Radio planetary nebulae in the Magellanic Clouds

We report the extragalactic radio-continuum detection of 15 planetary nebulae (PNe) in the Magellanic Clouds (MCs) from recent Australia Telescope Compact Array+Parkes mosaic surveys. These detections were supplemented by new and high-resolution radio, optical and infrared observations which helped to resolve the true nature of the objects. Four of the PNe are located in the Small Magellanic Cloud (SMC) and 11 are located in the Large Magellanic Cloud (LMC). Based on Galactic PNe the expected radio flux densities at the distance of the LMC/SMC are up to ∼2.5 and ∼2.0 mJy at 1.4 GHz, respectively. We find that one of our new radio PNe in the SMC has a flux density of 5.1 mJy at 1.4 GHz, several times higher than expected. We suggest that the most luminous radio PN in the SMC (N S68) may represent the upper limit to radio-peak luminosity because it is approximately three times more luminous than NGC 7027, the most luminous known Galactic PN. We note that the optical diameters of these 15 Magellanic Clouds (MCs) PNe vary from very small (∼0.08 pc or 0.32 arcsec; SMP L47) to very large (∼1 pc or 4 arcsec; SMP L83). Their flux densities peak at different frequencies, suggesting that they may be in different stages of evolution. We briefly discuss mechanisms that may explain their unusually high radio-continuum flux densities. We argue that these detections may help solve the 'missing mass problem' in PNe whose central stars were originally  1–8 M_⊙  . We explore the possible link between ionized haloes ejected by the central stars in their late evolution and extended radio emission. Because of their higher than expected flux densities, we tentatively call this PNe (sub)sample –'Super PNe'.     

Li-bearing, disordered Mg-rich tourmaline from a pegmatite-marble contact in the Austroalpine basement units (Styria, Austria)

Pale-blue to pale-green tourmalines from the contact zone of Permian pegmatites to mica schists and marbles from different localities of the Austroalpine basement units (Rappold Complex) in Styria, Austria, are characterized. All these Mg-rich tourmalines have small but significant Li contents, up to 0.29 wt% Li₂O, and can be characterized as dravite, with FeO contents of ?~?0.9–2.7 wt%. Their chemical composition varies from ^X (Na_0.67Ca_0.19?K_0.02?_0.12) ^Y (Mg_1.26Al_0.97Fe²⁺ _0.36Li_0.19Ti⁴⁺ _0.06Zn_0.01?_0.15) ^Z (Al_5.31?Mg_0.69) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.66(OH)_0.34], with a?=?15.9220(3), c?=?7.1732(2) Å to ^X (Na_0.67Ca_0.24?K_0.02?_0.07) ^Y (Mg_1.83Al_0.88Fe²⁺ _0.20Li_0.08Zn_0.01Ti⁴⁺ _0.01?_0.09) ^Z (Al_5.25?Mg_0.75) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.87(OH)_0.13], with a?=?15.9354(4), c?=?7.1934(4) Å, and they show a significant Al-Mg disorder between the Y and the Z sites (R1?=?0.013–0.015). There is a positive correlation between the Ca content and?<?Y-O?>?distance for all investigated tourmalines (r?≈?1.00), which may reflect short-range order configurations including Ca and Fe²⁺, Mg, and Li. The tourmalines have X_Mg (X_Mg?=?Mg/Mg?+?Fe_total) values in the range 0.84–0.95. The REE patterns show more or less pronounced negative Eu and positive Yb anomalies. In comparison to tourmalines from highly-evolved pegmatites, the tourmaline samples from the border zone of the pegmatites of the Rappold Complex contain relatively low amounts of total REE (~8–36 ppm) and Th (0.1–1.8 ppm) and have low La_N/Yb_N ratios. There is a positive correlation (r?≈?0.91) between MgO of the tourmalines and the MgO contents of the surrounding mica schists. We conclude that the pegmatites formed by anatectic melting of mica schists and paragneisses in Permian time. The tourmalines crystallized from the pegmatitic melt, influenced by the metacarbonate and metapelitic host rocks.     

