Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Affine distortion of small GPS networks with large height differences

GPS is a promising tool for real-time monitoring of deformations of slopes or large structures. However, remaining systematic effects in GPS phase observations after double differencing and application of a priori models affect the resulting coordinates. They complicate the proper separation of the actual deformations from pseudo-deformations induced by the systematic effects. This paper shows that for small monitoring networks (baseline lengths <5 km) only affine distortions of the network geometry are generated by the remaining distance dependent systematic effects, e.g. unmodelled tropospheric and ionospheric propagation effects, or satellite orbit errors. Hence, a generic correction model is given by a three-dimensional affine transformation involving a maximum of 12 transformation parameters. For the determination of these parameters, four high quality GPS stations are necessary which are not affected by the actual deformations to be monitored. Based on the analysis of network geometries of synthetic GPS networks with large height differences and considering the physics of the GPS observations it is shown, however, that less than 12 parameters are sufficient for the computation of the corrections. The proposed 8 parameter model was applied to the GPS monitoring network of the Gradenbach landslide. For this small network with large height differences, it was shown that the distortions can be reduced by about 75%.     

A Discussion of IGS Solutions and Their Impact on Geodetic and Geophysical Applications

The International Association of Geodesy officially established the International GPS Service (IGS) on Janaury 1, 1994. Its prime objective is to provide support and a rerefence system for a wide variety of scientific and practical applications involving GPS. To fulfill its role the IGS also generates, in addition to its fundamental products (orbital/staion positions and consistent Earth orientation parameters), additional reference-system products providing the necessary infrastructure, standards, and means of calibrations for timing and various atmospheric applications of GPS. The generation and efficient application of IGS products and their impact on a number of positioning and atmospheric applications, including low earth orbit satellites, is reviewed and discussed. @ 1998 John Wiley & Sons, Inc.     

Strain determination from the measurement of pebble shapes

Cross-sections of pebbles or other near-ellipsoidal bodies in rocks can be measured in three planes, conveniently chosen orthogonal to each other, but otherwise oriented arbitrarily. The three sets of measurements, referred to a single Cartesian coordinate system, can in principle be used to calculate the average pebble shape. Some of these measurements, however, are necessarily redundant and, generally, not compatible without adjustments for the distribution of an error. The calculation of the average ellipsoid is developed, as is that of the strain which transforms an original sphere into such an ellipsoid. This calculation involves the distribution by a weighted least-squares method of the error due to redundancy and leads to the assignment of an estimated error to each of the second-rank tensor components of the strain. The assumption is made that, after being referred to the common coordinate system, the measured values for each tensor component have a normal distribution. This assumption may not always be correct but could be tested before this method is used.     

Eodiagenetische Vorgänge bei der Bildung von Salinargesteinen

Zusammenfassung Chemische Präzipitate bleiben als Sedimente nur so lange erhalten, als sie mit der darüberstehenden Lösung, dem Bodenwasser des Salinarbeckens, im chemischen Gleichgewicht stehen. Die in dem Laugenkörper solcher Meeresbecken bestehenden, horizontalen Dichtegrenzen, die auf Konzentrationsunterschieden beruhen, können sich durch klimatische, meeresgeographische u. a. Veränderungen vertikal verschieben. Dadurch ist das Sediment (der Bodenkörper) Umbildungen ausgesetzt. Verdünnung der Lauge bringt entweder totale Wiederauflösung oder selektive Rücklösung der leichtestlöslichen Sediment-Anteile mit sich: durch NaCl-Auflösung bei Haliten ein tonig-anhydritisches Residuum (hardground), Sylvinitisierung (bis Halitisierung) durch Ent-Carnallitisierung (MgCl₂-Wegführung) bei Kalisalzen. Tiefgreifende Umkristallisationen und Entstehung von polygonalen Pfeilern erheblicher Tiefenerstreckung sprechen für Stillstand der Sedimentation und für subaquatische Verkarstung. Auf mechanische Umformungen durch Wellenschlag gehen wohl Augensalze und Knollenanhydrite zurück (Tempestite). An paläogeographisch geeigneten Positionen entstanden durch Gleitbewegungen (slumping) Breccienbänke und Falten erheblichen Ausmaßes in Anhydriten und Kalisalzen. Alle diese Vorgänge werden in das früheste Stadium der Diagenese eingeordnet.Zur Vermeidung der aus zwei verschiedenen Sprachen zusammengesetzten Wortkombination Frühdiagenese wird die BezeichnungEodiagense hiermit in Vorschlag gebracht.

