Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

Palaeoleptus burmanicus n. gen., n. sp., an Early Cretaceous shore bug (Hemiptera: Palaeoleptidae n. fam.) in Burmese amber

Palaeoleptus burmanicus gen. et sp. nov. (Hemiptera: Leptopodomorpha: Palaeoleptidae fam. nov.) is described from Early Cretaceous Burmese amber. The fossil is characterized by nearly completely coreaceous wings with only a small membranous area at the distal tip, and a unique wing venation consisting of eight closed cells, including four obliquely orientated toward the embolar wing margin and two large vertically-positioned cells extending nearly to the apical wing margin. Additional characters are large, compound eyes, three pairs of cephalic trichobothria, four antennal segments all similar in texture, spines on the profemur, ocelli positioned on a tubercle and a rostrum extending to the mesocoxae, with the second segment bearing four pairs of spines. The female fossil contains an asymmetrical subgenital plate orientated toward the left side of the body, indicating a side-by-side mating behavior as occurs in extant Leptopodomorpha.     

Periodic orbits and escapes in dynamical systems

We study the periodic orbits and the escapes in two different dynamical systems, namely (1) a classical system of two coupled oscillators, and (2) the Manko-Novikov metric which is a perturbation of the Kerr metric (a general relativistic system). We find their simple periodic orbits, their characteristics and their stability. Then we find their ordered and chaotic domains. As the energy goes beyond the escape energy, most chaotic orbits escape. In the first case we consider escapes to infinity, while in the second case we emphasize escapes to the central ??bumpy?? black hole. When the energy reaches its escape value, a particular family of periodic orbits reaches an infinite period and then the family disappears (the orbit escapes). As this family approaches termination it undergoes an infinity of equal period and double period bifurcations at transitions from stability to instability and vice versa. The bifurcating families continue to exist beyond the escape energy. We study the forms of the phase space for various energies, and the statistics of the chaotic and escaping orbits. The proportion of these orbits increases abruptly as the energy goes beyond the escape energy.     

A Comparative Plume Study of DRO,GRO, Benzene,and MTBE: Implications for Risk Management

Groundwater remediation and no-further action decision making at petroleum underground storage tank (UST) sites has largely been based on an understanding of plume length, plume stability, and attenuation rates for key hydrocarbon constituents. Regulatory guidance to support and guide such decisions is based in part on plume studies involving individual hydrocarbon constituents, namely benzene and methyl tert-butyl ether (MTBE). Questions remain regarding whether current guidance is applicable to chemical mixtures such as gasoline range organics (GRO), diesel range organics (DRO), and oxygen containing organic compounds (OCOCs) resulting from hydrocarbon biodegradation. To help address this concern, data from California's GeoTracker database were used to estimate maximum plume lengths, plume stability, and attenuation rates of DRO (which can be used as an analytical surrogate for OCOCs) and GRO relative to benzene and MTBE. The distributions of maximum plume lengths were similar for the four constituents with medians ranging from 27 to 32 m. The fraction of monitoring wells with a decreasing concentration trend ranged from 19% for DRO to 40% for MTBE, while fewer than 7% of the wells had an increasing concentration trend for any of the constituents. Median attenuation rates ranged from 0.10% day⁻¹ for DRO to 0.17% day⁻¹ for MTBE. The results suggest attenuation based risk management is appropriate for DRO and GRO plumes at most petroleum UST sites.     

The early-type galaxies NGC 1407 and NGC 1400 – I. Spatially resolved radial kinematics and surface photometry

This is the first paper of a series focused on investigating the star formation and evolutionary history of the two early-type galaxies NGC 1407 and NGC 1400. They are the two brightest galaxies of the NGC 1407 (or Eridanus-A) group, one of the 60 groups studied as part of the Group Evolution Multi-wavelength Study.
Here, we present new high signal-to-noise ratio long-slit spectroscopic data obtained at the ESO 3.6-m telescope and high-resolution multiband imaging data from the Hubble Space Telescope /Advanced Camera for Surveys and wide-field imaging from Subaru Suprime-Cam. We spatially resolved integrated spectra out to ∼0.6 (NGC 1407) and ∼1.3 (NGC 1400) effective radii. The radial profiles of the kinematic parameters v _rot, σ, h ₃ and h ₄ are measured. The surface brightness profiles are fitted to different galaxy light models and the colour distributions analysed. The multiband images are modelled to derive isophotal shape parameters and residual galaxy images. The parameters from the surface brightness profile fitting are used to estimate the mass of the possible central supermassive black hole in NGC 1407. The galaxies are found to be rotationally supported and to have a flat core in the surface brightness profiles. Elliptical isophotes are observed at all radii and no fine structures are detected in the residual galaxy images. From our results, we can also discard a possible interaction between NGC 1400, NGC 1407 and the group intergalactic medium. We estimate a mass of  ∼1.03 × 10⁹ M_⊙  for the supermassive black hole in NGC 1407 galaxy.     

