Esmeralda Bank: Geochemistry of an active submarine volcano in the Mariana Island Arc

Esmeralda Bank is the southernmost active volcano in the Izu-Volcano-Mariana Arc. This submarine volcano is one of the most active vents in the western Pacific. It has a total volume of about 27 km³, rising to within 30 m of sea level. Two dredge hauls from Esmeralda recovered fresh, nearly aphyric, vesicular basalts and basaltic andesites and minor basaltic vitrophyre. These samples reflect uniform yet unusual major and trace element chemistries. Mean abundances of TiO₂ (1.3%) and FeO^* (12.6%) are higher and CaO (9.2%) and Al₂O₃ (15.1%) are lower than rocks of similar silica content from other active Mariana Arc volcanoes. Mean incompatible element ratios K/Rb (488) and K/Ba (29) of Esmeralda rocks are indistinguishable from those of other Mariana Arc volcanoes. On a Ti-Zr plot, Esmeralda samples plot in the field of oceanic basalts while other Mariana Arc volcanic rocks plot in the field for island arcs.Incompatible element ratios K/Rb and K/Ba and isotopic compositions of Sr (⁸⁷Sr/⁸⁶Sr=0.70342–0.70348), Nd (_ND=+7.6 to +8.1), and O(¹⁸O=+5.8 to +5.9) are incompatible with models calling for the Esmeralda source to include appreciable contributions from pelagic sediments or fresh or altered abyssal tholeiite from subduction zone melting. Instead, incompatible element and isotopic ratios of Esmeralda rocks are similar to those of intra-plate oceanic islands or hot-spot volcanoes in general and Kilauean tholeiites in particular. The conclusion that the source for Esmeralda lavas is an ocean-island type mantle reservoir is preferred.Esmeralda Bank rare earth element patterns are inconsistent with models calling for residual garnet in the source region, but are adequately modelled by 7–10% equilibrium partial melting of spinel lherzolite. This is supported by consideration of the results of melting experiments at 20 kbars, 1,150° C with CO₂ and H₂O as important volatile components. These experiments further indicate that low MgO (4.1%), MgO/FeO^*(0.25) and Ni(12 ppm) in Esmeralda Bank melts are characteristic of initial melts generated by moderate degrees of melting of hydrous and carbonated mantle. Consideration of experimental determinations and spinel-lherzolite to garnet-lherzolite stabilities indicates Esmeralda Bank melts were generated by partial melting within the upper 60–110 km of the mantle.     

General circulation model CO2 sensitivity experiments: Snow-sea ice albedo parameterizations and globally averaged surface air temperature

Two experiments are performed with the NCAR Community Climate Model (CCM) coupled to a swamp ocean with annually averaged solar forcing. A swamp ocean model is one in which the ocean temperature is computed from a surface energy balance. Both experiments are run with present (1 × CO₂) and doubled (2 × CO₂) amounts of atmospheric carbon dioxide (CO₂). The first tests the sensitivity of the model to a snow and sea-ice-albedo formulation which facilitates relatively greater ice melt. The second assesses the model response when the basic state of the model in the control run is colder due to a 2% decrease in solar constant. Both are compared to a previous experiment with the same model using a different snow and sea-ice-albedo formulation and the present value of the solar constant. It is found that the globally averaged surface air temperature increase due to a doubling of CO₂ is highly dependent on (1) the type of snow-sea-ice-albedo formulation used such that the parameterization which better facilitates relatively greater ice melt exhibits a greater sensitivity to increased CO₂, and (2) the basic state of the control run such that the colder the basic state, the greater the warming due to increased CO₂.A portion of this study is supported by the U.S. Department of Energy as part of its Carbon Dioxide Research Program.The National Center for Atmospheric Research is sponsored by the National Science Foundation     

Asymmetric back-arc spreading, heat flux and structure associated with the Central Volcanic Region of New Zealand

The Central Volcanic Region of New Zealand is an active back-arc basin developed within continental lithosphere, and therefore offers a rare opportunity to study back-arc extension from land-based observations. Two parameters related to the heat output from the Central Volcanic Region are of particular interest. Firstly, the average heat flow for the eastern half of the Central Volcanic Region is about 800 mW/m²—in order to maintain this heat flow over geological time periods an efficient mass-transfer of heat is required. Secondly, the observed asymmetry in the pattern of heat output, coupled with the tectonic erosion of blocks of continental crust from the eastern axial ranges into the Central Volcanic Region, suggests that the process currently in progress at the eastern margin of the Region is asymmetric spreading with concomitant thermal differentiation of continental crust into its silicic and basic components.     

