Preserved organic matter in a fossil Ocean Continent Transition in the Alps: the example of Totalp,SE Switzerland

Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C₁₇–C₃₆. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems.     

Silt- and Bioclastic-Rich Flocs and Their Relationship to Sedimentary Structures: Modern Observations from the Petitcodiac River Estuary

Fine-grained sediment deposition is often conceived to happen in still water conditions and to represent slow sedimentation rates. However, it has been increasingly noted that mud sedimentation commonly occurs under high-energy conditions. The macrotidal Petitcodiac River estuary is used as an example to investigate the significance of flocculation as an important process in the rapid removal of large amounts of sediments from suspension under turbulent flow conditions. A range of physical sedimentary structures was observed at the Petitcodiac River estuary intertidal flats and bars, including low-angle and horizontal planar lamination, current and climbing ripples, surficial fluid mud, soft-sediment deformation, microfaults, and mud rip-up clasts. Fluid mud within the study area contains considerable proportions of clay (21–67%) and contributes to the formation of creeping fluid-mud sheets and streams. Detailed examination of the naturally occurring clay flocs shows that they contain up to 77% of the entangled silt- and sand-sized grains. SEM and microscopic imaging of fluid mud reveal a substantial amount of bioclastic material within the flocs and dispersed among the sediments. These observations show that physicochemical and biological processes influence silt, plankton, and clay aggregation. Water samples and observations from the Petitcodiac River estuary confirm that flocs form in the water column and then settle to the tidal-channel floor and flanking intertidal flats. Laboratory experiments, using Petitcodiac sediment, show how the clay flocs have the potential to sweep the water of silt-sized suspended grains. Additionally, diatoms and their associated extracellular polymeric substance (EPS) sheaths might play a role in mineral aggregation and increased sediment cohesiveness.     

Iterative selective spatial variance reduction of MYD11A2 LST data

The aim of this research effort is to develop a method that will allow to map and evaluate thermal anomalies in SW USA from the MYD11A2 night land surface temperature (LST) imagery being available for the year 2014, that present higher spatial (1 km) and temporal (46 images per year) resolution than the MYD11C3 LST data (12 images per year at 5.6 km spatial resolution). The fact that is MYD11A2 LST imagery is projected to a rectangular grid did not affect the X, Y and elevation (H) spatial decorrelation stretch. Principal component analysis and linear regression models isolated and removed the X, Y, H (spatial) dependent variance included in the data while metrics devised verified the selective spatial variance reduction. The reconstructed 46 LST images represent the amount the LST deviates from the X, Y and H predicted for the year 2014. The thematic information content of the reconstructed LST images is verified by cluster analysis and mapped the spatial extend and the temporal variability of thermal anomalies within the study area. The positive thermal anomaly clusters are spatially arranged mainly west of Sierra Nevada in Great Basin Section where extensional tectonics create a series of titled elongated mountain blocks along the N to S direction in between basins bounded by normal faults, while the negative thermal anomaly clusters are spatially arranged along the coastal region, further north and in the western region far from the tilted mountain tectonic blocks of the Great Basin Section. The spatial maps that define regions with (positive or negative) thermal anomalies and distinct mean land response could assist landcover studies and support urban and rural planning in the context of emerging climatic change.     

Weathering of the New Albany Shale, Kentucky: II. Redistribution of minor and trace elements

During weathering, elements enriched in black shale are dispersed in the environment by aqueous and mechanical transport. Here a unique evaluation of the differential release, transport, and fate of Fe and 15 trace elements during progressive weathering of the Devonian New Albany Shale in Kentucky is presented. Results of chemical analyses along a weathering profile (unweathered through progressively weathered shale to soil) describe the chemically distinct pathways of the trace elements and the rate that elements are transferred into the broader, local environment. Trace elements enriched in the unweathered shale are in massive or framboidal pyrite, minor sphalerite, CuS and NiS phases, organic matter and clay minerals. These phases are subject to varying degrees and rates of alteration along the profile. Cadmium, Co, Mn, Ni, and Zn are removed from weathered shale during sulfide-mineral oxidation and transported primarily in aqueous solution. The aqueous fluxes for these trace elements range from 0.1 g/ha/a (Cd) to 44 g/ha/a (Mn). When hydrologic and climatic conditions are favorable, solutions seep to surface exposures, evaporate, and form Fe-sulfate efflorescent salts rich in these elements. Elements that remain dissolved in the low pH (<4) streams and groundwater draining New Albany Shale watersheds become fixed by reactions that increase pH. Neutralization of the weathering solution in local streams results in elements being adsorbed and precipitated onto sediment surfaces, resulting in trace element anomalies.Other elements are strongly adsorbed or structurally bound to solid phases during weathering. Copper and U initially are concentrated in weathering solutions, but become fixed to modern plant litter in soil formed on New Albany Shale. Molybdenum, Pb, Sb, and Se are released from sulfide minerals and organic matter by oxidation and accumulate in Fe-oxyhydroxide clay coatings that concentrate in surface soil during illuviation. Chromium, Ti, and V are strongly correlated with clay abundance and considered to be in the structure of illitic clay. Illite undergoes minimal alteration during weathering and is concentrated during illuvial processes. Arsenic concentration increases across the weathering profile and is associated with the succession of secondary Fe(III) minerals that form with progressive weathering. Detrital fluxes of particle-bound trace elements range from 0.1 g/ha/a (Sb) to 8 g/ha/a (Mo). Although many of the elements are concentrated in the stream sediments, changes in pH and redox conditions along the sediment transport path could facilitate their release for aqueous transport.     

