Geochemical and cosmochemical cycles involving sulfur,sulfide, sulfite and sulfate

Raman spectra of aqueous systems containing sulfur dioxide, elemental sulfur and sulfate indicate that the equilibrium between these species is catalyzed by elemental sulfur. Therefore, dynamic equilibrium can be expected under conditions prevalent on Venus, on Io and in epigenic sulfur deposits.     

The geography of mineral supply: The mainsprings of future uncertainties

This paper suggests that the major uncertainties overhanging the future geography of mineral supply in the non-Communist world derive from intellectual rather than resource inadequacies. In particular, the paucity of medium-term, macro-economic forecasts of growth in the economies of the OECD seriously undermine the value of mineral-demand forecasts. At the same time, the altered investment climate for mineral exploration and development will have a substantial impact upon mineral supplies, but its magnitude and geography remain a matter for dispute. And, third, the future pattern of mineral trade, shaped by the shifting geography of mineral-processing activities and metal manufacture, continues to elude convincing analysis.     

Evaluation of cold-water carbonates as a possible paleoclimatic indicator

The common belief currently shared by many geoscientists concerning the climatic interpretation of limestones is that a warm-water environment is essential. This concept is not necessarily true because the rate and extent of terrigenous sediment dilution, rather than water temperature, is the primary factor determining whether or not a limestone forms at nearshore or continental shelf depths. Because carbonate productivity is lowest in cold climates, however, CaCO₃ abundance and the thickness of carbonate accumulations tend to be least at high latitudes. In this regard present-day continental shelves and beaches offer a poor model for comparing cold-water and warm-water carbonates because of the generally emergent continental tectonic framework, recent eustatic sea-level changes, and the presence of ice caps at the modern poles.Typically, the influence of climate on non-reef continental shelf and beach environments cannot be clearly distinguished by the presence or absence of major taxonomic groups. Faunal diversity and equitability are more sensitive in this regard. The absence of shelf-depth inorganic carbonate precipitates, micrite envelopes, and peloids may also point to the cold-water origin of a rock. Skeletal mineralogy and oxygen isotopes of certain unrecrystallized carbonates may be good paleoclimatic indicators; however, trace elements and physical-textural attributes of the carbonate fraction are probably temperature insensitive.Previous studies of high-latitude continental shelves have concentrated merely on the abundance of calcareous material and there is seemingly a disproportionate amount of information with respect to low-latitude carbonate studies. Further research on cold-water carbonates may open up new avenues for alternative paleoenvironmental and paleoclimatic interpretations.     

Gefüge und Entstehung der Ringdünen in den grauen Tuffen des Laacher Vulkans

The last products of the pleistocene Laach volcano (Eifel, about 40 kms SW of Bonn, Germany) are grey tuffs. Outcrops in the rim show characteristic cross-bedding in these tuffs. It is in discussion whether these structures are produced by wind or by phreato-magmatic outbursts. At all larger outcrops in the rim we measured numerous depositional elements of the tuffs, and analyzed their geometrical structure. So we are able to reconstruct shape, structure and orientation of dunes in the tuffs. They show transport vectors in centrifugal orientation, radially to the vent. The dunes are orientated concentrically to the vent, we intruduce the term “concentrical dune” for this dune type. This points out that the dunes in the Laach tuffs are of volcanic origin. But our geometrical results give no authorization to assume phreato-magmatic processes during the activity of the Laach volcano. We think that the grey Laach tuffs are no base surge deposits, but products of gas-rich eruptions in the phase of decreasing volcanic energy.     