Textural trend analysis of coastal barrier sediments along the Middle Atlantic Bight,North Carolina

Comparative polynomial trend analyses of textural parameters were conducted on adjacent foreshore, berm, and dune sediment populations along a coastal barrier chain of the Middle Atlantic Bight. The analyses indicate that systematic textural patterns exhibited by the barrier sediments consist of both regional trends and local cyclicity.The regional trends appear to reflect progressive variability of both the hydraulic and aeolian regimes. Variability of the hydraulic regime consists of a progressive southward increase in average wave energy, with a concomitant decrease in energy consistency; this is attributed to the coastal wave refraction pattern, and to a progressive southward decrease in shelf width. The aeolian regime is characterized by a constant average energy level along the barrier chain, but exhibits a progressive northward decrease in wind energy consistency, and a corresponding increase in winnowing efficiency. Local cyclicity along the barrier appears to reflect textural variations in the barrier source materials excavated from a heterogeneous Pleistocene substrate. The cyclic patterns suggest the presence of a buried ancestral Albemarle fluvial channel near the present mouth of Albemarle Sound.In developing systematic textural variations along the barrier, size characteristics of the source material appear to be the most influential factor, while the influences of both the hydraulic and aeolian regimes are subordinate. The berm and dune field environments are most amenable to the development of systematic variation, while the foreshore is most susceptible to random component variation.     

Modeling the earth's climate

Mathematical models of the earth's climate provide intriguing opportunities to study a wide range of interdisciplinary problems involving processes within the climate system in a controlled and systematic manner. This paper is intended as a nontechnical review of climate modeling to enable researchers who are unfamiliar with the topic to better evaluate and judge the credibility of the model results. The types of climate models available for climate research are reviewed here, and four broad categories of climate models are identified. These range from the more simple energy balance models (EBMs) and radiative-convective models (RCMs), to the more complex statistical-dynamical models (SDMs), to the most powerful tools yet available for studying climate, the general circulation models (GCMs). This last category includes gridpoint and spectral GCMs. Four representations of the oceans which can be coupled to GCMs are described and include prescribed sea surface temperatures, an energy balance or swamp ocean, a mixed layer or slab ocean, or a fully computed ocean general circulation model. Selected examples considered representative of the types of studies possible with the various classes of models are given. Taken together, the spectrum of climate models provides a hierarchy of learning and research tools with which to effectively study the extremes of past climates, the vagaries of present-day climate, and possible climatic fluctuations well into the future.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Two New Carbonate Stable-Isotope Standards

Two new carbonate isotope standards have been prepared for distribution by the IAEA and NBS. The first, TS limestone, NBS #19, will substitute for PDB, while the second carbonate, NBS #18 is depleted in ¹⁸O and ¹³C compared to the first.     

The effects of alongshore variation in bottom topography on a boundary current—(topographically induced upwelling)

A theory which describes the constant f-plane flow of a steady inviscid baroclinic boundary current over a continental margin with a bathymetry that varies slowly in the alongshore but rapidly in the offshore directions is developed in the parameter regime (L_D/L)² ≤ Ro 1, where L_D is the internal deformation radius, L the horizontal length scale, and Ro the Rossby number. To lowest order in the Rossby number the flow is along isobaths with speed q_o = V_u(h,z)|Vh|/α, where V_u(h,z) is the upstream speed, α the upstream bottom slope at depth h, and Vh the bottom slope downstream at depth h. The lowest order flow produces a variation in the vertical component of relative vorticity along the isobath as the magnitude and direction of Vh vary in the downstream direction. The variation of vorticity requires a vertical as well as a cross-isobath flow at first order in the Rossby number. The first order vertical velocity is computed from the vorticity equation in terms of upstream conditions and downstream variations of the bathymetry. The density, pressure, and cross-isobath flow at first order in the Rossby number are then calculated. It is shown that in the cyclonic region of current (d/dh(V_u/α) > 0), if the isobaths diverge in the downstream direction ((∂/∂s)|Vh| < 0), then upwelling and onshore flow occur. The theory is applied to the northeastern Florida shelf to explain bottom temperature observations.     

