Organic geochemistry of Walvis Bay diatomaceous ooze—I. Occurrence and significance of the fatty acids

Diatomaceous ooze of the shelf off Walvis Bay (S.W. Africa) was analysed for lipid material. The lipids from the sediment consist of a mixture of hydrocarbons, alcohols, ketones, fatty acids, sterols, carotenoid pigments and chlorophylls. The total fatty acid mixture has been analysed by capillary gas chromatography mass spectrometry and shown to consist of straight chain, iso-, anteiso- and isoprenoid acids. The environmental setting of the S.W. African shelf (Walvis Bay) makes it possible to discuss these fatty acids as markers for the fate of organic matter. The acids in the sediment point to a generation during passage of algal lipids through levels of microbial activity either on or slightly above the burial surface.     

Immunological studies on microbial mats from Solar Lake (Sinai)— A contribution to the organic geochemistry of sediments

Immunological and biochemical techniques were used to investigate organic matter in microbial mats from Solar Lake (Sinai, Egypt). Antibodies, elicited in rabbits against samples taken at different depths from a core of these mats, were used for the detection of immunological determinants preserved in these samples. Special attention was given to an antiserum directed against a top mat fraction (3–10 mm depth) and an antiserum against a fraction from a lower section of the core (380–390 mm depth). Both antisera, tested in a dot-blot immunobinding assay, were found to give positive reactions with organic matter from different depths of the sediment. An immunohistochemical experiment with the antisera points to antigenic determinants on Recent and subfossil sheaths of Microcoleus. In addition, extracts of sediment samples were submitted to electrophoresis in polyacrylamide gels in order to characterize the separated macromolecules by immunological means. The results showed a rapid decrease in the number of antigenic determinants from Recent to subfossil samples. However, even in the deepest layers of the sediment (690–700 mm depth) intact biopolymers were detected.     

A comparison of the sedimentary records of the 1960 and 2010 great Chilean earthquakes in 17 lakes: Implications for quantitative lacustrine palaeoseismology

Seismically‐induced event deposits embedded in the sedimentary infill of lacustrine basins are highly useful for palaeoseismic reconstructions. Recent, well‐documented, great megathrust earthquakes provide an ideal opportunity to calibrate seismically‐induced event deposits for lakes with different characteristics and located in different settings. This study used 107 short sediment cores to investigate the sedimentary impact of the 1960 M_w 9·5 Valdivia and the 2010 M_w 8·8 Maule earthquakes in 17 lakes in South‐Central Chile (i.e. lakes Negra, Lo Encañado, Aculeo, Vichuquén, Laja, Villarrica, Calafquén, Pullinque, Pellaifa, Panguipulli, Neltume, Riñihue, Ranco, Maihue, Puyehue, Rupanco and Llanquihue). A combination of image analysis, magnetic susceptibility and grain‐size analysis allows identification of five types of seismically‐induced event deposits: (i) mass‐transport deposits; (ii) in situ deformations; (iii) lacustrine turbidites with a composition similar to the hemipelagic background sediments (lacustrine turbidites type 1); (iv) lacustrine turbidites with a composition different from the background sediments (lacustrine turbidites type 2) and (v) megaturbidites. These seismically‐induced event deposits were compared to local seismic intensities of the causative earthquakes, eyewitness reports, post‐earthquake observations, and vegetation and geomorphology of the catchment and the lake. Megaturbidites occur where lake seiches took place. Lacustrine turbidites type 2 can be the result of: (i) local near‐shore mass wasting; (ii) delta collapse; (iii) onshore landslides; (iv) debris flows or mudflows; or (v) fluvial reworking of landslide debris. On the contrary, lacustrine turbidites type 1 are the result of shallow mass wasting on sublacustrine slopes covered by hemipelagic sediments. Due to their more constrained origin, lacustrine turbidites type 1 are the most reliable type of seismically‐induced event deposits in quantitative palaeoseismology, because they are almost exclusively triggered by earthquake shaking. Moreover, they most sensitively record varying seismic shaking intensities. The number of lacustrine turbidites type 1 linearly increases with increasing seismic intensity, starting with no lacustrine turbidites type 1 at intensities between V½ and VI and reaching 100% when intensities are higher than VII½. Combining different types of seismically‐induced event deposits allows the reconstruction of the complete impact of an earthquake.     

