Foreword

Destructive earthquakes have caused great damage in China and the United States and collapsing buildings have caused many deaths and injuries. The field of earthquake engineering studies earthquake hazards, the occurrence of     

Mean horizontal wind profiles measured in the atmospheric boundary layer about a simulated block building

Instrumented wind towers are used to measure the three components of wind about a simulated block building. The mean horizontal wind profiles over the building are compared with wind profiles measured in the absence of the building and the wind speed deficit in the wake of the building is correlated.Horizontal mean wind speeds measured in the natural atmospheric boundary layer with and without the presence of a simulated building show excellent reproducibility and agreement with fundamental concepts of fluid mechanics. The data possess all the characteristic features reported from wind-tunnel studies of building flows. In the present study the turbulence intensity is of the order of 20% in the undisturbed flow whereas the free stream turbulence intensity of wind-tunnel studies is generally not more than 5%. The effect of smaller averaging periods and the structure of the turbulence will be reported at a later time.The velocity profiles measured in the undisturbed flow zones support the representation of a neutrally stable atmospheric boundary layer with a logarithmic wind profile.     

Remote Sensing of Three-dimensional Winds with Elastic Lidar: Explanation of Maximum Cross-correlation Method

Maximum cross-correlation provides a method toremotely de-ter-mine high-lyre-solved three-dimensional fields of horizontalwinds with e-las-tic li-darthrough-out large volumes of the planetaryboundary layer (PBL). This paperdetails the technique and shows comparisonsbetween elastic lidar winds, remotelysensed laser Doppler velocimeter (LDV) windprofiles, and radiosonde winds.Radiosonde wind data were acquired at Barcelona,Spain, during the BarcelonaAir-Quality Initiative (1992), and the LDVwind data were acquired at SunlandPark, New Mexico during the 1994 Border AreaAir-Quality Study. Comparisonsshow good agreement between the differentinstruments, and demonstrate the methoduseful for air pollution management at thelocal/regional scale. Elastic lidar windscould thus offer insight into aerosol andpollution transport within the PBL. Lidarwind fields might also be used to nudge orimprove initialization and evaluation ofatmospheric meteorological models.     

Shuram-Wonoka carbon isotope excursion:Ediacaran revolution in the world ocean's meridional overturning circulation

The late Ediacaran Shuram-Wonoka excursion, with δ~(13)C_(carb) values as low as-12‰(PDB) in marineshelf deposits and spanning up to 10 Myr, is the deepest and most protracted δ~(13)C_(carb) negative anomaly recognised in Earth history. The excursion formed on at least four continents in low(≤32°) palaeolatitudes, and in China is associated with a major phosphogenic event. Global and intrabasinal correlation, magnetostratigraphy, isotope conglomerate tests and further geochemical data are consistent with a primary or syn-depositional origin for the excursion. Continental-margin phosphorites are generated by oceanic upwelling driven by surface winds, and δ~(13)C_(carb) negative anomalies are explicable by oceanic upwelling of 13 C-depleted deep oceanic waters, arguing that a feature common to these exceptional Ediacaran events was unprecedented perturbation of the world ocean. These events occurred during the transition from an alien Proterozoic world marked by low-palaeolatitude glaciation near sea level and strong seasonality to the familiar Phanerozoic Earth with circum-polar glaciation and temperate climate, suggesting that the Shuram-Wonoka excursion is related to this profound change in Earth's climate system. Of various hypotheses for Proterozoic low-palaeolatitude glaciation, only the high obliquity(54°) hypothesis, which posits secular decrease in obliquity to near the present-day value(23.5°) during the Ediacaran, predicts an unparalleled revolution in the Ediacaran world ocean. The obliquity controls the sense of the world ocean's meridional overturning circulation, which today is driven by the sinking of cold, dense water at the poles and upwelling driven by zonal surface winds.When the decreasing obliquity passed the critical value of 54° during the Ediacaran the meridional temperature gradient reversed, with the equator becoming warmer than the poles and Hadley lowlatitude(30°-35°) atmospheric zonal circulation reversing. This reversal of the temperature gradient is unique to the Ediacaran Period and caused reversal of the oceanic meridional overturning circulation,with upwelling of anoxic, 13 C-depleted deep oceanic waters producing a deeply negative and protractedδ~(13)C_(carb) signature on late Ediacaran marine-shelf deposits.     

On Internal Gravity Waves Associated with the Stable Boundary Layer

The stable planetary boundary layer at the baseof the residual layer supports internalwaves that are unambiguously boundary layer incharacter. Some of these wavesare instabilities and some are neutrally stable modes, but they all have critical levelsin the residual layer. These waves exist for a broad range of conditions and should bea major component of any ducted disturbance that propagates within ninety degreesof the wind direction. The wave properties can be computed without the numericaldifficulties usually associated with critical-level systems.     

