On the pair-instability supernovae and gamma-ray burst phenomenon

We present a model of a gamma-ray burst (GRB) related to “very massive” stars. In the framework of our model, the GRB phenomenon is a result of helium burning in degenerate conditions in a massive star (≳130 M _⊙), in which the thermal nuclear burning occurs in the deflagration regime and has a pulsating temporal pattern. The shock runs away from the burning (reaction) zone, which leads to the development of a coronal outflow (jet-like) structure. In our scenario the GRB observable prompt fast rise and decay part can be a result of photon propagation through the hot corona (Comptonization photosphere) of the star. On the other hand, the GRB afterglow is a cooling phase of the expanding and outflowing envelope. Presumably, the X-ray part of the GRB emergent spectrum is formed due to upscattering of soft photons of outer layers of the star off hot coronal electrons, and thus it should have a specific shape of the Comptonization spectrum.     

Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).     

Thick sections of layered ultramafic cumulates in the Oman ophiolite revealed by an airborne hyperspectral survey: Petrogenesis and relationship to mantle diapirism

Using the HyMap instrument, we have acquired visible and near infrared hyperspectral data over the Maqsad area of the Oman ophiolite (~ 15 × 60 km). This survey allowed us to identify and map the distribution of clinopyroxene-rich cumulates (inter-layered clinopyroxenites and wehrlites) whose occurrence was previously undocumented in this area. The cumulates reach several hundred meters in thickness and crop out at distances exceeding 15 km on both sides of the Maqsad former spreading centre. They occur either in mantle harzburgites, as km-sized layered intrusions surrounded by fields of pegmatitic dykes consisting of orthopyroxene-rich pyroxenite and gabbronorites, or at the base of the crustal section where they are conformably overlain by cumulate gabbros. These ultramafic cumulates crystallized from silica- and Mg-rich melts derived from a refractory mantle source (e.g. high Cr#, low [Al₂O₃], low [TiO₂]). These melts are close to high-Ca boninites, although, strictly speaking, not perfect equivalents of present-day, supra-subduction zone, boninites. Chemical stratigraphy reveals cycles of replenishment, mixing and fractional crystallization from primitive (high Mg#) melts, typical of open magma chambers and migration of inter-cumulus melts. The TiO₂ content of clinopyroxene is always low (≤ 0.2 wt.%) but quite variable compared to the associated pegmatites that are all derived from a source ultra-depleted in high field strength elements (HFSE). This variability is not caused by fractional crystallization alone, and is best explained by hybridization between the ultra-depleted melts (parent melts of the pegmatites) and the less depleted mid-ocean ridge basalts (MORB) parent of the dunitic–troctolitic–gabbroic cumulates making up the crustal section above the Maqsad diapir.We propose that, following a period of magma-starved spreading, the Maqsad mantle diapir, impregnated with tholeiitic melts of MORB affinity, reached shallow depths beneath the ocean ridge. This diapir induced melting of the formerly accreted and hydrothermally altered lithosphere. At this stage, these boninitic-like lithospheric melts crystallized as pegmatitic dykes. As the diapir continued to rise, the amount of MORB reaching shallow depths increased, together with the surrounding temperature, leading to the formation of magma chambers where the crystallization of layered cumulates became possible. These cumulates remained rich in pyroxene and devoid of plagioclase as long as the contribution of MORB-derived melts was moderate relative to the lithospheric-derived melts. As the contribution of MORB to the refilling of the magma chamber increased, gabbroic cumulates started to crystallize.     

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.     

Impacts of Indian Ocean SST biases on the Indian Monsoon: as simulated in a global coupled model