Environmental problems associated with the development and operation of a lined and unlined landfill site: a case study demonstrating two landfill sites in Patra,Greece

The present work demonstrates the environmental problems associated with the development and operation of a lined and unlined landfill site, both used for municipal solid waste landfilling, that are situated next to the city of Patra, Greece. Findings from a detailed site investigation as well calculations on hydrologic evaluation of landfill’s performance and measurements on leachate composition proved that the lined landfill site is more secure and environmental friendly compared with the unlined landfill site. Even though, until today, there is no evidence from near boreholes for severe contamination problems generated by any of the two landfills, in the forthcoming future several environmental problems are expected to occur from the unlined site. In addition the prevailing hydrogeotechnical conditions indicated that the unlined site is a potential source of contamination; hence extra remedial measures should be received by the local authorities to prevent severe contamination in soil and groundwater.     

Effect of Soil Parameters on Dynamic Cone Penetration Indices of Laterite Sub-grade Soils from India

The focus of this study was on correlating the effect of grain-size, maximum dry-density (MDD), field moisture content, and the void ratios on penetration measured using the dynamic cone penetrometer (DCP) for laterite soils blended with fines. Tests were performed on soil samples compacted to MDD for moulding water contents set to the optimum moisture content (OMC), dry of OMC, and wet of OMC un-soaked condition. The results indicated that an increase in the fines-content caused a decrease in the MDD, and an increase in the OMC and the DCP penetration. Regressions were developed correlating various parameters.     

Dynamic responses under the excitation of pulse sequences

This paper studies the dynamic responses of SDOF system under pulse-dominant excitations. The purpose of the study is to prepare for scrutiny of some near-field pulse-dominant ground motions and their potential to cause structural damage. Extending the single pulse dynamics, we consider the effect of pulse sequences. This kind of excitation was particularly obvious in some of previous earthquakes such as Northridge (1994) and Chi-Chi (1995). Based on the duration,peak and rise and decay era of the main pulse as well as its relationship with the predecessor and successor pulses, we propose a classification for the pulse sequences. Consequent studies have been carried out for acceleration, velocity and displacement response spectra of the main pulse with either a predecessor or a successor pulse. The analysis also includes general response behaviors in different fundamental period segments and special aspects of response at certain points (e.g., the corresponding peak points).     

The dayside magnetospheric boundary layer at Mercury

Magnetic field and plasma data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft on the outbound portions of the first (M1) and second (M2) flybys of Mercury reveal a region of depressed magnetic field magnitude and enhanced proton fluxes adjacent to but within the magnetopause, which we denote as a dayside boundary layer. The layer was present during both encounters despite the contrasting dayside magnetic reconnection, which was minimal during M1 and strong during M2. The overall width of the layer is estimated to be between 1000 and 1400 km, spanning most of the distance from the dayside planetary surface to the magnetopause in the mid-morning. During both flybys the magnetic pressure decrease was ∼1.6 nPa, and the width of the inner edge was comparable to proton gyro-kinetic scales. The maximum variance in the magnetic field across the inner edge was aligned with the magnetic field vector, and the magnetic field direction did not change markedly, indicating that the change in field intensity was consistent with an outward plasma-pressure gradient perpendicular to the magnetic field. Proton pressures in the layer inferred from reduced distribution observations were 0.4 nPa during M1 and 1.0 nPa during M2, indicating either that the proton pressure estimates are low or that heavy ions contribute substantially to the boundary-layer plasma pressure. If the layer is formed by protons drifting westward from the cusp, there should be a strong morning–afternoon asymmetry that is independent of the interplanetary magnetic field (IMF) direction. Conversely, if heavy ions play a major role, the layer should be strong in the morning (afternoon) for northward (southward) IMF. Future MESSENGER observations from orbit about Mercury should distinguish between these two possibilities.     

Strong shock-phenomena at petawatt-picosecond laser side-on ignition fusion of uncompressed hydrogen-boron11

An extreme anomaly of laser-plasma interaction with petawatt-picosecond (PW-ps) pulses of very high contrast ratio for suppression of relativistic self-focusing permitted a come-back of the Bobin-Chu side-on ignition of uncompressed deuterium-tritium (DT) fusion fuel. The plasma blocks for the side-on ignition have to be produced by the well confirmed nonlinear force acceleration which is about 100,000 times higher than thermo-kinetic fluid-dynamic acceleration for comparison with astrophysical cases. It is essential that the dielectric plasma properties within the nonlinear force are used. Using the measured ion beam densities above 10¹¹ A s/cm² the ignition mechanism needed numerical and theoretical studies of extremely strong shock phenomena. When extending these results to the side-on ignition of uncompressed hydrogen-boron11 (HB11), surprisingly, the ignition by this shock mechanism was only about 10 times more difficult than for DT in contrast to ignition by spherical laser driven compression using thermo-kinetic conditions in which case HB11 ignition is 100,000 times more difficult than DT.     

Barnacle larval transport in the Mandovi–Zuari estuarine system, central west coast of India

A two-dimensional hydrodynamic and particle tracking model was used to estimate the dispersion and retention of barnacle larvae from their possible spawning sites in a tropical monsoon-influenced estuarine system (central west coast of India). Validation of the hydrodynamic simulations yielded a good match with field measurements. The pattern of larval dispersal in the region varied with the winds and currents. The seasonal changes in abundance could be attributed to physical forcing and weather conditions. The extent of barnacle larval dispersal from spawning sites varied from 10 to 78 km for different sites and seasons. During a 24-h cycle, the larval abundance showed one to two peaks in the estuarine area. The increased larval abundance is favored by the flood currents, pushing the larvae into the estuary. Physical forcing in the region helps in transport of the larvae from their spawning sites hugging to the coast and contributing to the population within the estuary. Field observations and numerical experiments suggest the occurrence of higher larval abundance in the estuary during post-monsoon. The dispersal pattern indicated that the barnacle population present in the estuary is well mixed, and with a seasonally changing pattern.