Dimensionless measures of turbulent magnetohydrodynamic dissipation rates

The magnetic Reynolds number, R _M, is defined as the product of a characteristic scale and associated flow speed divided by the microphysical magnetic diffusivity. For laminar flows, R _M also approximates the ratio of advective to dissipative terms in the total magnetic energy equation, but for turbulent flows this latter ratio depends on the energy spectra and approaches unity in a steady state. To generalize for flows of arbitrary spectra we define an effective magnetic dissipation number,   R _M,e  , as the ratio of the advection to microphysical dissipation terms in the total magnetic energy equation, incorporating the full spectrum of scales, arbitrary magnetic Prandtl numbers, and distinct pairs of inner and outer scales for magnetic and kinetic spectra. As expected, for a substantial parameter range   R _M,e∼ O (1) ≪ R _M  . We also distinguish   R _M,e  from     where the latter is an effective magnetic Reynolds number for the mean magnetic field equation when a turbulent diffusivity is explicitly imposed as a closure. That   R _M,e  and     approach unity even if   R _M≫ 1  highlights that, just as in hydrodynamic turbulence, energy dissipation of large-scale structures in turbulent flows via a cascade can be much faster than the dissipation of large-scale structures in laminar flows. This illustrates that the rate of energy dissipation by magnetic reconnection is much faster in turbulent flows, and much less sensitive to microphysical reconnection rates compared to laminar flows.     

High resolution facies architecture and digital outcrop modeling of the Sandakan formation sandstone reservoir,Borneo:Implications for reservoir characterization and flow simulation

Advances in photogrammetry have eased the acquisition of high-resolution digital information from outcrops, enabling faster, non-destructive data capturing and improved reservoir modeling. Geocellular models for flow dynamics with in the virtual outcrop in siliciclastic deposits at different sets of sandstone facies architecture remain, however, a challenge. Digital maps of bedding, lithological contrast, spatial-temporal variations of bedding and permeability characteristics make it more easy to understand flow tortuosity in a particular architecture. An ability to precisely model these properties can improve reservoir characterization and flow modeling at different scales. Here we demonstrate the construction of realistic 2 D sandstone facies based models for a pragmatic simulation of flow dynamics using a combination of digital point clouds dataset acquired from LiDAR and field investigation of the Sandakan Formation, Sabah, Borneo.Additionally, we present methods for enhancing the accuracy of outcrop digital datasets for producing high resolution flow simulation. A well-exposed outcrop from the Sandakan Formation, Sabah, northwest Borneo having a lateral extent of 750 m was chosen in order to implement our research approach. Sandstone facies and its connectivity are well constrained by outcrop observations, data from air-permeability measurements, bilinear interpolation of permeability, grid construction and water vector analysis for flow dynamics.These proportions were then enumerated in terms of static digital outcrop model(DOM) and facies model based on sandstone facies bedding characteristics. Flow simulation of water vector analysis through each of the four sandstone facies types show persistent spatial correlation of permeability that align with either cross-bedded orientation or straight with more dispersion high quality sandstone(porosity 21.25%-41.2%and permeability 1265.20-5986.25 mD) and moderate quality sandstone(porosity 10.44%-28.75% and permeability 21.44-1023.33 mD). Whereas, in more heterolithic sandstone(wavy-to flaser-bedded and bioturbated sandstone), lateral variations in permeability show spatially non-correlated patterns over centimeters to tens of meters with mostly of low quality sandstone(porosity 3.4%-12.31% and permeability < 1 mD to 3.21 mD). These variations reflect the lateral juxtaposition in flow dynamics. It has also been resulted that the vertical connectivity and heterogeneities in terms of flow are mostly pragmatic due to the interconnected sandstone rather than the quality of sandstone.     

Impact of flooded rice paddy on remotely sensed evapotranspiration in the Krishna River basin,India

Evapotranspiration (ET) is one of the major water exchange processes between the earth's surface and the atmosphere. ET is a combined process of evaporation from open water bodies, bare soil and plant surfaces, and transpiration from vegetation. Remote sensing-based ET models have been developed to estimate spatially distributed ET over large regions, however, many of them reportedly underestimate ET over semi-arid regions (Jamshidi et al., Journal of Hydrometeorology, 2019, 20, 947–964). In this work, we show that underestimation of ET can occur due to the open water evaporation from flooded rice paddies ignored in the existing ET models. To address the gap in ET estimation, we have developed a novel approach that accounts for the missing ET component over flooded rice paddies. Our method improved ET estimates by a modified Penman-Monteith algorithm that considered the fraction of open water evaporation from flooded rice paddies. Daily ET was calculated using ground based meteorological data and the MODIS satellite data over the Krishna River Basin. Seasonal and annual ET values over the Krishna Basin were compared with two different ET algorithms. ET estimates from these two models were also compared for different crop combinations. Results were validated with flux tower-based measurements from other studies. We have identified a 17 mm/year difference in average annual ET over the Krishna River Basin with this new ET algorithm. This is very critical in basin scale water balance analysis and water productivity studies.     

Landscape transform and spatial metrics for mapping spatiotemporal land cover dynamics using Earth Observation data-sets

Analysis of Earth observation (EO) data, often combined with geographical information systems (GIS), allows monitoring of land cover dynamics over different ecosystems, including protected or conservation sites. The aim of this study is to use contemporary technologies such as EO and GIS in synergy with fragmentation analysis, to quantify the changes in the landscape of the Rajaji National Park (RNP) during the period of 19 years (1990–2009). Several statistics such as principal component analysis (PCA) and spatial metrics are used to understand the results. PCA analysis has produced two principal components (PC) and explained 84.1% of the total variance, first component (PC1) accounted for the 57.8% of the total variance while the second component (PC2) has accounted for the 26.3% of the total variance calculated from the core area metrics, distance metrics and shape metrics. Our results suggested that notable changes happened in the RNP landscape, evidencing the requirement of taking appropriate measures to conserve this natural ecosystem.