Simulation of subcritical flow at open-channel junction

The spectrum of this survey turns on the evaluation of various existing theoretical combining models, when invoked within the internal boundary condition management at a junction. Based on the assumption that: when the Froude number is low (i.e. the flow is subcritical), the energy equation at the junction can be approximated by the stages heads equality. Actual literature and many commercial packages rather use this concept for the treatment of the junction’s internal boundary handling because it is easy to implement and it avoids the solving of nonlinear equations. In the last decade, many nonlinear combining models, based on the momentum conservation through the junction, have been reported. However, using them to operate within the internal boundary condition treatment of an open-channel confluence has not yet been investigated. Hence, this research focuses on studying the practical aspect of several combining models, once applied within the junction’s internal boundary management. Therefore, the recent nonlinear models of Gurram, Hsu and Shabayek have been briefly detailed together with the traditional concept of assuming water stages equality at the junction. Subsequently, an experimental examination was performed according to available experiments as mean to pre-evaluate (separately at the junction) the four junction models in the steady state. Moreover, according to the latter inspection the attention was constrained to study the effect of high/low subcritical Froude number at the junction. Finally, two hypothetical hydraulic problems were defined and computed in order to exhibit the performance of these junction models when used to contend the junction’s internal boundary handling. The problems involved: (a) steady and transient flows; (b) high and low (subcritical) Froude number at the junction. Supported by the experimental and numerical investigations, it can be concluded that even while the Froude number spectrum is subcritical, precautions have to be taken when dealing with the concept of energy heads equality, notably for a Froude higher than 0.35 at the junction.     

On the Mass Balance of Low Latitude Glaciers with Particular Consideration of the Peruvian Cordillera Blanca

Glacier mass balance studies in the low latitudes are rare and glaciological methods and terminology are basically adapted from mid- and high latitude conditions. The low latitudes are considered to be the tropics and, to some extent, the adjoining dry subtropics. The outer tropics are proposed as an intermediate zone with tropical character during the humid season and subtropical character during the dry season. Delimitations as well as respective climate and glacier regimes are discussed in order to distinguish them from each other and from the mid-latitudes. Different sensitivities of the glaciers can be expected and promise, in turn, a complex climatological interpretation of glacier fluctuations. For this, detailed mass balance studies on low latitude glaciers are required. The respective discussion is concentrated on the Peruvian Cordillera Blanca whose topographical setting provides both spatial and temporal subdivisions in humid and dry regimes in one region. However, theoretical considerations and field experience show problems for the determination of mass balance variables in the Cordillera Blanca and the low latitudes in general. The absence of annual temperature variations hinders the development of impermeable layers which can be identified as annual reference layers and which prevent meltwater from percolating into the firn body. Thus, a combination of ablation measurements and the application of the flux divergence method for the determination of accumulation is proposed.     

The 1958�C2009 Greenland ice sheet surface melt and the mid-tropospheric atmospheric circulation

In order to assess the impact of the mid-tropospheric circulation over the Greenland ice sheet (GrIS) on surface melt, as simulated by the regional climate model MAR, an automatic Circulation type classification (CTC) based on 500?hPa geopotential height from reanalyses is developed. General circulation correlates significantly with the surface melt anomalies for the summers in the period 1958?C2009. The record surface melt events observed during the summers of 2007?C2009 are linked to the exceptional persistence of atmospheric circulations favouring warm air advection. The CTC emphasizes that summer 500?hPa circulation patterns have changed since the beginning of the 2000s; this process is partly responsible for the recent warming observed over the GrIS.     

Did the massive magnetite “lava flows” of El Laco (Chile) form by magmatic or hydrothermal processes? New constraints from magnetite composition by LA-ICP-MS

