Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Macrofossil evidence of alder (Alnus sp.) in Britain early in the Late Glacial Interstadial: implications for the northern cryptic refugia debate

Wood macrofossil remains of alder and willow/poplar have been recovered from a sediment sequence in the valley of the Turker Beck in the Vale of Mowbray, North Yorkshire. These remains have yielded radiocarbon dates early in the Devensian Late Glacial (14.7–14k cal a bp ), equivalent to the early part of the Greenland Interstadial (GI-1e) of the GRIP ice-core record. These are the earliest dates recorded for the presence of alder in the Late Glacial in the British Isles. Associated biological remains have provided a palaeoenvironmental record for this early part of the Greenland Interstadial, generally indicative of open environments dominated by herbaceous taxa on both the wetland and dryland surfaces. However, stands of alder, birch and willow woodland were also present, and indicate the possibility that such tree species survived in cryptic refugia in Britain as elsewhere in northern Europe during the Last Glacial Maximum. The absence of alder pollen at Turker Beck, in a sequence in which its macrofossil remains are relatively abundant, lends support to the view that pollen can be a poor indicator of the presence of tree species in Late Glacial sequences in northern and western Europe.     

The impacts of climate change on local hydrology and low flow frequency in the Geum River Basin,Korea

The climate sensitive analysis of potential climate change on streamflow has been conducted using a hydrologic model to identify hydrologic variability associated with climate scenarios as a function of perturbed climatic variables (e.g. carbon dioxide, temperature, and precipitation). The interannual variation of water resources availability as well as low flow frequency driven by monsoonal time shifts have been investigated to evaluate the likelihood of droughts in a changing climate. The results show that the timing shift of the monsoon window associated with future climate scenarios clearly affect annual water yield change of ? 12 and ? 8% corresponding to 1‐month earlier and 1‐month later monsoon windows, respectively. Also, a more severe low flow condition has been predicted at 0·03 m³/s as opposed to the historic 7Q10 flow of 1·54 m³/s given at extreme climate scenarios. Copyright © 2011 John Wiley & Sons, Ltd.     

Quantitative decomposition of radiative and non-radiative contributions to temperature anomalies related to siberian high variability

Climate Dynamics - In this study, we carried out an attribution analysis that quantitatively assessed relative contributions to the observed temperature anomalies associated with strong and weak...     

Water quality assessment at Jinhae Bay and Gwangyang Bay,South Korea

A new water quality index for evaluating the water quality of Jinhae Bay and Gwangyang Bay was developed. Four water quality parameters were selected as water quality indicators for the water quality index: dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), chlorophyll-a (Chl-a), and dissolved oxygen (DO). Reference levels of DIN, DIP, and Chl-a were determined as 6.22 μmol L^?1, 0.38 μmol L^?1, and 2.32 μmol L^?1, respectively, on the basis of a long-term dataset that was collected monthly in the Korea Strait over a period of seven years (2006–2012). The water quality index established for Jinhae Bay and Gwangyang Bay is (bottom DO grade × 0.33) + (surface Chl-a grade × 0.33) + (surface DIN grade × 0.17) + (surface DIP grade × 0.17). On the basis of a three-year observation, the water quality of Jinhae Bay was classified as “good” in winter and spring, “poor” in summer, and “fair” in autumn and exhibited large spatial variation, with the lowest-quality water observed in Masan Bay. The water quality of Gwangyang Bay was classified as “good” in winter, “fair” in spring, “poor” in summer, and “fair” in autumn. Unlike Jinhae Bay, the water quality of Gwangyang Bay exhibited minimal spatial variation. In both bays, water quality among the four seasons was worse during summer. It is essential that a survey for water quality evaluation be conducted during summer.     

Retrieval of the single scattering albedo of Asian dust mixed with pollutants using lidar observations

The vertical distribution of single scattering albedos （SSAs） of Asian dust mixed with pollutants was derived using the multi-wavelength Raman lidar observation system at Gwangju （35.10°N,126.53°E）.Vertical profiles of both backscatter and extinction coefficients for dust and non-dust aerosols were extracted from a mixed Asian dust plume using the depolarization ratio from lidar observations.Vertical profiles of backscatter and extinction coefficients of non-dust particles were input into an inversion algorithm to retrieve the SSAs of non-dust aerosols.Atmospheric aerosol layers at different heights had different light-absorbing characteristics.The SSAs of non-dust particles at each height varied with aerosol type,which was either urban/industrial pollutants from China transported over long distances at high altitude,or regional/local pollutants from the Korean peninsula.Taking advantage of independent profiles of SSAs of non-dust particles,vertical profiles of SSAs of Asian dust mixed with pollutants were estimated for the first time,with a new approach suggested in this study using an empirical determination of the SSA of pure dust.The SSAs of the Asian dust-pollutants mixture within the planetary boundary layer （PBL） were in the range 0.88-0.91,while the values above the PBL were in the range 0.76-0.87,with a very low mean value of 0.76 ± 0.05.The total mixed dust plume SSAs in each aerosol layer were integrated over height for comparison with results from the Aerosol Robotics Network （AERONET） measurements.Values of SSA retrieved from lidar observations of 0.92 ± 0.01 were in good agreement with the results from AERONET measurements.     