10Be and 26Al exposure‐age dating of bedrock surfaces on the Aran ridge,Wales: evidence for a thick Welsh Ice Cap at the Last Glacial Maximum

This paper presents results of the analysis of paired cosmogenic isotopes (¹⁰Be and ²⁶Al) from eight quartz‐rich samples collected from ice‐moulded bedrock on the Aran ridge, the highest land in the British Isles south of Snowdon. On the Aran ridge, comprising the summits of Aran Fawddwy (905 m a.s.l.) and Aran Benllyn (885 m a.s.l.), ²⁶Al and ¹⁰Be ages indicate complete ice coverage and glacial erosion at the global Last Glacial Maximum (LGM). Six samples from the summit ridge above 750–800 m a.s.l. yielded paired ¹⁰Be and ²⁶Al ages ranging from 17.2 to 34.4 ka, respectively. Four of these samples are very close in age (¹⁰Be ages of 17.5 ± 0.6, 17.5 ± 0.7, 19.7 ± 0.8 and 20.0 ± 0.7 ka) and are interpreted as representing the exposure age of the summit ridge. Two other summit samples are much older (¹⁰Be ages of 27.5 ± 1.0 and 33.9 ± 1.2 ka) and these results may indicate nuclide inheritance. The ²⁶Al/¹⁰Be ratios for all samples are indistinguishable within one‐sigma uncertainty from the production rate ratio line, indicating that there is no evidence for a complex exposure history. These results indicate that the last Welsh Ice Cap was thick enough to completely cover the Aran ridge and achieve glacial erosion at the LGM. However, between c. 20 and 17 ka ridge summits were exposed as nunataks at a time when glacial erosion at lower elevations (below 750–800 m a.s.l.) was achieved by large outlet glaciers in the valleys surrounding the mountains. Copyright © 2011 John Wiley & Sons, Ltd.     

M and Mg values in igneous rocks: proposed usage and a comment on currently employed Fe2O3 corrections

It is proposed that the ‘M value’ of an igneous rock should be 100Mg/(Mg + ΣFe) and that the ‘Mg value’ should be 100Mg/(Mg + Fe²⁺). A plea is made to standardize any necessary corrections for Fe₂O₃ so that $\text{Fe}{}_2\text{O}{}_3\text{(Fe}{}_2\text{O}{}_3\text{+ FeO)}\text{= 02}$ for basic rocks.     

Metal ion complex formation constants of some sedimentary humic acids with Zn(II), Cu(II) and Cd(II)

Metal ion complex formation constants were determined for several sedimentary humic acids (SHA) derived from a fresh water lake and several coastal marine environments, using a method based on size exclusion chromatography. Only one type of binding site was observed in all cases, and conditional log K_f values of between 5 and 7 (at pH 8, I = 0.01 M) were found. Elemental composition of the SHA was similar to soil HA, except that nitrogen content was significantly higher in the SHA. Other chemical properties of the SHA were consistent with those reported by other workers. While spectroscopic measurements indicated that the SHA may have contained significant amounts of polysaccharide compounds which were not removed by conventional separation and purification procedures, analysis indicated only very low levels of polysaccharides were present in the SHA.     

Floodplain inundation: Processes and relationships with channel discharge

The factors affecting the relationship between channel discharge and volume of inundation are discussed. For many floodplains this relationship is not simple, but involves hysteretic effects which vary according to the hydrological characteristics of individual floods and the way in which these interact with the surface form of the floodplain reach. Some methods of deriving or estimating the extent of the hysteresis on floodplain reaches are suggested, although an acute lack of available data prevents detailed examination at present. Further investigations are required before floodplain conductivity relations can be used as an aid to flood routing procedures or in floodplain management problems. A major priority must be the acquisition of sequential inundation data.