Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.     

Paleogene–Neogene Boundary of Primorye,Russian Far East

Complex geological and paleobotanic analysis of sections of the boundary Oligocene–Miocene sediments of southern Primorye is conducted. The presence of a stratigraphic hiatus is identified in the transitional complexes of the Pushkino and Pavlovka depressions but not in the sections of the Rakovka depression; thus, it is suggested to use one of them (borehole no. 15) to choose the stratotype of the Paleogene–Neogene boundary. The previous conclusion on the presence of economic coal deposits of Primorye within the Paleogene part of the Tertiary complex is supported. It is suggested to use the section which is exposed by the Rakovka brown coal open pit (point 9209) as a stratotype of the upper subformation of the Pavlovka Formation.     

Assessment of spatial distribution of contaminants and their levels in soil and water resources of Calabar,Nigeria using geophysical and geological data

The contamination levels of soils and water resources in Calabar, Nigeria have been investigated using resistivity (vertical electrical sounding and electrical resistivity tomography), geochemical analyses of soil and water resources and textural analysis. Sixty randomly sited VES sites were investigated in two seasons while ERT investigations were performed along four profiles. The geochemical investigations were spread across seasons in order to track seasonal changes in physico-chemical parameters: hydrogen ion concentration (pH), electrical conductivity, total dissolved solids, chloride ion (Cl^?), nitrate ion (\( {\text{NO}}_{ 3}^{ - } \)), bicarbonate (\( {\text{HCO}}_{ 3}^{ - } \)), sulphate ion (\( {\text{SO}}_{ 4}^{2 - } \)), calcium ion (Ca²⁺), sodium ion (Na⁺), potassium ion (K⁺) and magnesium ion (Mg²⁺). Additionally, concentrations of ammonium, aluminium and nitrite ions in soils were determined. Results show that ionic concentrations in the sand-dominated soils and water are within permissible limits and baseline standards. The resistivities follow known trends in the area. However, at the central waste disposal site, a localised thin (< 5 m), low resistivity (< 15 Ωm) anomaly suspected to be due to contamination by leachates was observed. Comparatively, the contaminated area is also characterised by marginal increase in ionic concentrations. Strong attenuation capacities of overlying and adjoining clay/lateritic sediments and optimal design of the waste dump site probably reduced the spread of contaminants. The contaminated zone need to be closely monitored so that it does not extend to the aquifers. Hence, all strategies presently being used in managing wastes in Calabar should be sustained.     

Effects of historical and projected land use/cover change on runoff and sediment yield in the Netravati river basin,Western Ghats,India

In this study, the effects of changes in historical and projected land use land cover (LULC) on monthly streamflow and sediment yield for the Netravati river basin in the Western Ghats of India are explored using land use maps from six time periods (1972, 1979, 1991, 2000, 2012, and 2030) and the soil and water assessment tool (SWAT). The LULC for 2030 is projected using the land change modeller with the assumption of normal growth. The sensitivity analysis, model calibration, and validation indicated that the SWAT model could reasonably simulate streamflow and sediment yield in the river basin. The results showed that the spatial extent of the LULC classes of urban (1.80–9.96%), agriculture (31.38–55.75%), and water bodies (1.48–2.66%) increased, whereas that of forest (53.04–27.03%), grassland (11.17–4.41%), and bare land (1.09–0.16%) decreased from 1972 to 2030. The streamflow increased steadily (7.88%) with changes in LULC, whereas the average annual sediment yield decreased (0.028%) between 1972 and 1991 and increased later (0.029%) until 2012. However, it may increase by 0.43% from 2012 to 2030. The results indicate that LULC changes in urbanization and agricultural intensification have contributed to the increase in runoff, amounting to 428.65 and 58.67 mm, respectively, and sediment yield, amounting to 348 and 43 ton/km², respectively, in the catchment area from 1972 to 2030. The proposed methodology can be applied to other river basins for which temporal digital LULC maps are available for better water resource management plans.     

