphic Geology》2018,36(1):23-39
Strain localization within shear zones may partially erase the rock fabric and the metamorphic assemblage(s) that had developed before the mylonitic event. In poly‐deformed basements, the loss of information on pre‐kinematic phases of mylonites hinders large‐scale correlations based on tectono‐metamorphic data. In this study, devoted to a relict unit of Variscan basement reworked within the nappe stack of the Northern Apennines (Italy), we investigate the possibility to reconstruct a complete pressure (P)–temperature (T)–deformation (D) path of mylonitic micaschist and amphibolite by integrating microstructural analysis, mineral chemistry and thermodynamic modelling. The micaschist is characterized by a mylonitic fabric with fine‐grained K‐white mica and chlorite enveloping mica‐fishes, quartz, and garnet pseudomorphs. Potassic white mica shows Mg‐rich cores and Mg‐poor rims. The amphibolite contains green amphibole+plagioclase+garnet+quartz+ilmenite defining S1 with a superposed mylonitic fabric localized in decimetre‐ to centimetre‐scale shear zones. Garnet is surrounded by an amphibole+plagioclase corona. Phase diagram calculations provide P–T constraints that are linked to the reconstructed metamorphic‐deformational stages. For the first time an early high‐P stage at >11 kbar and 510°C was constrained, followed by a temperature peak at 550–590°C and 9–10 kbar and a retrograde stage (<475°C, <7 kbar), during which ductile shear zones developed. The inferred clockwise P–T–D path was most likely related to crustal thickening by continent‐continent collision during the Variscan orogeny. A comparison of this P–T–D path with those of other Variscan basement occurrences in the Northern Apennines revealed significant differences. Conversely, a correlation between the tectono‐metamorphic evolution of the Variscan basement at Cerreto pass, NE Sardinia and Ligurian Alps was established. 相似文献
53.
Francesco Soldovieri Giancarlo Prisco Svein-Erik Hamran 《Planetary and Space Science》2009,57(8-9):1076-1084
The exploitation of ground penetrating radar in Mars subsurface exploration is becoming assessed in remote sensing observations and is of timely interest for high resolution in situ prospecting of the first meters of the underground.In this framework, we deal with a novel processing approach based on microwave tomography. Aiming to achieve accurate and reliable “images” of the investigated subsurface region in order to detect, localize and possibly determine the extent and the geometrical features of the embedded layers while reducing at the minimum possible the “interpretation” of the diagnostics result.The feasibility of the microwave tomographic approach has been tested in realistic cases dealing with conditions analogue to the Mars subsurface ones. In particular, we will present the tomographic reconstruction results achieved by experimental data collected in a field survey at Svalbard Islands (Norway) with a time-domain GPR. 相似文献
54.
Giancarlo Della Ventura G. Diego Gatta Gunter J. Redhammer Fabio Bellatreccia Anja Loose Gian Carlo Parodi 《Physics and Chemistry of Minerals》2009,36(4):193-206
We relate a single-crystal FTIR (Fourier transform infrared) and neutron diffraction study of two natural cancrinites. The structural refinements show that the oxygen site of the H2O molecule lies off the triad axis. The water molecule is almost symmetric and slightly tilted from the (0001) plane. It is involved in bifurcated hydrogen bridges, with Ow···O donor–acceptor distances >2.7 Å. The FTIR spectra show two main absorptions. The first at 3,602 cm?1 is polarized for E ⊥ c and is assigned to the ν3 mode. The second, at 3,531 cm?1, is also polarized for E ⊥ c and is assigned to ν1 mode. A weak component at 4,108 cm?1 could possibly indicate the presence of additional OH groups in the structure of cancrinite. Several overlapping bands in the 1,300–1,500 cm?1 range are strongly polarized for E ⊥ c, and are assigned to the vibrations of the CO3 group. 相似文献
55.
Raúl R. Castro Giancarlo Monachesi Luca Trojani Marco Mucciarelli Massimo Frapiccini 《Journal of Seismology》2002,6(1):43-59
We studied spatial and temporal characteristics of seismic attenuation inCentral Italy using S- and coda- waves recorded by the MarchesanSeismograph Network from earthquakes located in the epicentral area ofthe 1997 Umbria-Marche sequence. The amplitude decay of the S waveswith distance was defined calculating empirical attenuation functions at 15frequencies between 1 and 25 Hz. We analyzed separately foreshocks andaftershocks and we found the same attenuation functions, suggesting thatthe possible temporal variations could be confined in a small area. Thefrequency dependence of Q
S was approximated by the equation Q
S=18 · f
2.0between 1 and 10 Hz. At higher frequencies (10–25 Hz), the frequencydependence of Q
s weakens, having an average value of Q
S=990. We also estimated Q from coda waves (Q
C) using the single-scattering models of Aki andChouet (1975) and Sato (1977). We found that Q
C=77 · f
0.6, (between 2 and 20Hz) at the western side of the mountain chain, using either foreshocks oraftershocks. This relation is consistent with previous estimates of Q
Creported for the Central Apennines. For a volume sampling the Colfioritobasin, the Apennines and the Marche region we found that Q
C=55 · f
0.8,indicating highattenuation below the mountain belt. To detect small temporal changes ofQ, we calculated spectral ratios of 5 temporal doublets located in theepicentral area and recorded at the closest station. We found temporalchanges of Q that vary from 27% to 56%, depending on the locationof the doublets. This variability suggests that the temporal change ofattenuation may depend on the spatial variation of Q and perhaps on thespatial distribution of tectonic stress in the epicentral area. 相似文献
56.