Trace-element and isotopic constraints on the source of magmas in the active volcano and Mariana island arcs, Western Pacific

Analytical results of the relative and absolute abundance of LIL-incompatible trace elements (K, Rb, Cs, Sr, and Ba) and isotopic compositions ( , , and ) are summarized for fresh samples from active and dormant volcanoes of the Volcano and Mariana island arcs. The presence of thickened oceanic crust (T 15–20 km) beneath the arc indicates that while hybridization processes resulting in the modification of primitive magmas by anatectic mixing at shallow crustal levels cannot be neglected, the extent and effects of these processes on this arc's magmas are minimized. All components of the subducted plate disappear at the trench. This observation is used to reconstruct the composition of the crust in the Wadati-Benioff zone by estimating proportions of various lithologies in the crust of the subducted plate coupled with analyses from DSDP sites. Over 90% of the mass of the subducted crust consists of basaltic Layers II and III. Sediments and seamounts, containing the bulk of the incompatible elements, make up the rest. Bulk Western Pacific seafloor has , δ ¹⁸O +7.2, K/Rb 510, K/Ba 46, and K/Cs 13,500. Consideration of trace-element data and combined systematics limits the participation of sediments in magmagenesis to less than 1%, in accord with the earlier results of Pb-isotopic studies. Combined data indicate little, if any, involvement of altered basaltic seafloor in magmagenesis. Perhaps more important than mean isotopic and LIL-element ratios is the restricted range for lavas from along over 1000 km of this arc. Mixtures of mantle with either the subducted crust or derivative fluids should result in strong heterogeneities in the sources of individual volcanoes along the arc. Such heterogeneities would be due to: (1) gross variations of crustal materials supplied to the subduction zone; and (2) lesser efficiency of mixing processes accompanying induced convection between arc segments (parallel to the arc) as compared to that perpendicular to the arc. The absence of these heterogeneities indicates that either some process exists for the efficient mixing of mantle and subducted material parallel to the arc or that subducted materials play a negligible role in the generation of Mariana-Volcano arc melts.Consideration of plausible sources in the mantle indicates that (1) an unmodified MORB-like mantle cannot have generated the observed trace-element and isotopic composition of this arc's magmas, while (2) a mantle similar to that which has produced alkali-olivine basalts (AOB) of north Pacific “hot spot” chains is indistinguishable in many respects spects from the source of these arc lavas.     

Detrital zircon provenance evidence for an early Permian longitudinal river flowing into the Midland Basin of west Texas

ABSTRACT

Collision of Gondwana and Laurentia in the late Palaeozoic created new topography, drainages, and foreland basin systems that controlled sediment dispersal patterns on southern Laurentia. We utilize sedimentological and detrital zircon data from early Permian (Cisuralian/Leonardian) submarine-fan deposits in the Midland Basin of west Texas to reconstruct sediment dispersal pathways and palaeogeography. New sedimentological data and wire-line log correlation suggest a portion of the early Permian deposits have a southern entry point. A total of 3259 detrital zircon U-Pb and 357 εHf data from 12 samples show prominent groups of zircon grains derived from the Appalachian (500–270 Ma) and Grenville (1250–950 Ma) provinces in eastern Laurentia and the peri-Gondwana terranes (800–500 Ma) incorporated in the Alleghanian-Ouachita-Marathon orogen. Other common zircon groups of Mesoproterozoic-Archaean age are also present in the samples. The detrital zircon data suggest throughout the early Permian, Appalachia and Gondwana detritus was delivered by a longitudinal river system that flowed along the Appalachian-Ouachita-Marathon foreland into the Midland Basin. Tributary channels draining the uplifted Ouachita-Marathon hinterland brought Gondwana detritus into the longitudinal river with headwaters in the Appalachians or farther northeast. This drainage extended downstream westward and delivered sediments into the Permian Basin near the west terminus of the Laurentia-Gondwana suture. Estimated rates of deposition and proportions of zircons from more local (Grenville) versus more distal (Pan-African) sources indicate that river strength decreased throughout early Permian time. Primary sediment delivery pathway was augmented by minor input from the Ancestral Rocky Mountains and wind deflation of fluvial sediments north and east of the basin. Slope failure associated with early Permian deposition in the southeastern margin of the Midland Basin triggered gravity flows leading to submarine fan deposition.