Factors affecting sulfur incorporation into lake sediments: paleoecological implications

This paper discusses the use of S as a paleolimnological tracer of limnetic sulfate concentration. A positive relationship (p<0.05) was found between limnetic sulfate and sediment S concentrations for the Great Lakes, English Lakes, and lakes from the Adirondack and Northern New England regions. There is a positive correlation (p<0.05) between C and S concentration in sediment across all regions studied. The importance of C in affecting S content in sediment was also examined by a series of cores taken at different water depths in Big Moose Lake (Adirondacks). There was a strong relationship between C and S among cores with sediment from deeper water having higher C and S concentrations (r ²=0.99). Sulfur from the shallower cores had greater concentrations of chromium-reducible S (pyrite), while cores from deeper waters had a greater proportion of organic S fractions including C-bonded S and ester sulfates.For assessing historical changes in S accumulation in sediments, enrichment factors were calculated for the PIRLA lakes. Pre-1900 net sediment accumulation rates of S were very similar across all regions. Sulfur enrichment was greatest in Adirondack sediment which had total post-1900 S accumulation of 1.1 to 7.4 times pre-1900 S accumulation. Sediment from Northern New England (NNE) generally had lower S concentration than Adirondack sediments and S enrichment factors ranged from 1.2 to 2.1. Sediment from the Northern Great Lakes States region had similar S concentration and distribution with depth to NNE sediment. In two Northern Florida lakes, sediment showed little variation in S concentration with depth, but in two other lakes from the same region, there was higher S concentration in deeper layers. Lakes which had the greatest enrichment factors also exhibited the most marked changes in C:S ratios. Ratios of C:N showed little variation (10.6 to 26.1) among the PIRLA lakes. A first order model indicated slow decomposition within these organic rich sediments.Elemental concentrations and ratios of sediment from a variety of lakes and reservoirs were complied. Maximum and minimum elemental ratios for all the data were 28 to 8.1 for C:N, 0.81 to 0.11 for C:H, and 675 to 12.5 for C:S, respectively. For the C:S ratios in all regions except the Great Lakes, the maximum ratio was less than 231. Both the maximum and minimum amount of N and H concentration of organic matter is related to biotic processes. The minimum concentration of S is regulated not only by nutrient demands but also by non-assimilatory processes.Sulfur incorporation into sediments is a function of a complex of factors, but limnetic sulfate concentration and organic matter content play a major role in regulating the S content of sediment. Further quantification of S incorporation pathways will aid in the paleolimnological interpretation of sediment S profiles. Such information is also important in assessing how S sediment pools will respond to decreases in limnetic sulfate concentration which may occur with decreases in inputs from acidic deposition.This is the eighth of a series of papers to be published by this journal which is a contribution to the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D.F. Charles and D.R. Whitehead are guest editors for this series.     

Erosion response to anthropogenic activity and climatic changes during the Holocene: case studies in northwestern China and southern Norway

Soil erosion assessment and prediction play critical roles in addressing problems associated with erosion control or soil conservation. The past dynamics of soil erosion can provide valuable information for us to understand the relations of soil erosion to environmental change and anthropogenic activity. The present paper has compared Holocene climatic changes in northwestern China with those in southern Norway, and investigated the past dynamics of erosion activity during the Holocene. Modern soil erosion on the Loess Plateau is a combination of the intensive natural erosion and human-induced erosion, the latter being four times greater than the former. Because of global warming and increasing human activities, climate on the Loess Plateau is becoming dryer and more unstable, causing an enhanced erosion problem and water scarcity. In the arctic-alpine region of southern Norway, however, the global warming and regional wetting caused expansion of the largest European ice cap. This has accentuated the erosion in that region, with a higher frequency of avalanches and debris flows.     

Engineering geology in underground aggregate mining and space utilisation

As consumption of construction aggregates increased in the Toronto (Canada) area and as regular source areas faced constraints, attention was given to the possibility of underground mining of limestone aggregate. Following a study of transportation costs and the drilling of several, continuously cored drill holes through the Paleozoic strata, Ontario Hydro and three Ontario government ministries undertook a feasibility study of the mining of limestone aggregate in the Toronto area.