Giancarlo Serri 《Earth and Planetary Science Letters》1981,52(1):203-212
Ophiolites have been divided into two groups: high-Ti and low-Ti types. These can be discriminated by studying the fractionation trends of both gabbroic complexes (this work) and lavas and dykes [16], particularly in the TiO2/M.I. diagram. The first type typically shows MORB-like magmas whereas in the second the magma types have a spectrum of composition from mid-ocean ridge basalts to island arc tholeiites and boninite-like magmas often occur.High-Ti ophiolites are petrologically and geochemically similar to major oceanic and ensialic back-arc basin crusts as well as oceanic crust generated during the intermediate and late-stage opening of intraoceanic back-arc basins.Parental magmas and fractionation processes of low-Ti ophiolites fit with an hypothesis of their formation in the early stage of opening of intraoceanic back-arc basins. 相似文献
57.
58.
Lateral flow of African mantle below the nearby Tyrrhenian plate: geochemical evidence 总被引:1,自引:0,他引:1
The Quaternary magmatism of the Southern Tyrrhenian basin represents a rare example of an active volcanic arc system where ocean island basalt (OIB) and island arc basalt (IAB) magmas coexist. Although there is general agreement on the importance of the Ionian oceanic lithosphere subduction in the genesis of the IAB magmatism, the tectono‐magmatic processes producing the coexisting OIB magmas are still poorly understood. Here we show that the geochemistry of the Quaternary Southern Tyrrhenian OIB‐type magmatism (i.e. Ustica island and Prometeo, a previously unknown submarine lava field) is very similar to that of OIB‐type volcanoes situated on the nearby African plate (i.e. Etna and Hyblean Plateau). Among the possible geodynamic scenarios proposed to explain the coexistence of OIB and IAB magmas in arc settings, we consider the development of a tear at the edge of the Ionian plate as the more likely mechanism to favour the flow of African asthenospheric mantle below the Tyrrhenian plate. 相似文献
59.
We evaluated nekton habitat quality at 5 shallow-water sites in 2 Rhode Island systems by comparing nekton densities and biomass,
number of species, prey availability and feeding, and abundance of winter flounderPseudopleuronectes americanus. Nekton density and biomass were compared with a 1.75-m2 drop ring at 3 sites (marsh, intertidal, and subtidal) in Coggeshall Cove in Narragansett Bay and two subtidal sites (eelgrass
and macroalgae) in Ninigret Pond, a coastal lagoon. We collected benthic core samples and examined nekton stomach contents
in Coggeshall Cove. We identified 16 species of fish, 16 species of crabs, and 3 species of shrimp in our drop ring samples.
A multivariate analysis of variance indicated differences in total nekton, invertebrates, fish, and winter flounder across
the five sites. Relative abundance of benthic invertebrate taxa did not match relative abundance of prey taxa identified in
the stomachs. Nonmetric multidimensional scaling plots showed groupings in nekton and benthic invertebrate prey assemblages
among subtidal, intertidal, and marsh sites in Coggeshall Cove. Stepwise multiple regression indicated that biomass of macroalgae
was the most important variable predicting abundance of nekton in Coggeshall Cove, followed by elevation and depth. In Rhode
Island systems that do not experience chronic hypoxia, macroalgae adds structure to unvegetated areas and provides refuge
for small nekton. All sites sampled were characterized by high abundance and diversity of nekton pointing to the importance
of shallow inshore areas for production of fishes and decapods. Measurements of habitat quality should include assessment
of the functional significance of a habitat (this can be done by comparing nekton numbers and biomass), some measure of habitat
diversity, and a consideration of how habitat quality varies in time and space. 相似文献
60.
Giancarlo Della Ventura Fabio Bellatreccia Paolo Rossi 《Physics and Chemistry of Minerals》2007,34(10):727-731
We report here a single-crystal polarized-light study of stoppaniite, ideally (Fe,Al,Mg)4(Be6Si12O36)(H2O)2(Na,□), from Capranica (Viterbo). Polarized-light FTIR spectra were collected on an oriented (hk0) section, doubly polished
to 15 μm. The spectrum shows two main bands at 3,660 and 3,595 cm−1; the former is strongly polarized for E ⊥c, while the latter is polarized for E //c. A sharp and very intense band at 1,620 cm−1, plus minor features at 4,000 and 3,228 cm−1 are also polarized for E //c. On the basis of literature data and considering the pleochroic behavior of the absorptions, the 3,660 cm−1 band is assigned to the ν3 stretching mode and the 1,620 cm−1 (associated with an overtone 2*ν2 at 3,230 cm−1) band to the ν2 bending mode of “type II” water molecules within the structural channels of the studied beryl. The sharp band at 3,595 cm−1 is not associated with a corresponding ν2 bending mode; thus it is assigned to the stretching vibration of O–H groups in the sample. The minor 4,000 cm−1 feature can be assigned to the combination of the O–H bond parallel to c with a low-frequency metal-oxygen mode such as the Na–O stretching mode. The present results suggest that the interpretation
of the FTIR spectrum of Na-rich beryl needs to be carefully reconsidered. 相似文献