Hydrogeochemical characterization and evolution of a regional karst aquifer in the Cuatrociénegas area,Mexico

The Cuatrociénegas area is useful for the investigation of the effect of groundwater extraction in the Chihuahuan freshwater xeric ecoregion. It has been investigated at this time using a selection of geochemical indicators (major, minor and trace elements) and δ³⁴S data, to characterize the origin of groundwater, the main geochemical processes and the mineral/groundwater interactions controlling the baseline geochemistry. The area is composed of limestones of Mesozoic age, with a composite thickness of about 500 m, overlaid by basin fill (poorly consolidated young sediments). Substantial water extraction and modification of natural discharges from the area along the last century have produced a detrimental impact on ecosystem structure and function. Water–rock interactions, mixing and evaporative processes dominate the baseline groundwater quality. Natural recharge is HCO₃–Ca type in equilibrium with calcite, low salinity (TDS?<?500 mg/L), Cl^? lower than 11 mg/L and average Li⁺ concentration of 0.005 mg/L. Along the groundwater flow systems, δ³⁴S evidence and mass transfer calculations indicate that Cretaceous gypsum dissolution and dedolomitization reactions adjust water composition to the SO₄–Ca type. The increase of water–rock interaction is reflected by Cl^? values increase (average 68 mg/L), TDS up to about 1500 mg/L and an average Li⁺ concentration of 0.063 mg/L. Calculations with chemical geothermometers indicate that temperature at depth could be at maximum of 15–20 °C higher than field-measured temperature for pozas. After groundwater is discharged to the surface, chemical evolution continues; water evaporation, CO₂ degassing and precipitation of minerals such as gypsum, calcite and kaolinite represent the final processes and reactions controlling water chemical composition.     

Coastal lateral spreading in the world heritage site of the Tramuntana Range (Majorca,Spain). The use of PSInSAR monitoring to identify vulnerability

The Bàlitx area is located on the steep coastal side of the Tramuntana Range (Majorca), a mountainous region which was declared a World Heritage Site by UNESCO in 2011 in the cultural landscape category. The Bàlitx site was occupied by farming areas with dry stone constructions and water storing systems of both Roman and Islamic origin. The coastal landscape is characterised by a large fault escarpment of up to 260 m in height. Lateral spreading processes are favoured by local stratigraphy and tectonics in an energetic coastal dynamics scenario. Block spreading morphologies are identified along the escarpment, with large, rocky blocks of volumes up to 60?×?10³ m³ moving very slowly until their collapse. Consequently, a thick and highly karstified breccia deposit is accumulated at the base of the scarp. The lowest, oldest breccia outcrop has been dated (Th/U), and an age of 82.5?±?5.6 kyr was obtained, reflecting the time span this process has been active. Additionally, numerous geomorphological slope features are identified in the area: landslides, rockfalls, and, more specifically, long and deep cracks in the hanging wall block of the fault, which also reveal active lateral spreading processes. Coastal dynamics have been investigated by interpreting offshore geophysical studies, bathymetry data and borehole information to determine the role of wave energy in the stability of the slope. Additionally, 14 SAR images from the ALOS PALSAR satellite have been exploited for the present work, covering a period spanning from 2007 to 2010, an anomalous rainy period in the region. Images were processed using the Persistent Scattered Interferometry (PSI) technique. PSInSAR results reveal that the rate of movement for the Bàlitx lateral spreading is extremely low (??5.2 mm/year on average), but major activity has been detected in the NE sector, where velocity rates can reach values of up to ??16 mm/year Coastal dynamics in the area can explain this, as a small island generates wave refraction and reflection determining more intense erosive processes in the NE part, which lead to a greater destabilising effect on the slopes. A simple vulnerability approach has been developed to take the elements of cultural heritage into account. Vulnerability increases from SW to NE, in accordance with landslide activity. The Bàlitx case study could provide a testimony to the effects of mass movements and coastal dynamics in an exceptional example of Mediterranean agricultural landscape.     

Seismogenic basin and range and intra‐arc normal faulting in the central Mexican Volcanic Belt,Querétaro,México

North‐northwest normal faults intersect ENE normal faults in the vicinity of Querétaro City, in central México, affecting the Miocene–Pliocene northern‐central sector of the Mexican Volcanic Belt province. This intersection produced an orthogonal arrangement of grabens, half‐grabens and horsts that include the Querétaro graben. The NNW faults are part of the Taxco–San Miguel de Allende fault system, which is proposed here as part of the southernmost Basin and Range province in México. The ENE to E–W faults are part of the E–W oriented Chapala–Tula fault zone, which has been interpreted as an active intra‐arc fault system of the Mexican Volcanic Belt. Seventy‐four normal faults were mapped, of which the NNW faults are the largest and have the best morphological expression in the region. More numerous, although shorter, are the ENE faults. Total length of the ENE faults is greater than the total length of the NNW faults. Both sets are dominantly normal faults, indicating ENE extension for the NNW set and NNW extension for the ENE set. Field data indicate that displacement on the two fault sets has overlapped in time, as some NNW faults are younger than some ENE faults, which are supposed to be the younger ones. Seismicity in 1998 on a NNW fault indicates ENE active extension on the NNW faults. These observations support our interpretation that the northern Mexican Volcanic Belt lies on the boundary between the Basin and Range province, which is undergoing ENE extension, and the central Mexican Volcanic Belt province, which is undergoing northerly extension. The apparent overlap in space and time of displacements on the two fault sets reflects the difference in stress regime between the two provinces. Copyright © 2005 John Wiley & Sons, Ltd.     