In this study, the impact of the ocean–atmosphere coupling on the atmospheric mean state over the Indian Ocean and the Indian Summer Monsoon (ISM) is examined in the framework of the SINTEX-F2 coupled model through forced and coupled control simulations and several sensitivity coupled experiments. During boreal winter and spring, most of the Indian Ocean biases are common in forced and coupled simulations, suggesting that the errors originate from the atmospheric model, especially a dry islands bias in the Maritime Continent. During boreal summer, the air-sea coupling decreases the ISM rainfall over South India and the monsoon strength to realistic amplitude, but at the expense of important degradations of the rainfall and Sea Surface Temperature (SST) mean states in the Indian Ocean. Strong SST biases of opposite sign are observed over the western (WIO) and eastern (EIO) tropical Indian Ocean. Rainfall amounts over the ocean (land) are systematically higher (lower) in the northern hemisphere and the south equatorial Indian Ocean rainfall band is missing in the control coupled simulation. During boreal fall, positive dipole-like errors emerge in the mean state of the coupled model, with warm and wet (cold and dry) biases in the WIO (EIO), suggesting again a significant impact of the SST errors. The exact contributions and the distinct roles of these SST errors in the seasonal mean atmospheric state of the coupled model have been further assessed with two sensitivity coupled experiments, in which the SST biases are replaced by observed climatology either in the WIO (warm bias) or EIO (cold bias). The correction of the WIO warm bias leads to a global decrease of rainfall in the monsoon region, which confirms that the WIO is an important source of moisture for the ISM. On the other hand, the correction of the EIO cold bias leads to a global improvement of precipitation and circulation mean state during summer and fall. Nevertheless, all these improvements due to SST corrections seem drastically limited by the atmosphere intrinsic biases, including prominently the unimodal oceanic position of the ITCZ (Inter Tropical Convergence Zone) during summer and the enhanced westward wind stress along the equator during fall.     

LA‐ICP‐MS Analysis of Small Samples: Carbonate Reference Materials and Larval Fish Otoliths

This article proposes a methodology to analyse the composition of very small carbonate samples such as larval fish otoliths. The chemical composition of otoliths, which are carbonate structures in the inner ear, is often used to explore population dynamics in fishes. Recent advances in laser ablation‐inductively coupled plasma‐mass spectrometry have suggested its potential application to this field. In this study, analyses were performed using a 193 nm ArF Resonetics LA system, coupled to an Agilent 7700X‐ICP‐MS, with the following ablation parameters: a beam diameter of 5 μm, energy of 3 mJ, 2.7 J cm^?2, laser repetition rate of 10 Hz and translation speed of 2.5 μm s^?1. NIST SRM 610 glass was used as the primary calibration material. Performing this protocol, characterisation of a USGS GP‐4 reference material was achieved with suitable precision and accuracy, but the USGS MACS‐3 reference material appeared more heterogeneous under the ablation conditions tested. Calibration was performed using two different beam diameters (5 and 11 μm). Capelin (Mallotus villosus) otoliths measuring between 10 and 20 μm in diameter were tested. Even though a smaller beam diameter and lower energy were used compared with those normally employed to analyse larger otoliths, the method was successful.     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.     

Mineralogy and geochemical behaviour during weathering of greenstone belt under tropical dry conditions in the extreme North Cameroon (Central Africa)

Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.     

A Comprehensive Framework for Intrinsic OpenStreetMap Quality Analysis

OpenStreetMap (OSM) is one of the most popular examples of a Volunteered Geographic Information (VGI) project. In the past years it has become a serious alternative source for geodata. Since the quality of OSM data can vary strongly, different aspects have been investigated in several scientific studies. In most cases the data is compared with commercial or administrative datasets which, however, are not always accessible due to the lack of availability, contradictory licensing restrictions or high procurement costs. In this investigation a framework containing more than 25 methods and indicators is presented, allowing OSM quality assessments based solely on the data's history. Without the usage of a reference data set, approximate statements on OSM data quality are possible. For this purpose existing methods are taken up, developed further, and integrated into an extensible open source framework. This enables arbitrarily repeatable intrinsic OSM quality analyses for any part of the world.     

Thermochronological evidence for Mio‐Pliocene late orogenic extension in the north‐eastern Albanides (Albania)

New apatite and zircon (U–Th)/He and apatite fission‐track (FT) data allow constraining the timing of Miocene–Pliocene extensional exhumation that affected the central part of the Dinarides‐Albanides‐Hellenides orogen. Apatite (U–Th)/He ages in the northern and western Internal Albanides range from 57 to 17 Ma, contrasting to younger ages of 5.2–9.3 Ma in the eastern Internal Albanides. Eastward younging is also reflected in zircon (U–Th)/He ages varying from 101 Ma in the north‐western Internal Albanides to 19–50 Ma in the east, as well as in recently published apatite FT ages. Thermal history predictions with the new data point to a phase of rapid exhumation of the eastern Internal Albanides around 6–4 Ma, while the western Internal Albanides record slower continuous exhumation since the Eocene. This asymmetric exhumation pattern is most likely linked to extensional reactivation of NE–SW‐trending thrusts east of the Mirdita zone and within the Korabi zone of the eastern Internal Albanides.