The geological study showed the suitability of the Ordovician Gull River Formation as a source rock for the aggregate and the structural conditions suitable for mining operations.

A mining operation to produce 3–5 million tonnes/year over 16–30 years was investigated. This involved a decline or a shaft (depending on location) down to a mechanized room and pillar operation (square or rectangular grid) at depths between 200–500 m. Pillar stresses were calculated at less than 40 Mpa — well below the 100 Mpa unconfined compressive strength of the limestone. Operations would be mostly in dry conditions because of the presence of high horizontal stresses.     

An empirical sapphirine-spinel Mg---Fe exchange thermometer and its application to high grade xenoliths in the Popes Harbour dyke, Nova Scotia, Canada

Spinel-sapphirine-corundum-rutile parageneses in metapelitic xenoliths from the lamprophyric Popes Harbour dyke are enclosed by feldspathic (±rare quartz) haloes that embay aluminosilicates and biotite. These feldspathic haloes contain plagioclase (An_20–40) and/or an alkali or ternary (hypersolvus) feldspar, and show a variety of igneous and devitrification textures, suggesting an anatectic origin. The spinel-bearing parageneses are interpreted as the refractory residue formed by the incongruent melting of biotite, aluminosilicates and associated phases.

Equilibration temperatures of these assemblages are estimated from an empirical sapphirine-spinel Mg---Fe exchange thermometer derived from literature data on both silica-saturated and undersaturated sapphirine granulites. Linear regression (R=0.81) of the calibrant data yields the expression T(°C) = [800 + (228^*InKd)] − 273 where

Kd=(X^sp_Fe/X^sp_Mg)/(X^sa_Fe/X^sa_Mg)

Precision is estimated at ± 100°C, but will likely be less for highly oxidized sapphirine granulites owing to (1) errors in the stoichiometric estimation of X_Fe³⁺ from microprobe data and (2) the formation of magnetite at the expense of spinel or sapphirine, leading to an increase in X_Mg in either or both phases during cooling. Application of this expression to the reduced (graphite-bearing) Popes Harbour xenoliths yields T of 725–795°C. Anatexis is attributed to thermal metamorphism by the lamprophyric magma prior to and/or during entrainment of xenolith material in the dyke. Higher-T assemblages were quenched before the xenoliths attained thermal equilibrium with the magma, consequently prograde reaction textures and compositional zoning patterns are preserved.     

An experimental study of the isotopic enrichment in Ar, Kr, and Xe when trapped in water ice

The isotopic enrichment of argon, krypton, and xenon, when trapped in water ice, was studied experimentally. The isotopes were found to be enriched according to their (m1/m2)1/2 ratio. These enrichment factors could be useful for comparison among the uncertain cosmic or solar isotopic ratios, the hopeful in situ cometary ratio, and those in Earth's atmosphere, in the context of cometary delivery of volatiles to Earth.     

Magma mixing in granitic rocks of the central Sierra Nevada,California

The El Capitan alaskite exposed in the North American Wall, Yosemite National Park, was intruded by two sets of mafic dikes that interacted thermally and chemically with the host alaskite. Comparisons of petrographic and compositional data for these dikes and alaskite with published data for Sierra Nevada plutons lead us to suggest that mafic magmas were important in the generation of the Sierra Nevada batholith. Specifically, we conclude that: (1) intrusion of mafic magmas in the lower crust caused partial melting and generation of alaskite (rhyolitic) magmas; (2) interaction between the mafic and felsic magmas lead to the observed linear variation diagrams for major elements; (3) most mafic inclusions in Sierra Nevada plutons represent chilled pillows of mafic magmas, related by fractional crystallization and granitoid assimilation, that dissolve into their felsic host and contaminate it to intermediate (granodioritic) compositions; (4) vesiculation of hydrous mafic magma upon chilling may allow buoyant mafic inclusions and their disaggregation products to collect beneath a pluton's domed ceiling causing the zoning (mafic margins-to-felsic core) that these plutons exhibit.     