Evaluation of a wind erosion model in a desert area of northern Asia by eddy covariance

For the first time, vertical fluxes of mineral dust measured by Eddy Covariance in two desert sites of Northern Asia have been used to test the performances of a wind erosion model in the field. Soil parameters required by the model were obtained through field and laboratory determinations. Model predictions and direct measurements have been compared. The main finding was that the direction of the horizontal wind relative to the orientation of nebkhas played a crucial role in determining the emission of particles in one of the investigated sites. Being unable to simulate such interaction, the model generally overestimated the actual emission. It provided, instead, reliable predictions (r² = 0·87) when the wind direction was suitable in detaching loose erodible elements placed on nebkhas thanks to their normal orientation. Copyright © 2009 John Wiley & Sons, Ltd.     

Array analysis using circular-wave-front geometry:an application to locate the nearby seismo-volcanic source

The zero-lag cross-correlation technique, used for array analysis in the hypothesis of plane waves, has been modified to allow the wave front to be circular. Synthetic tests have been performed to check the capability of the method, which returns the input test data when the source–array distances are not greater than two or three times the array aperture. For this distance range the method furnishes an estimate of the apparent velocity and the epicentral coordinates of the source. For more distant sources the method becomes equivalent to that based on the planar-wave approximation, which gives an estimate of the backazimuth to the source and the apparent velocity. The method has been applied to seismic data recorded at the active volcano located at Deception Island, Antarctica. 35 volcanic long-period events occurring in a small swarm were selected. Results show that the epicentres are close to the array (between 0.4 and 2 km) and aligned in a SW direction, in agreement with one of the main directions of the fracture system of Deception volcano.     

Hydrodynamic model of cells for designing systems of urban groundwater drainage

An improved mathematical hydrodynamic quasi-two-dimensional model of cells, CELSUB3, is presented for simulating drainage systems that consist of pumping well fields or subsurface drains. The CELSUB3 model is composed of an assemblage of algorithms that have been developed and tested previously and that simulate saturated flow in porous media, closed conduit flow, and flow through pumping stations. A new type of link between aquifer cells and drainage conduits is proposed. This link is verified in simple problems with well known analytical solutions. The correlation between results from analytical and mathematical solutions was considered satisfactory in all cases. To simulate more complex situations, the new proposed version, CELSUB3, was applied in a project designed to control the water-table level within a sewer system in Cha?ar Ladeado Town, Santa Fe Province, Argentina. Alternative drainage designs, which were evaluated under conditions of dynamic recharge caused by rainfall in a critical year (wettest year for the period of record) and a typical year, are briefly described. After analyzing ten alternative designs, the best technical–economic solution is a subsurface drainage system of closed conduits with pumping stations and evacuation channels. Electronic Publication     

Combined effects of waves and plants on a mud deposition event at a mudflat-saltmarsh edge in the Bahía Blanca estuary

This study was carried out at the Bahía Blanca Estuary, Argentina, at the seaward edge of a saltmarsh. The saltmarsh-mudflat boundary in the study area shows sediment deposits at a higher elevation immediately seaward of the saltmarsh edge. We compared field determinations of water velocity, bed shear stress, wind wave conditions and variations of the bed elevation in the mudflat and within the Spartina alterniflora canopy at the seaward edge of a saltmarsh, and we evaluated the relative role of vegetation in the observed morphology. A mud deposition event that raised bed elevation in more than 5 cm occurred during the study period, with TSS concentrations > 500 mg l⁻¹, but simultaneous measurements performed on the bed levels confirmed that the sediments deposited did not originate from local resuspension within the edge of the canopy. In similar tidal cycles in terms of local wave activity and bed shear stresses at the sampling site, deposition occurred only with winds aligned with the azimuth of the Canal Principal, reaching a maximum fetch of more than 20 km in front of the sampling site.     

The suevite of drill hole Yucatàn 6 in the Chicxulub impact crater

Abstract— The suevite breccia of the Chicxulub impact crater, Yucatàn, Mexico, is more variable and complex in terms of composition and stratigraphy than suevites observed at other craters. Detailed studies (microscope, electron microprobe, SEM, XRF) have been carried out on a noncontinuous set of samples from the drill hole Yucatàn 6 (Y6) located 50 km SW from the center of the impact structure. Three subunits can be distinguished in the suevite: the upper unit is a fine‐grained carbonate‐rich suevite breccia with few shocked basement clasts, mostly altered melt fragments, and formerly melted carbonate material; the middle suevite is a coarse‐grained suevite with shocked basement clasts and altered silicate melt fragments; the lower suevite unit is composed of shocked basement and melt fragments and large evaporite clasts. The matrix of the suevite is not clastic but recrystallized and composed mainly of feldspar and pyroxene. The composition of the upper members of the suevite is dominated by the sedimentary cover of the Yucatàn target rock. With depth in well Y6, the amount of carbonate decreases and the proportion of evaporite and silicate basement rocks increases significantly. Even at the thin section scale, melt phases of different chemistry can be identified, showing that no widespread homogenization of the melt took place. The melt compositions also reflect the heterogeneity of the deep Yucatàn basement. Calcite with characteristic feathery texture indicates the existence of formerly pure carbonate melt. The proportion of carbonate to evaporite clasts is less than 5:1, except in the lower suevite where large evaporite clasts are present. This proportion constrains the amount of CO₂ and SO_X released by the impact event.