Geodemographic biases in crowdsourced knowledge websites: Do neighbours fill in the blanks?

Crowdsourced knowledge websites such as Wikipedia and OpenStreetMap are increasingly attracting a critical literature which has highlighted the fact that the contributor bases of these sites are often geodemographically biased: drawn from more affluent and better educated segments of the population. However, while bias in contributors is well known, we know less about whether this also results in a bias in outcomes on these websites: or whether the partial portion of the population which does make contributions also works to “fill in the blanks”, by adding knowledge about other less well-off neighbouring areas which have not attracted a contributor base. This article addresses the question of whether such “neighbourhood effects” exist in practice. It makes use of a novel dataset of alcohol license data in the UK to assess variation in the completeness of the volunteer geographic information site OpenStreetMap. The results support existing literature in showing that completeness is related to demographics: areas with higher levels of wealth and education typically exhibit higher levels of completeness. The article then makes a novel contribution by showing evidence of the existence of neighbourhood effects: poorer regions with more affluent neighbours typically having higher levels of completeness than poorer regions which are also surrounded by poorer neighbours. The results suggest that crowdsourced knowledge websites can aspire to a kind of completeness even whilst user bases remain partial and biased.     

On the wave propagation in inhomogeneous non-isotropic media

Summary FollowingEason, we have discussed here the propagation of elastic waves in non-homogeneous spheres and cylinders when the curved surface is given a uniform normal loading. The material is assumed to be transversely isotropic with respect to a direction of symmetry, the stress and displacement components within the body may be assumed to depend on one space co-ordinate and time alone. The particular case in which the elastic parameters are proportional to (radius) ⁿ has been considered.     

Disturbances due to time-dependent body forces in a non-isotropic elastic medium

Summary In this paper, the disturbances produced due to time-dependent body forces in an anisotropic elastic medium resting on a semi-infinite non-isotropic layer have been discussed.     

The Son Poc rockfall (Mallorca,Spain) on the 6th of March 2013: 3D simulation

The Son Poc rockfall took place on the 6th of March 2013 in the municipality of Bunyola, on the southern side of the Tramuntana Range (Mallorca) and after a rainy and cold period on the region. A volume of rock of 4.000 m³ was detached from the cliff crowning the peak falling down by toppling. The impact of the boulder caused its fragmentation, and numerous boulders bounced and rolled downslope with volumes from 1 to 35 m³, following two trajectories: southwest (SW) and southeast (SE). The SE trajectory, with a larger runout (376 m), reached an urban area, where some of the boulders hit the roofs and walls of nearby houses, stopping others in their gardening areas. Fortunately, no fatalities occurred despite of the presence of some people at that moment, but the event caused great concern in a region which lives from and for tourism. The Son Poc rockfall has been simulated using RocPro3D software which uses GIS technology to produce 3D rockfall trajectories lines, estimated velocity and energy of falling blocks, as well as bounce heights, impacts, and stopping points. The results are in agreement with field observations and with a very good accuracy between real and modeled outcomes.     

Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.     

二安替比林对羟基苯乙烯基甲烷与钒的高灵敏显色反应

合成了试剂二安替比林对羟基苯乙烯基甲烷 (DApHVM) ,研究了它与V(Ⅴ )的显色反应。在H3PO4介质中 ,Mn(Ⅱ )和Tween 2 0协同作用下 ,DApHVM与V(Ⅴ )生成红色产物 ,λmax为 540nm ,ε=1 0 3× 1 0 6 L·mol-1 ·cm-1 ,V(Ⅴ )的质量浓度在 0～ 50 μg/L内符合比尔定律。方法用于中草药及钢样中V(Ⅴ )的测定 ,结果与原子吸收法一致 ,加标回收率在 96%～ 1 0 5 % ,5次测定结果的RSD <3 5 %。