Evaporation of perennial semi‐arid woodland in southeastern Australia is adapted for irregular but common dry periods

Measurements of water vapour flux from semi‐arid perennial woodland (mallee) were made for 3 years using eddy covariance instrumentation. There have been no previous long‐term, detailed measures of water use in this ecosystem. Latent energy flux (LE) on a half hourly basis was the measure of the combined soil and plant evaporation, ‘evapotranspiration’ (E_LE) of the site. Aggregation over 3 years of the site measured rain (1136 mm) and the estimated evaporation (794 mm) suggests that 342 mm or 30% of rain had moved into or past the root zone of the vegetation. Above average rainfall during 2011 and the first quarter of 2012 (633 mm, 15 months) would likely have been the period during which significant groundwater recharge occurred. At times immediately after rainfall, E_LE rates were the same or exceeded estimates of potential E calculated from a suitably parameterized Penman–Monteith (E_PMo) equation. Apparent free water E from plant interception and soil evaporation was about 2.3 mm and lasted for 1.3 days following rainfall in summer, while in autumn, E was 5.1 mm that lasted over 5.4 days. The leaf area index (LAI) needed to adjust a wind function calibrated Penman equation (E_PMe) to match the E_LE values could be back calculated to generate seasonal change in LAI from 0.12 to 0.46 and compared well with normalized difference vegetation index; r = 0.38 and p = 0.0213* and LAI calculated from digital cover photography. The apparently conservative response of perennial vegetation evaporation to available water in these semi‐arid environments reinforces the conclusion that these ecosystems use this mechanism to survive the reasonably common dry periods. Plant response to soil water availability is primarily through gradual changes in leaf area. Copyright © 2015 John Wiley & Sons, Ltd.     

First evidence for large earthquakes on the Deshir Fault,Central Iran Plateau

Although sliced by several strike slip faults, a large part of Central Iran remained aseismic during the period of time covered by the instrumental and historical seismic records. Stating the existence of earthquakes in the Holocene is therefore important for the assessment of the regional seismic hazard. A palaeoseismic study of the Deshir fault demonstrates that Central Iran hosted large earthquakes during latest Pleistocene and Holocene. The last event corresponds to 1 m‐deep fissures, which sandy infilling yielded an optically stimulated luminescence (OSL) age of 2.8 ± 1.4 ka. At least two previous events, outlined by older fissures and/or colluvial wedges, have been recorded over the last 10–30 ka. The magnitudes are difficult to assess because the actual slips per event are unknown. The size of the fissures and the significant vertical displacement associated with a colluvial wedge are nevertheless compatible with M ≈ 7 events along a primary strike‐slip surface break.     

Variations in 24-μm morphologies among galaxies in the Spitzer Infrared Nearby Galaxies Survey: new insights into the Hubble sequence

To study the distribution of star formation and dust emission within nearby galaxies, we measured five morphological parameters in the 3.6- and 24-μm wavebands for 65 galaxies in the Spitzer Infrared Nearby Galaxies Survey (SINGS) and eight galaxies that were serendipitously observed by SINGS. The morphological parameters demonstrate strong variations along the Hubble sequence, including statistically significant differences between S0/a-Sab and Sc-Sd galaxies. Early-type galaxies are generally found to be compact, centralized, symmetric sources in the 24-μm band, while late-type galaxies are generally found to be extended, asymmetric sources. These results suggest that the processes that increase the real or apparent sizes of galaxies' bulges also lead to more centralized 24-μm dust emission. Several phenomena, such as strong nuclear star formation, Seyfert activity, or outer ring structures, may cause galaxies to deviate from the general morphological trends observed at 24 μm. We also note that the 24-μm morphologies of Sdm-Im galaxies are quite varied, with some objects appearing very compact and symmetric but others appearing diffuse and asymmetric. These variations reflect the wide variation in star formation in irregular galaxies as observed at other wavelengths. The variations in the 24-μm morphological parameters across the Hubble sequence mirror many of the morphological trends seen in other tracers of the ISM and in stellar emission. However, the 24-μm morphological parameters for the galaxies in this sample do not match the morphological parameters measured in the stellar wavebands. This implies that the distribution of dust emission is related to but not equivalent to the distribution of stellar emission.