The representative concentration pathways: an overview

This paper summarizes the development process and main characteristics of the Representative Concentration Pathways (RCPs), a set of four new pathways developed for the climate modeling community as a basis for long-term and near-term modeling experiments. The four RCPs together span the range of year 2100 radiative forcing values found in the open literature, i.e. from 2.6 to 8.5 W/m². The RCPs are the product of an innovative collaboration between integrated assessment modelers, climate modelers, terrestrial ecosystem modelers and emission inventory experts. The resulting product forms a comprehensive data set with high spatial and sectoral resolutions for the period extending to 2100. Land use and emissions of air pollutants and greenhouse gases are reported mostly at a 0.5?×?0.5 degree spatial resolution, with air pollutants also provided per sector (for well-mixed gases, a coarser resolution is used). The underlying integrated assessment model outputs for land use, atmospheric emissions and concentration data were harmonized across models and scenarios to ensure consistency with historical observations while preserving individual scenario trends. For most variables, the RCPs cover a wide range of the existing literature. The RCPs are supplemented with extensions (Extended Concentration Pathways, ECPs), which allow climate modeling experiments through the year 2300. The RCPs are an important development in climate research and provide a potential foundation for further research and assessment, including emissions mitigation and impact analysis.     

On the speciation of metals in the water column of a polluted estuary

The dissolved (<0.40 γm) fraction of water samples from Newark Bay, New Jersey was analysed for Zn, Cu and Pb content by differential pulse anodic stripping polarographic techniques. In the dissolved fraction, non-labile forms of Zn, Cu and Pb exist as shown by differential pulse anodic stripping voltammetry analysis on acidified samples and acidified-UV irradiated samples. The particulate fraction (>;0.40 μm) contains metals in the form of sulphides (Fe, Zn, Cu, Mn), oxides and oxyhydroxides (Si, Al, Fe, Cu, Ni, Sn), phosphate (Ca, Ce, La), clay minerals (Fe, Zn, Cu, Ti) and carbonaceous material (Fe, Cu, Zn) as demonstrated by X-ray microanalysis. The solid phases are likely present in colloidal form in the dissolved fraction of the water column as well. The forms of the metals in the water column are partially due to the resuspension of bottom sediments by dredging and natural processes, to sewage outfall and to natural geochemical processes.     

Late Cryogenian glaciation in South Australia:Fluctuating ice margin and no extreme or rapid post-glacial sea-level rise

Postulated extreme sea-level rise of up to 1-1.5 km with the late Cryogenian Ghaub deglaciation in Namibia is contentious,as is the great rapidity(<104 yr)of the sea-level rise.Such extreme glacioeustatic events,if real,would have been global and affected all continents.In South Australia,up to six glacial advances and retreats during the late Cryogenian Elatina glaciation indicate a fluctuating ice margin.The latter stage of the Elatina glaciation and the immediate post-glacial environment are examined here for evidence of extreme and rapid sea-level rise.In the central Adelaide Rift Complex,diamictite with faceted and striated clasts occurs at the top of the Elatina Formation<1-2 m beneath the early Ediacaran Nuccaleena Formation’cap carbonate’.One hundred kilometres to the south,~30 m of siltstone and sandstone followed by^6 m of clast-poor diamictite with clasts 10+cm long occur between tidal rhythmites and the cap carbonate.Three hundred kilo metres further south,~70 m of siltsto ne,dolo mitic siltstone and minor dolomite separate tidal rhythmites and early Ediacaran strata.Hence the rhythmites were deposited during a high stand(interstadial or interglacial),not during post-glacial sea-level rise.Storm-generated erosional surfaces within tidal rhythmites at Warren Gorge indicate intermittent rhythmite deposition,and water depth and other palaeoenvironmental factors are uncertain,casting doubt on a published estimate of rapid sea-level rise during rhythmite deposition.The lack of late Cryogenian deeply incised valleys and thick valley-fill deposits in South Australia and central Australia argues against extreme sea-level variations.A hiatus occurred between Elatina deglaciation and deposition of the Nuccaleena cap carbonate,and three palaeomagnetic polarity chrons identified in the cap carbonate imply slow deposition spanning 10^5-10^6 yr.This is supported by independent evidence from magnetic chronostratigraphy for Ediacaran strata in South Australia and California,and by stratigraphic and sedimentological arguments for condensed deposition of cap carbonates.It is concluded that neither extreme nor rapid sea-level rise was associated with late Cryogenian deglaciation in South Australia.     

Determination of the Electrochemical Properties of a Soluble Aqueous FeS Species Present in Sulfidic Solutions

Field and laboratory data are presented that show a soluble FeS species(FeS_aq) exists in sulfidic seawater solutions, and is observedwhen the IAP exceeds the K_sp of amorphous FeS. TheFeS_aq yields a discrete signal (double peak) using square-wavevoltammetry and two one-electron waves in sampled DC polarographyexperiments at the Hg electrode. The aqueous FeS species reacts irreversiblyat the electrode as a single FeS subunit and not as a polymeric entity. Thepeak potential of FeS_aq occurs at -1.1 V whereas the peakpotential of Fe occurs at-1.45 V; the positive shift for Fe²⁺ reduction inFeS_aq indicates a change in geometry for Fe²⁺from octahedral to tetrahedral. The kinetics of electron transfer at theelectrode are determined to be similar for both Fe²⁺ andFeS_aq. Molecular orbital energy diagrams, further indicatethat Fe(II) does change from octahedral to tetrahedral geometry in solution.First, Fe(II) exists as octahedralFe in solution whichundergoes a substitution reaction of bisulfide for water. The resultingcomplex, Fe(H₂O)₅(HS)⁺, thentransforms to a tetrahedral complex on further addition of sulfide. Thisgeometry change is consistent with the formation of amorphous FeS thatconverts to mackinawite which has tetrahedral Fe(II). The process is entropydriven because of the water loss that occurs. The overall sequence can berepresented as: Soluble FeS species are important asreactants in the formation of iron-sulfide minerals including pyrite.