The El Laco magnetite deposits consist of more than 98 % magnetite but show field textures remarkably similar to mafic lava flows. Therefore, it has long been suggested that they represent a rare example of an effusive Fe oxide liquid. Field and petrographic evidence, however, suggest that the magnetite deposits represent replacement of andesite flows and that the textures are pseudomorphs. We determined the trace element content of magnetite by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) from various settings at El Laco and compared them with magnetite from both igneous and hydrothermal environments. This new technique allows us to place constraints on the conditions under which magnetite in these supposed magnetite “lava flows” formed. The trace element content of magnetite from the massive magnetite samples is different to any known magmatic magnetite, including primary magnetite phenocrysts from the unaltered andesite host rocks at El Laco. Instead, the El Laco magnetite is most similar in composition to hydrothermal magnetite from high-temperature environments (>500 °C), such as iron oxide-copper-gold (IOCG) and porphyry-Cu deposits. The magnetite trace elements from massive magnetite are characterised by (1) depletion in elements considered relatively immobile in hydrothermal fluids (e.g. Ti, Al, Cr, Zr, Hf and Sc); (2) enrichment in elements that are highly incompatible with magmatic magnetite (rare earth elements (REE), Si, Ca, Na and P) and normally present in very low abundance in magmatic magnetite; (3) high Ni/Cr ratios which are typical of magnetite from hydrothermal environments; and (4) oscillatory zoning of Si, Ca, Mg, REE and most high field strength elements, and zoning truncations indicating dissolution, similar to that formed in hydrothermal Fe skarn deposits. In addition, secondary magnetite in altered, brecciated host rock, forming disseminations and veins, has the same composition as magnetite from the massive lenses. Euhedral magnetite lining both open-spaced veins in the brecciated host rock and along the walls of large, hollow chimneys in the massive magnetite lenses also displays oscillatory zoning and most likely formed by fluctuating composition and/or physio-chemical conditions of the fluid. Thus, the chemical fingerprint of magnetite from the supposed El Laco magnetite lava flows supports the hydrothermal model of metasomatic replacement of andesite lava flows, by dissolution and precipitation of magnetite from high-temperature fluids, rather than a magmatic origin from an effusive Fe oxide liquid.     

Some mineralogical applications of synchrotron radiation

Synchrotron radiation offers several advantages over the conventional X-ray sources, among which the most important are its high intensity, broad spectral range and natural collimation. Among the numerous techniques which have been recently developed we present a review of the results concerning more specifically mineralogical systems: X-ray absorption spectroscopy concerning high-resolution edge spectra and Extended X-ray absorption fine structure (EXAFS), X-ray diffraction under high P-high T conditions, small-angle scattering, X-ray microanalysis and X-ray topography. For each technique the basic principles are described together with the experimental devices used, before mineralogical examples are given. Two main applications may be pointed out: chemical and structural characterization of disordered systems and kinetic studies (phase transitions and evolution). Many other techniques (photoelectron spectroscopy, X-ray fluorescence analysis ...) which are actually under development as a result of the rapid increase of the use of storage rings are not covered in the present review but will possibly also be used in the near future in Earth Sciences.     

30 and 43 months period cycles found in air temperature time series using the Morlet wavelet method

A wavelet-based methodology is applied to relevant climatic indices and air temperature records and allow to detect the existence of unexpected cycles. The scale spectrum shows the presence of two cycles of about 30 and 43 months, respectively, in the air–temperature time series, in addition to the well-known cycles of 1 day and 1 year. The two cycles do not affect the globe uniformly: some regions seem to be more influenced by the period of 30 months (e.g. Europe), while other areas are affected by the period of 43 months (e.g. North-West of the USA). Similar cycles are found in the indices and the regions influenced by these indices: the NAO index and the Western Europe display a cycle of 30 months, while the cycle of 43 months can be found in the ENSO index and in regions where it is known to have an impact.     

Genesis of the Assif El Mal Zn–Pb (Cu,Ag) vein deposit. An extension-related Mesozoic vein system in the High Atlas of Morocco. Structural,mineralogical, and geochemical evidence