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.     

The impact of the risk environment and energy prices to the budget of Korean households

Energy is closely related to environmental risk. A rising fuel price in the 1970s had hurt consumers and caused disturbance to the natural environment. Households could not afford high imported energy prices and thus resorted to fuel wood. Land competed for fuel wood and agricultural crops, and thus high fuel prices strained the environment with respect to the use of land. If human health and safe housing were included in environmental risk, a high energy price would induce broader environmental risk. Households with limited income would not be able to use expensive fossil energy to warm their houses and would depend on only electric mats or blankets to keep warm. Such insufficient warming methods would not only threaten their health but would also worsen the condition of their houses. The abrupt increase in energy prices in 2007 and 2008 had significantly impacted environmental risk. It forced low income households to spend more on energy, leaving less for other expenditure segments, but had left high income households generally intact. This contrasting effect between different income groups had increased the sustainability of the energy risks at the high prices. This study shows how risks associated with the household economy have increased in response to the recent dramatic increases in energy prices. We develop a method for assessing risk by using the variance of ratios of energy expenditure to current income. We then examine how differently the economic change has increased risk across expenditure segments. We find energy expenditure as the biggest contributor to the risk. In addition, we illustrate how energy expenditure has changed the risk profile for each income group, with the first group (i.e., the lowest income group) experiencing the greatest increase. This group hurts the most during days of high energy prices.     

Geotectonic framework of Permo–Triassic magmatism within the Korean Peninsula

This study presents sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon ages, and whole-rock chemical and isotopic (Sr-Nd) compositions of representative Triassic plutons from South Korea. The plutons from the Gyeonggi massif (Hongseong, Namyang, Yangpyeong and Odesan), the central Okcheon belt (Baeknok and Yongsan), and the Yeongnam massif (Sangju, Gimcheon, Hamyang and Macheon) yield zircon U–Pb ages of ca. 232–226 Ma, 227–226 Ma, and 240–228 Ma, respectively. Among the Triassic plutonic suite in South Korea, those within the Gyeonggi massif are dominated by granite, syenite, monzonite, monzodiorite and gabbro. Plutons within the Okcheon belt are mainly by granite to quartz monzodiorite. The Yeongnam massif mainly incorporates granite to granodiorite and minor monzodiorite intrusions. The geochemical signatures of the Triassic plutons are characterized by Ta–Nb troughs, depletion of P and Ti, and enrichment of LILE. Most plutons except Macheon monzodioritic pluton show high initial ⁸⁷Sr/⁸⁶Sr ratios (0.708248–0.714678) and strongly negative ε_Nd(T) (− 20.3 to − 7.7) values, suggesting contribution from middle to upper crust. In contrast, the Macheon monzodioritic pluton in the Yeongnam massif shows relatively low initial ⁸⁷Sr/⁸⁶Sr ratios (0.706547-0.706629) and negative ε_Nd(T) (− 4.43 to − 3.62) values. The Middle Triassic syenite–monzonite–granite–gabbro series in and around the Gyeonggi massif possess high-K calc-alkaline and shoshonitic affinity suggesting a post-collisional magmatic event following the Permo–Triassic collision between the North and South China blocks. The Triassic plutons in the Yeongnam massif and the Okcheon belt, together with a Permian Yeongdeok pluton in the Gyeongsang basin, show features typical of high- to medium-K calc-alkaline magmatism with LREE and LILE enrichments. This together with a depletion of Y and HREE suggests their formation in a subduction setting. Our results provide robust evidence to consider the Gyeonggi massif as an extension of the Qinling–Dabie–Sulu belt between the North and South China blocks in central China. The Okcheon belt and Yeongnam massif in South Korea, together with the continental margin of South China, are marked by a common Permian to Triassic magmatic episode, probably related to the paleo-Pacific slab subduction.     

Factors controlling fluoride contents of groundwater in north-central and northwestern Sri Lanka

Chemical characterization has been made of groundwater bodies at 294 locations in four village districts in north-central and northwestern Sri Lanka, with special focus on fluorine contamination. High fluoride contents in groundwater are becoming a major problem in the dry zone of Sri Lanka, and dental fluorosis and renal failures are widespread. Field measurements of temperature, pH, and electrical conductivity were made during sampling. Chemical analyses of the water samples were later made using atomic absorption spectroscopy, spectrophotometry, and titration. Fluoride concentrations in the study area vary from 0.01 to 4.34 mg/l, and depend on pH and the concentrations of Na, Ca, and HCO₃ ⁻. Basement rocks including hornblende biotite gneiss, biotite gneiss, and granitic gneiss seem to have contributed to the anomalous concentrations of fluoride in the groundwater. Longer residence time in aquifers within fractured crystalline bedrocks may enhance fluoride levels in the groundwater in these areas. In addition, elevated fluoride concentrations in shallow groundwater in intensive agricultural areas appear to be related to the leaching of fluoride from soils due to successive irrigation.