The Red Sea depositional architecture: insights from 3D modeling

More than half a century of geological and exploration studies have taken place in the Red Sea area, and still very limited information is available to the geological community in regard to the lithological distribution and the stratigraphic architecture. In this study, extensive well data was used to build the first lithologic and stratigraphic 3D models of the entire Red Sea to better understand the lithological distribution. The potential models have been constrained by bathymetric and geophysical data. Studied data demonstrate that up to 5 km of sediments were deposited in the Red Sea. It is mainly comprised of limestones, evaporites, and shales. Our models show that the evaporite body represents more than 70% of the Red Sea succession. In particular, the evaporite succession seems to be well developed in the southern region. Salt dome features are present and developed close to the margins. The models suggest that domal formation did not enable thick carbonate accumulation in some parts of the basin but the carbonate generally follows the evaporite trend. The models help to identify the main controls leading to salt diapir by highlighting the distribution of this body and the geometry of geological structures. Syn-rift faulting and rifting has been one of the most prominent structural features. Complex interplay of tectono-stratigraphic events played a significant role in shaping the stratigraphic evolution of the Red Sea basin with multiple evolution phases of paleoenvironment and paleogeographic were recognized based on the models. Our synthesis and interpretation support that moderately deep marine conditions dominated in the Miocene, whereas shallow seas dominated the whole basin during the Plio-Pleistocene period as a result of episodic marine invasion. However, lacustrine environment may have prevailed at the Oligocene time in isolated half grabens.     

Developing a seismic source model for the Arabian Plate

A seismic source model is developed for the entire Arabian Plate, which has been affected by a number of earthquakes in the past and in recent times. Delineation and characterization of the sources responsible for these seismic activities are crucial inputs for any seismic hazard study. Available earthquake data and installation of local seismic networks in most of the Arabian Plate countries made it feasible to delineate the seismic sources that have a hazardous potential on the region. Boundaries of the seismic zones are essentially identified based upon the seismicity, available data on active faults and their potential to generate effective earthquakes, prevailing focal mechanism, available geophysical maps, and the volcanic activity in the Arabian Shield. Variations in the characteristics given by the above datasets provide the bases for delineating individual seismic zones. The present model consists of 57 seismic zones extending along the Makran Subduction Zone, Zagros Fold-Thrust Belt, Eastern Anatolian Fault, Aqaba-Dead Sea Fault, Red Sea, Gulf of Aden, Owen Fracture Zone, Arabian Intraplate, and a background seismic zone, which models the floating seismicity that is unrelated to any of the distinctly identified seismic zones. The features of the newly developed model make the seismic hazard results likely be more realistic.     

Radioactive anomalies associated with the graphite-bearing metasediments,Wadi Umm Gheig area,Central Eastern Desert,Egypt

The study area is located in the central part of the Eastern Desert of Egypt and is mainly covered by different varieties of Precambrian basement rocks represented mainly by younger and older granites, metadiorite, metavolcanics, and metasediments. The analysis and interpretation of airborne gamma-ray spectrometric survey data are essentially based on the computation of the three radioelements (U, Th, and K) favorability indices, estimation of uranium migration rate percentage, variation of eU with eTh and eU/eTh ratio, and the construction of the contour map of the (eU-eTh/3.5) in the different rock units. The highest percent of uranium migration- out or leaching rate is connected with the red and pink granites of Gebel Kadabora El-hamra, metadiorite, and red and pink granites of G. Umm Rakham (??20.8%, ??18.57%, and ??8.45% respectively), which indicates that they could represent a major U-source bodies in the area. It was observed that the metasediments and associated graphite-bearing schists west and northwest of G. Kadabora El-hamra reflect more precipitation than the other locations around the pluton (the uranium migration rates varies between 2.59 and 30%) which mean that the graphite may have acted as a reducing agent for uranium carried in oxidizing fluids (surface meteoric water) and resulted in its precipitation. In the light of the availability of uranium source, its mobility, and graphite-bearing metasediments, the area has a good potential for the possible occurrence of uranium mineralization.     

Synthesis of biochar from sugarcane filter-cake and its impacts on physiological performance of lettuce (<Emphasis Type="Italic">Lettuce sativa</Emphasis>) grown on cadmium contaminated soil

Soil contamination with cadmium has become major concern all over the world because of its adverse impacts on ecosystem health and agricultural land. Soil amendment with biochar may have varied effects on physical and chemical properties of soil. The objective of the study was to explore the impact of sugarcane filter-cake biochar on physiological performance and growth of lettuce in an aged soil. Four different doses (0, 1.5%, 3%, and 5%) of biochar were used in the soil and conditioned for 1 month. After this, lettuce seedlings were grown in the soil. The results showed that the biochar treatment improved the fresh and dry biomass of leaves and roots as well as plant height while diminished the bioavailability of cadmium from the soil. As compared to control, biochar significantly enhanced the chlorophyll content in lettuce leaves. Due to the biochar amendment, the oxidative stress decreased in lettuce shoots over the control. As compared to control, concentration of cadmium in lettuce significantly decreased after the application of biochar. It was concluded that biochar could mitigate the toxicity of cadmium in lettuce by altering the biochemical and physiological processes in cadmium contaminated soil.