A comparison of aggregation behavior in aqueous humic acids

The ability of six humic acids (HAs) to form pseudomicellar structures in aqueous solution was evaluated by five techniques: size exclusion chromatography; pyrene fluorescence enhancement; the pyrene I₁/I₃ ratio; the cloud point of dilute HA solutions; and the fluorescence anisotropy of HAs. Soil HAs were found to aggregate most easily, both on microscopic and macroscopic scales. The formation of amphiphilic structures was chiefly related to HA-solvent interactions: highly solvated HAs aggregated poorly, while a lignite derived material underwent intermolecular, rather than intramolecular, rearrangements. A newly discovered algal HA was found to have minimal aggregative properties.     

Preliminary Examinations of the Ore-forming Process by Fluid Mixing – a Test of MIX99

Abstract: Possible ore deposition by fluid mixing was preliminarily examined using MIX 99, a FORTRAN program developed for simulating water-rock interactions. We consider mixing of two fluids, the low f_O2 and high temperature source fluid and the high f_O2 and low temperature seawater. Oxygen fugacity of a mixed fluid formed by titration of seawater into the source fluid gradually decreases with decreasing temperature (model A). Sequential precipitation of ore-forming minerals was examined in this model. On the other hand, simultaneous precipitation of the minerals could be followed by simulation of instantaneous overall mixing of the two fluids (model B). Results of simulation of the both models revealed that a temporal sequence of mineralization observed in the Karuizawa mine, NE Japan, can be formed by model A, while model B is suitable for the mineralization of an active chimney found in the Rainbow hydrothermal area of the Mid-Atlantic Ridge.     

A near-infrared polarized bipolar cone in the Circinus galaxy

We present near-infrared broad-band polarization images of the nuclear regions of the Circinus galaxy in the J , H and K bands. For the first time the south-eastern reflection cone is detected in polarized light, which is obscured at optical wavelengths behind the galactic disc. This biconical structure is clearly observed in J - and H -band polarized flux, whilst in the K band a more compact structure is detected. Total flux J − K and H − K colour maps reveal a complex colour gradient toward the south-east direction (where the Circinus galactic disc is nearer to us). We find enhanced extinction in an arc-shaped structure, at about 200 pc from the nucleus, probably part of the star formation ring.
We model the polarized flux images with the scattering and torus model of Young et al., with the same basic input parameters as used by Alexander et al. in the spectropolarimetry modelling of Circinus. The best fit to the polarized flux is achieved with a torus radius of ∼16 pc, and a visual extinction A _V , through the torus, to the near-infrared emission regions of >66 mag.     

Cyclic variations in the angular diameter of χ Cygni

We report the direct detection of cyclic diameter variations in the Mira variable χ Cygni. Interferometric observations made between 1997 July and 1999 September, using the Cambridge Optical Aperture Synthesis Telescope (COAST) and the William Herschel Telescope (WHT), indicate periodic changes in the apparent angular diameter at a wavelength of 905 nm, with amplitude 45 per cent of the smallest value. The star appears largest at minimum light. Measurements made at a wavelength of 1.3 μm over the same period suggest much smaller size changes. This behaviour is consistent with a model in which most of the apparent diameter variation at 905 nm is caused by a large increase in the opacity of the outer atmospheric layers (which is mostly owing to titanium oxide) near minimum light, rather than by physical motions of the photosphere. The 1.3-μm waveband is relatively uncontaminated by TiO, and so much smaller size changes would be expected in this band. The latest non-linear pulsational models predict maximum physical size close to maximum light, and increases in opacity near minimum light that are too small to reproduce the diameter variation seen at 905 nm. This suggests either that the phase-dependence of the model pulsation is incorrect, or that the opacities in the models are underestimated. Future interferometric monitoring in uncontaminated near-infrared wavebands should resolve this question.     

Geochronologic evidence for Early Cretaceous volcanic activity on Barton Peninsula, King George Island, Antarctica

Ages of six volcanic and plutonic rocks on Barton Peninsula, King George Island, were determined using ⁴⁰Ar/³⁹Ar and K-Ar isotopic systems. The ⁴⁰Ar/³⁹Ar and K-Ar ages of basaltic andesite and diorite range from 48 My to 74 My and systematically decrease toward the upper stratigraphic section. Two specimens of basaltic andesite which occur in the lowermost sequence of the peninsula, however, apparently define two distinct plateau ages of 52-53 My and 119-120 My. The latter is interpreted to represent the primary cooling age of basaltic andesite, whereas the former is interpreted as the thermally-reset age caused by the intrusion of Tertiary granitic pluton. The isochron ages calculated from the isotope correlation diagram corroborate our interpretation based on the apparent plateau ages. It is therefore likely that volcanism was active during the Early Cretaceous on Barton Peninsula. When the K-Ar ages of previous studies are taken into account with our result, the ages of basaltic andesite in the northern part of the Barton Peninsula are significantly older than those in the southern part. Across the north-west-south-east trending Barton fault bounding the two parts, there are significant differences in geochronologic and geologic aspects.     

Spatio-temporal variability in sea surface wind stress near and off the east coast of Korea

Sea surface wind stress variabilities near and off the east coast of Korea, are examined using 7 kinds of wind datasets from measurements at 2 coastal (land) stations and 2 ocean buoys,satellite scatterometer (QuikSCAT), and global reanalyzed products (ECMWF,NOGAPS,and NCEP/NCAR). Temporal variabilities are analyzed at 3 frequency bands; synoptic (2-20 d), intra-seasonal (20-90 d),and seasonal (>90 d).Synoptic and intra-seasonal     

Hydrology of hillslope‐wetland streams,Polar Bear Pass,Nunavut, Canada

Polar Bear Pass is a large High Arctic low‐gradient wetland (100 km²) bordered by low‐lying hills which are notched by a series of v‐shaped valleys. The spring and summer hydrology of two High Arctic hillslope‐wetland catchments, a first‐order stream, 0·2 km² Landing Strip Creek (LSC) and a larger second‐order basin, 4·2 km² Windy Creek (WC), is described here. A water balance framework was employed in 2008 to examine the movement of water from upland reaches into the low‐lying wetland. Snowcover was low in both basins (<50 mm in water equivalent units), but they both exhibited nival‐type regimes. After the main snowmelt season ended, runoff ceased in the smaller catchment (LSC), but not at the larger basin (WC) which continued to flow throughout the summer. Both basins responded to summer rains in different ways. At LSC, late‐summer continuous streamflow occurred only when rainfall satisfied the large soil moisture deficit in the upper bowl‐shaped zone of the basin. At WC, the presence of thinly thawed, ice‐rich polygonal terrain within the stream channel and in the upper reaches of the catchment likely limited infiltration in these near‐stream zones and enhanced runoff in response to both moderate and high rainfall. Subsequently, seasonal runoff ratios differed between the two sites (0·19 vs 0·68) as did the seasonal storage + residual (+16 vs ?50 mm). This suggests that the post‐snowmelt season runoff response to summer precipitation is very much modified by the unique basin characteristics (soil‐type, vegetation, ground ice) and their location within each stream order type. Copyright © 2010 John Wiley & Sons, Ltd.