The Assif El Mal Zn–Pb (Cu–Ag) vein system, located in the northern flank of the High Atlas of Marrakech (Morocco), is hosted in a Cambro-Ordovician volcaniclastic and metasedimentary sequence composed of graywacke, siltstone, pelite, and shale interlayered with minor tuff and mudstone. Intrusion of synorogenic to postorogenic Late Hercynian peraluminous granitoids has contact metamorphosed the host rocks giving rise to a metamorphic assemblage of quartz, plagioclase, biotite, muscovite, chlorite, amphibole, chloritoid, and garnet. The Assif El Mal Zn–Pb (Cu–Ag) mineralization forms subvertical veins with ribbon, fault breccia, cockade, comb, and crack and seal textures. Two-phase liquid–vapor fluid inclusions that were trapped during several stages occur in quartz and sphalerite. Primary inclusion fluids exhibit T _h mean values ranging from 104°C to 198°C. Final ice-melting temperatures range from −8.1°C to −12.8°C, corresponding to salinities of ∼15 wt.% NaCl equiv. Halogen data suggest that the salinity of the ore fluids was largely due to evaporation of seawater. Late secondary fluid inclusions have either Ca-rich, saline (26 wt.% NaCl equiv.), or very dilute (3.5 wt.% NaCl equiv.) compositions and homogenization temperatures ranging from 75°C to 150°C. The δ¹⁸O and δD fluid values suggest an isotopically heterogeneous fluid source involving mixing between connate seawater and black-shale-derived organic waters. Low δ¹³C_VPDB values ranging from −7.5‰ to −7.7‰ indicate a homogeneous carbon source, possibly organic matter disseminated in black shale hosting the Zn–Pb (Cu–Ag) veins. The calculated δ³⁴S_H2S values for reduced sulfur (22.5‰ to 24.3‰) are most likely from reduction of SO₄ ²⁻ in trapped seawater sulfate or evaporite in the host rocks. Reduction of sulfate probably occurred through thermochemical sulfate reduction in which organic matter was oxidized to produce CO₂ which ultimately led to precipitation of saddle dolomite with isotopically light carbon. Lead isotope compositions are consistent with fluid–rock interaction that leached metals from the immediate Cambro-Ordovician volcaniclastic and metasedimentary sequence or from the underlying Paleo-Neoproterozoic crustal basement. Geological constraints suggest that the vein system of Assif El Mal formed during the Jurassic opening of the central Atlantic Ocean.     

A two‐step process for the reflooding of the Mediterranean after the Messinian Salinity Crisis

The Messinian Salinity Crisis is well known to have resulted from a significant drop of the Mediterranean sea level. Considering both onshore and offshore observations, the subsequent reflooding is generally thought to have been very sudden. We present here offshore seismic evidence from the Gulf of Lions and re‐visited onshore data from Italy and Turkey that lead to a new concept of a two‐step reflooding of the Mediterranean Basin after the Messinian Salinity Crisis. The refilling was first moderate and relatively slow accompanied by transgressive ravinement, and later on very rapid, preserving the subaerial Messinian Erosional Surface. The amplitude of these two successive rises of sea level has been estimated at ≤500 m for the first rise and 600–900 m for the second rise. Evaporites from the central Mediterranean basins appear to have been deposited principally at the beginning of the first step of reflooding. After the second step, which preceeded the Zanclean Global Stratotype Section and Point, successive connections with the Paratethyan Dacic Basin, then the Adriatic foredeep, and finally the Euxinian Basin occurred, as a consequence of the continued global rise in sea level. A complex morphology with sills and sub‐basins led to diachronous events such as the so‐called ‘Lago Mare’.This study helps to distinguish events that were synchronous over the entire Mediterranean realm, such as the two‐step reflooding, from those that were more local and diachronous. In addition, the shoreline that marks the transition between these two steps of reflooding in the Provence Basin provides a remarkable palaeogeographical marker for subsidence studies.     

Modeling the sediment yield and the impact of vegetated filters using an event‐based soil erosion model—a case study of a small Canadian watershed

This paper presents the first application of the event‐based MHYDAS‐Erosion model to a small agricultural watershed under temperate climate conditions (Quebec, Canada). Simulation results based on observed and synthetic rainfall events revealed a bimodal behaviour of sediment yield. During high‐intensity rainfall events, most of the sediments reaching the watershed outlet originate from cropland. Meanwhile, during low‐intensity events, most of the sediments come from the drainage network. Furthermore, simulation results show that implementation of 5‐m and 20‐m wide vegetated filters throughout the watershed or at the edge of the most problematic fields (4% of the total fields) could reduce soil loss by 52% and 31%, respectively. The modeling framework could be used for the design and location of beneficial management practices such as grass strips and riparian zones Copyright © 2016 John Wiley & Sons, Ltd.