Infrared array measurements of sunspot magnetic fields

We have used a 128 × 128 format HgCdTl infrared array with the Sacramento Peak Observatory Vacuum Telescope (VTT) and Echelle spectrograph to obtain two-dimensional observations of the true magnetic field strength in a sunspot. The system we describe retains all of the spectral information contained in the unpolarized IR Fraunhofer line profile with time resolution of about a minute (depending on the scan area and spatial resolution). Unlike previous optical observations (cf. Adam, 1990), infrared observations readily allow direct field strength measurements out to the outer edge of the penumbra. Our data suggest that the magnetic flux density in the outer penumbra is not well described by an extrapolation of the quadratic polynomial, in normalized central distance, that describes the umbral field. We measure a relatively high field strength of 800 G at the penumbra-quiet-Sun boundary, which is consistent with the return-flux model of Osherovich and Garcia (1989).     

Late glacial environment and climate development in northeastern China derived from geochemical and isotopic investigations of the varved sediment record from Lake Sihailongwan (Jilin Province)

Total organic carbon (TOC) content, total nitrogen (TN) content, stable nitrogen isotope (δ¹⁵N) and stable organic carbon isotope (δ¹³C_org) ratios were continuously analysed on a high resolution sediment profile from Lake Sihailongwan (SHL), covering the time span between 16,500 and 9,500 years BP. Strong variations of the investigated proxy parameters are attributed to great climatic fluctuations during the investigated time period. Variations in organic carbon isotope ratios and the ratio of TOC/TN (C/N ratio) are discussed with respect to changing proportions of different organic matter (OM) sources to bulk sedimentary OM. Phases of high TOC content, high TN content, depleted δ¹³C_org values and high δ¹⁵N values are interpreted as times with increased productivity of lacustrine algae in relation to input of terrigenous organic matter. Two distinct phases of enriched nitrogen isotope ratios from 14,200 to 13,700 and 11,550 to 11,050 years BP point towards a reduced phytoplankton discrimination against ¹⁵N due to a diminished dissolved inorganic nitrogen pool. The combination of geochemical (TOC, TN, C/N ratio) and isotopic (δ¹³C_org, δ¹⁵N) proxy parameters points to a division of climate development into four stages. A cold and dry stage before 14,200 years BP, a warm optimum stage with high phytoplankton productivity from 14,200 to 12,450 BP, a colder and drier stage from 12,450 to 11,600 BP and a stage of climatic amelioration with high variability in TOC and TN contents after 11,600 BP. These results are discussed in relation to monsoon variability and Northern Hemisphere climate development of the late glacial.     

Sedimentary evidence for recent eutrophication in the northern basin of Lake Taihu,China: human impacts on a large shallow lake

Environmental change in Lake Taihu and its catchment since the early to middle part of the twentieth century has left a clear geochemical record in the lake sediments. The human activities in the lake and its catchment responsible for the change include agriculture, fishery, urbanisation, sewage and industrial waster disposal. Sediment cores were collected from Meilian Bay of northern Lake Taihu to investigate the record of anthropogenic impacts on the lake’s ecosystem and to assess its natural, pre-eutrophication baseline state. Two marked stratigraphic sediment units were identified on the basis of total phosphorus concentration (TP), pigments, total organic carbon (TOC)/total nitrogen (TN), δ¹³C and δ¹⁵N corresponding to stages in the lake history dominated by phytoplankton, and by aquatic macrophytes. Results show that as TP loading increased from the early 1950s the lake produced sediments with increasing amounts of organic matter derived from phytoplankton. In the early 1950s, the first evidence for eutrophication at the Meilian Bay site is recorded by an increase in C/N values and in sediment accumulation rate, but there is little change in phosphorus concentrations, pigments, δ¹³C and δ¹⁵N at this time. After 1990 a more rapid increase in trophic status took place indicated by increased levels of phosphorus, pigments, δ¹⁵N and by decreased δ¹³C and TOC/TN values in the lake sediments. The first increase in trophic status of the early 1950s results mainly from agricultural development in the catchment. In contrast, the acceleration from ca. 1990 originates from the recent development of fisheries and the urbanisation and industrialisation of the catchment.     

Electrical conductivity of the earth's crust and upper mantle

This review summarizes recent results of electrical resistivity studies of the earth's crust and upper mantle. Where available, the data are discussed in the context of further regional geophysical information. Electrical resistivity is very sensitive to a wide range of petrological and physical parameters, e.g., to carbon, fluids, volatiles and enhanced temperatures, making electrical resistivity methods a powerful tool in crust and upper mantle investigations. Yet, the general increase in resistivity data of the crust and mantle has not ended the battle of explanations for anomalous crustal conductivities.     

Zeitliche Beziehung zwischen variskischer Tektonik und initialem Magmatismus in Ostthüringen

Zusammenfassung Die voroberdevonischen Kerngesteine des Bergaer Sattels werden von wenige Meter mächtigen konkordanten und diskordanten Diabas-Gängen durchschlagen. Die diskordanten Gänge liegen ausnahmslos in der achsenflächenparallelen Transversalschieferung (s₁). Die Erklärung dieser Lagerungsform durch eine voroberdevonische Schieferung oder durch die Annahme eines nachsudetischen Intrusionsalters stünde im Widerspruch zu den bisherigen Ansichten. Eine genaue Überprüfung dieser s₁-parallelen Gänge erweist deutlich deren Bindung an die Mittelschenkel der Falten niederer Ordnung. Die aus der Schichtung abweichende Intrusion folgte demnach achsenflächenparallelen Schenkelbrüchen tiefoberdevonisch angelegter Embryonalfalten. Sie werden der reußischen Phase v.Gaertners (1951) zugeschrieben. Diese Bewegung an der Wende Mittel-/Oberdevon wird als intrageosynklinale Vorfaltung der saxothuringischen Zone des variskischen Orogens aufgefaßt.Dieser Beitrag ist das Teilergebnis einer regionalgeologischen Untersuchung, deren Anregung und Betreuung Verf. Herrn Professor Dr. F.Deubel verdankt.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.