Assessing the adequacy of North American agricultural land resources

This paper provides a prospective analysis of supply/demand conditions for agricultural land in Canada and the U.S.A. according to various growth scenarios and an assessment of the economic and environmental costs associated with expanding and intensifying the cropland base. Future cropland expansion is estimated on the basis of the interrelationship between growth in demand and the productivity of cereal output. The adequacy of the land resource base is assessed by comparing individual projections with expected reserves of cropland adjusted for non-agricultural demands for land. Within the context of these findings the paper proceeds with a general discussion of the man-made, resource and environmental constraints to expanding production and the resulting economic and environmental costs to society.     

SrCa and MgCa ratios in polygenetic carbonate allochems from a Michigan marl lake

Rapid accumulation of CaCO₃ is occurring in Littlefield Lake, a marl lake located in central Michigan. The sediment, which is 95% CaCO₃, primarily consists of eight different genetic groups of carbonate allochems. These include calcite muds, sands, algal oncoids and Chara encrustations, as well as the dominant aragonitic gastropods Valvota tricarinota. Gyraulus deflectus and Amnicola integra. and the dominant aragonitic pelecypod Sphaerium partumeium. Samples of each of these groups were analyzed for Ca, Sr and Mg. Molar $\text{Mg}\text{Ca}$ ratios are primarily controlled by allochem mineralogy, with calcitic forms having $\text{Mg}\text{Ca}$ ratios 5–10 times larger than aragonitic (shelled) forms. The $\text{Sr}\text{Ca}$ ratios are primarily controlled by biochemical fractionation, and are significantly lower than $\text{Sr}\text{Ca}$ ratios of inorganically precipitated aragonite from other settings. Partition coefficients were determined for both Sr and Mg for each carbonate allochem group and, based on comparisons with results reported by other workers, the partition coefficients determined here are generally considered ‘typical’ or representative values for biogeneous freshwater carbonates. An analysis of variance of the data indicates that most genera and species of carbonate-secreting organisms in marl lakes have highly characteristic $\text{Sr}\text{Ca}$ and $\text{Mg}\text{Ca}$ ratios. These ratios can potentially serve as geochemical tracers in future investigations of lacustrine carbonate diagenesis. Both Sr and Mg are influenced by grain size and/or surface area, probably due to the presence of these elements in non-lattice-held (exchangeable) positions.     

Q'gas: a minicomputer-based system to aid in the interpretation of exploration-oriented geochemical data

The past few years have seen an increasing application of computer-based procedures in the processing and interpretation of geochemical data. In many cases this has been carried out by non-geologists using large, general purpose computers remote from the exploration effort. In such situations, appreciation of the geological nature of the problems is often inadequate and in a number of cases misapplication of procedures has resulted. The present paper describes the Q'GAS system which consists of a minicomputer and a series of compatible interactive programs. These programs can be used independently by geologists who have a minimum of experience with computers allowing them the opportunity to carry out personally the processing and interpretation of geochemical data and to ensure that the methodology is based on a firm geological framework. The expense of such a system is relatively low: approximately $25,000 capital costs, and $3500 per year running costs including a maintenance contract. In addition approximately one man-month per year is required for supervision and up-keep.The system has the capability of: (a) selecting subgroups of samples that meet specified criteria (e.g. specific rock type or value ranges); (b) transforming data (addition, subtraction, multiplication, division, logarithms, exponentiation and random number generation); (c) making statistical computations; and (d) producing graphical displays (e.g. histograms, X-Y plots, symbol maps etc.). Flexible diskettes are used for data storage and communication with the system is achieved through a video terminal. Hard-copy output is produced on a small printer. The system presently includes programs for data management, univariate statistics with histograms, correlation analysis, X-Y plots, line printer symbol maps, line printer geochemical profiles, multiple linear regression, discriminant analysis, and R-mode factor analysis. Attention is presently being given to developing programs that use a pen plotter for producing better quality maps and diagrams at any scale.Experience has shown that the simpler programs for construction of maps, graphs, and diagrams can provide an immediate improvement in the quality, thoroughness, and speed of data interpretation as well as significantly reducing the tedium associated with manual methods. The multivariate statistical techniques, as always, require a higher level of expertise and many more man hours if they are to be used successfully.