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Chemical deposits are only preserved as sediments when they are in chemical equilibrium with the lowermost part of the brine basin. The brine bedding, caused by density, or concentration respectively, can be disturbed by changes of climate, by currents a. s. o. When the brine boundaries are shifted in vertical direction the bottom sediment may be transformed. A thinning of the brine will give rise either to total re-dissolution or to any selective removal of the highest soluble substance, f. i. NaCl from rock salt, by leaving anhydritic or marly residuals (hardground), or MgCl₂ from Carnallite, by leaving Sylvite etc. Breaks within the progressive sedimentation produce polygonal structures reaching several meters down into the pre-existing halite sediment. And thatone may be recrystallized in big scale. Physical influence, as movement in the waterbody by wind and waves, gave rise to so-called augensalz, fragmental anhydrites a. s. o. Brecciated anhydrites as well as huge creeping folds in anhydrites and in potash beds have to be explaned by slumping.All these transformations are caused by early diagenesis. For avoiding the term early diagenesis≓ which is composed by 2 words of different languages, the wordEodiagenesis is proposed herewith.

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Résumé Les sédiments chimiques ne sont conservés qu'aussi longtemps qu'ils sont en équilibre chimique avec la partie basale de la saumure qui se trouve au-dessus d'eux. Les plans de stratification, dûs aux différences de densité liées à la concentration en sels dans la saumure peuvent se déplacer verticalement sous l'action d'influences climatiques, océaniques, tectoniques etc., ce qui expose le sédiment déposé à des transformations. Une dilution de la saumure peut provoquer une redissolution totale ou une dissolution sélective des sels suivant leur solubilité. Par example: dans les halites normales, la solubilisation du NaCl laissera comme résidu un »hardground« composé d'une substance argiloanhydritique; dans les sels potassique, par la dissolution sélective du MgCl₂, la carnallitite sera transformée en sylvinite. — Dans nombre de gisements de halite des structures en pilliers polygonaux de quelques mètres de puissance, où la halite peut Être complètement récrystallisée sont probablement à attribuer à un arrÊt de la sédimentation et à une karstification.Des textures »conglomératiques« observées dans les anhydrites et dans les halites (»Knollenanhydrit«, »Augensalz«), sont à rapporter à l'action des vagues et pourraient donc Être des »tempestites«. Des bancs bréchoides et les plis d'ampleur considérable dans les anhydrites et les sels potassiques ne peuvent Être expliqués que par des glissements subaquatiques.Tous ces événements sont à classer dans un stade très précoce de la diagénèse. Pour éviter le terme de »Frühdiagenese« qui provient de deux langues différentes, il est proposé ici, de désigner ces changements diagénétique précoces sous le nom de »éodiagénèse«.

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, . , . — « » — . , , , - — hardground —, — — . . . . . , , « » «».

     

Thermal metamorphism of primitive meteorites—IX. On the mechanism of trace element loss from Allende heated up to 1400° C

We report data for Ag, Bi, Cd, Co, Cs, Ga, In, Se, Te, Tl and Zn determined by neutron activation in Allende samples heated for one week at 100° increments in the 1000–1400°C range in a low pressure (initially 10^?5atmH₂) environment using an apparatus of novel design. In the extremes, concentrations of these trace elements—initially present at ppm-ppb levels—in unheated material are lowered even farther by factors of 10^?4–10^?5 over a broad temperature span. Loss of some elements above 1000°C extends trends evident below 1000°C; loss of others is even more extreme. On Arrhenius diagrams some elements exhibit but one apparent activation energy over the entire temperature span of loss while others exhibit 2 or 3, each operative in a particular temperature region. These discontinuities seem related to mineralogic/petrologic alteration and probably reflect differences in diffusion mechanism rather than siting differences. The extension of previous experiments into the temperature regime postulated for chondritic differentiation should lead to a better understanding of the evolution of meteoritic parent bodies.     

