Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.     

Assessment of calanchi and rill–interrill erosion susceptibilities using terrain analysis and geostochastics: A case study in the Oltrepo Pavese,Northern Apennines,Italy

Soil erosion is one of the most important environmental problems distributed worldwide. In the last decades, numerous studies have been published on the assessment of soil erosion and the related processes and forms using empirical, conceptual and physically based models. For the prediction of the spatial distribution, more and more sophisticated stochastic modelling approaches have been proposed – especially on smaller spatial scales such as river basins. In this work, we apply a maximum entropy model (MaxEnt) to evaluate badlands (calanchi) and rill–interrill (sheet erosion) areas in the Oltrepo Pavese (Northern Apennines, Italy). The aim of the work is to assess the important environmental predictors that influence calanchi and rill–interrill erosion at the regional scale. We used 13 topographic parameters derived from a 12 m digital elevation model (TanDEM-X) and data on the lithology and land use. Additional information about the vegetation is introduced through the normalized difference vegetation index based on remotely sensed data (ASTER images). The results are presented in the form of susceptibility maps showing the spatial distribution of the occurrence probability for calanchi and rill–interrill erosion. For the validation of the MaxEnt model results, a support vector machine approach was applied. The models show reliable results and highlight several locations of the study area that are potentially prone to future soil erosion. Thus, coping and mitigation strategies may be developed to prevent or fight the soil erosion phenomenon under consideration. © 2020 John Wiley & Sons, Ltd.     

The role of urban surfaces (permeable pavements) in regulating drainage and evaporation: development of a laboratory simulation experiment

Permeable pavements and similar stormwater control devices have not been exploited in the UK, in part because their adoption has been hindered by a lack of detailed knowledge of their hydrological performance. This paper describes a research programme that produced detailed information on the hydrological behaviour of a car park surface. The study involved the construction of full‐scale permeable pavement model car park structures and a rainfall simulator for use in the laboratory. A monitoring procedure was developed in order to measure inputs and changes in drainage, storage and evaporation over short and long time‐scales (2 hours to 3 months). A range of simulated rainfalls, which varied in intensity and duration, was applied to the model car park surfaces. Hydrological processes were monitored over an 18‐month period. Results demonstrated that evaporation, drainage and retention in the structures were strongly influenced by the particle size distribution of the bedding material and by water retention in the surface blocks. In general, an average of 55% of a one‐hour duration, 15 mm h⁻¹ rainfall event could be retained by an initially air‐dry structure. Subsequent simulations demonstrated that 30% of a one‐hour duration, 15 mm h⁻¹ rainfall event could be stored by an initially wet structure (with a minimum time interval between rainfall applications of 72 hours). Copyright © 1999 John Wiley & Sons, Ltd.     

Returns from a speculation

A reply to a recent paper by Setten.     

Studies on the flotation of sulphides. I. The effect of Cu(II) ions on the flotation of zinc sulphide

The effect of Cu(II) ions on the froth flotation of ZnS in the absence of any collector has been studied in a Fuerstenau microflotation cell. The flotation of pure synthetic ZnS, in both cubic and hexagonal modifications, can be greatly enhanced by the adsorption of traces of Cu(II) ions. In the case of cubic ZnS, the “activating” effect of Cu(II): (a) involves the stoichiometric replacement of one Zn(II) ion in the lattice by one Cu(II) ion from solution at a rate which is independent of pH (1–5); (b) is noticeable at coverages corresponding to as little as 0.1% of a monolayer, reaches a maximum at coverages of 2–100% of a monolayer, and decreases again at higher coverages; (c) is unaffected by the presence or absence of O₂, by variation of the pH of flotation (6–10), by heating in vacuum at 250°C for two hours or by storing in the dry state for over one year; and (d) does not appear to involve any significant change in surface area or in the state of aggregation of the particles.     

Studies on the flotation of sulphides. II. The effect of urea on the flotation of zinc sulphide

The effect of three hydrophilic non-electrolytes on the flotation of ZnS has been studied using a Fuerstenau microflotation cell. The rate of flotation increases with increasing concentrations of urea(OC(NH₂)₂), but is unaffected by thiourea and slightly decreased by sucrose. This effect of urea was observed with all samples of ZnS (synthetic and natural) studied, is unaffected by extensive purification of the urea and by the presence or absence of O₂, and is reversed by dilution. Urea also increases the rate of flotation (in a Partridge and Smith cell) in the absence of frother. Surface tension measurements showed the absence of detectable concentrations of surfactants in the urea. The presence of urea has no effect on the rate of sedimentation (i.e. on the degree of aggregation) of ZnS or on the volume of water carried over during flotation. It is suggested that the effect of urea is (at least in part) to increase the rate of bubble-particle attachment by modifying the structure of water.     

Speciation and weathering of selenium in upper cretaceous chalk and shale from South Dakota and Wyoming, USA

In geologic materials, petroleum, and the environment, selenium occurs in various oxidation states (VI, IV, 0, -II), mineralized forms, and organo-Se complexes. Each of these forms is characterized by specific chemical and biochemical properties that control the element’s solubility, toxicity, and environmental behavior. The organic rich chalks and shales of the Upper Cretaceous Niobrara Formation and the Pierre Shale in South Dakota and Wyoming are bentoniferous stratigraphic intervals characterized by anomalously high concentrations of naturally occurring Se. Numerous environmental problems have been associated with Se derived from these geological units, including the development of seleniferous soils and vegetation that are toxic to livestock and the contamination of drinking water supplies by Se mobilized in groundwater.This study describes a sequential extraction protocol followed by speciation treatments and quantitative analysis by Hydride Generation-Atomic Absorption Spectroscopy. This protocol was utilized to investigate the geochemical forms and the oxidation states in which Se occurs in these geologic units. Organic Se and di-selenide minerals are the predominant forms of Se present in the chalks, shales, and bentonites, but distinctive variations in these forms were observed between different sample types. Chalks contain significantly greater proportions of Se in the form of di-selenide minerals (including Se associated with pyrite) than the shales where base-soluble, humic, organo-Se complexes are more prevalent. A comparison between unweathered samples collected from lithologic drill cores and weathered samples collected from outcrop suggest that the humic, organic-Se compounds in shale are formed during oxidative weathering and that Se oxidized by weathering is more likely to be retained by shale than by chalk. Selenium enrichment in bentonites is inferred to result from secondary processes including the adsorption of Se mobilized by groundwater from surrounding organic rich sediments to clay mineral and iron hydroxide surfaces, as well as microbial reduction of Se within the bentonitic intervals. Distinct differences are inferred for the biogeochemical pathways that affected sedimentary Se sequestration during periods of chalk accumulation compared to shale deposition in the Cretaceous seaway. Mineralogy of sediment and the nature of the organic matter associated with each of these rock types have important implications for the environmental chemistry and release of Se to the environment during weathering.