U-Pb and Rb-Sr dating of a polymetamorphic nappe terrain: The Caledonian Jotun nappe,southern Norway

The Caledonian Jotun nappe in the Tyin area of southern Norway has been investigated using U-Pb analysis of zircon and sphene and Rb-Sr measurements of minerals and whole rocks, with special reference to the reaction of the isotope systems to various kinds of metamorphic event. The nappe consists of Precambrian basement rocks and their cover, inversely thrust over the Baltic shield and its parautochthonous, presumably lower Paleozoic sediments during the Caledonian orogeny. While the nappe basement retained its pre-Caledonian structures, the nappe cover was penetratively deformed and metamorphosed to lower greenschist facies conditions.U-Pb analyses of zircon and sphene ofnappe basement rocks point to the crystallization of a syenitic to monzonitic magma at 1694± 20m.y., the intrusion of gabbros into the syenites and monzonites at 1252_?25⁺²⁸ m.y., and the metamorphism (upper greenschist-lower amphibolite facies) and deformation (gneissification and mylonitization) of the whole complex at 909± 16m.y. Although this latest event caused strong lead loss in all zircon populations, it had no influence on the Rb-Sr system on a whole rock scale. The Caledonian movements did not disturb the U-Pb system of zircon and sphene but strongly influenced the Rb-Sr system in certain minerals and zircon and/or its inclusions (K-feldspar and brown biotite partially, green biotite completely reset).In contrast to the nappe basement, zircons from thecover rocks show pronounced lead loss during the Caledonian metamorphism/deformation — U-Pb analysis give discordia lower intercept ages of 415± 21 m.y. and 395± 6m.y. Again, however, the Rb-Sr whole-rock system has not been reset in Caledonian time. Minerals from the same rocks which provided the zircons give Rb-Sr isochron ages of 390± 11m.y. and 386 ± 20 m.y.Comparison of U-Pb and Rb-Sr results from the nappe basement demonstrates that only the analysis of U-Pb systematics in zircon and especially sphene resolved the 900-m.y. event. Rb-Sr mineral data alone yield ambiguous results.The results from the nappe cover confirm that U-Pb analyses from penetratively deformed sediments are very useful in dating a metamorphic/tectonic event in lower greenschist facies conditions.From the measured cell dimensions of the zircon populations it is concluded that lead can be completely retained in zircon during recrystallization.     

Zur geomagnetischen Tiefensondierung

Zusammenfassung Eine Kurvenvergleichsmethode zur Interpretation räumlicher Induktions-pfeilprofile wird unter der Voraussetzung entwickelt, dass die Verteilung der von den geomagnetischen Variationen im Erdinnern induzierten Ströme linear ist. Sie gründet sich auf die lineare Abhängigkeit der Länge des Induktionspfeils von der vertikalen Komponente des Biot-Savartschen Gesetzes. Die Frequenzabhängigkeit des Induktionspfeiles ermöglicht die Angabe eines für die Leitfähigkeitsstruktur charakteristischen Widerstandes und einer Induktivität. Wird zur Bestimmung von Induktionspfeilen das gesamte Horizontalfeld benutzt, so geht die Linearität der Beziehung zwischen Pfeillänge und Ortsfunktion verloren. Für eine Reihe von Strommodellen werden derartige Ortsfunktionenp _z berechnet und diskutiert. Sie dienen als Beispiele von Musterkurven für die entwickelte Interpretationsmethode.

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Summary One curve-matching method is developed in order to interprete the geomagnetic induction arrow profiles when the distribution of telluric currents in the underground is assumed to be linear. It bases on the linear dependence of the lengths of the induction arrows from the vertical component of the Biot-Savarts Law, which is a function of the radius vector. This is valid when the inducing field has only a horizontal component and the induced horizontal field is zero. In case that the model approximates the current distribution one gets a resistivity and an inductivity from the dependence of frequency of the induction arrows. Some model curves concerning several current distributions are drawn and discussed.

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Mitteilung aus dem Geomagnetischen Institut der DAW, Potsdam, Nr. 212.